{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T01:17:23Z","timestamp":1789780643675,"version":"4.0.1"},"reference-count":71,"publisher":"American Chemical Society (ACS)","issue":"41","license":[{"start":{"date-parts":[[2018,10,5]],"date-time":"2018-10-05T00:00:00Z","timestamp":1538697600000},"content-version":"vor","delay-in-days":4,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_termsofuse.html"}],"funder":[{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["CHE-1565501"],"award-info":[{"award-number":["CHE-1565501"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100010663","name":"H2020 European Research Council","doi-asserted-by":"publisher","award":["772299"],"award-info":[{"award-number":["772299"]}],"id":[{"id":"10.13039\/100010663","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2018,10,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>[Ar\u2032SnCo]2 (1, Ar\u2032 = C6H3-2,6{C6H3-2,6-iPr2}2), a rare metal\u2013metal bonded cobalt\u2013tin cluster with low-coordinate tin atoms, was prepared by the reaction of [K(thf)0.2][Co(1,5-cod)2] (cod = 1,5-cyclooctadiene) with [Ar\u2032Sn(\u03bc-Cl)]2. This reaction illustrates a promising synthetic strategy to access uncommon metal clusters. The structure of 1 features a rhomboidal Co2Sn2 core with strong metal\u2013metal bonds between tin and cobalt and a weaker tin\u2013tin interaction. Reaction of 1 with white phosphorus afforded [Ar\u20322Sn2Co2P4] (2), the first molecular cluster compound containing phosphorus, cobalt and tin.<\/jats:p>","DOI":"10.1021\/jacs.8b08517","type":"journal-article","created":{"date-parts":[[2018,10,1]],"date-time":"2018-10-01T02:08:04Z","timestamp":1538359684000},"page":"13195-13199","source":"Crossref","is-referenced-by-count":29,"title":["Synthesis\nof a Cyclic Co2Sn2 Cluster Using a Co\u2013 Synthon"],"prefix":"10.1021","volume":"140","author":[{"given":"Christian M.","family":"Hoidn","sequence":"first","affiliation":[{"name":"University of Regensburg , , ,","place":["Regensburg, Germany, 93040"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian","family":"Ro\u0308dl","sequence":"additional","affiliation":[{"name":"University of Regensburg , , ,","place":["Regensburg, Germany, 93040"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Madison L.","family":"McCrea-Hendrick","sequence":"additional","affiliation":[{"name":"University of California, Davis , , One Shields Avenue , , ,","place":["Davis, California, United States, 95616"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Theresa","family":"Block","sequence":"additional","affiliation":[{"name":"University of Mu\u0308nster , , Corrensstra\u00dfe 30 , ,","place":["Mu\u0308nster, Germany, 48149"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rainer","family":"Po\u0308ttgen","sequence":"additional","affiliation":[{"name":"University of Mu\u0308nster , , Corrensstra\u00dfe 30 , ,","place":["Mu\u0308nster, Germany, 48149"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andreas W.","family":"Ehlers","sequence":"additional","affiliation":[{"name":"University of Amsterdam , , Science Park 904 , ,","place":["Amsterdam, The Netherlands, 1089 XH"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6262-3209","authenticated-orcid":true,"given":"Philip P.","family":"Power","sequence":"additional","affiliation":[{"name":"University of California, Davis , , One Shields Avenue , , ,","place":["Davis, California, United States, 95616"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4066-6483","authenticated-orcid":true,"given":"Robert","family":"Wolf","sequence":"additional","affiliation":[{"name":"University of Regensburg , , ,","place":["Regensburg, Germany, 93040"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2018,10,1]]},"reference":[{"key":"2026090114394080200_cit1","doi-asserted-by":"crossref","first-page":"485","DOI":"10.1002\/9783527673353.ch14","volume-title":"Molecular Metal-Metal\nBonds","author":"Less","year":"2015"},{"key":"2026090114394080200_cit2a","doi-asserted-by":"publisher","first-page":"317a","DOI":"10.1039\/c3973000317a","author":"Davidson","year":"1973","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"2026090114394080200_cit2b","doi-asserted-by":"publisher","first-page":"261","DOI":"10.1039\/c39760000261","author":"Goldberg","year":"1976","journal-title":"J. Chem. Soc., Chem.\nCommun."},{"key":"2026090114394080200_cit3a","doi-asserted-by":"publisher","first-page":"5930","DOI":"10.1021\/ja0257164","volume":"124","author":"Phillips","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"2026090114394080200_cit3b","doi-asserted-by":"publisher","first-page":"1650","DOI":"10.1002\/anie.200704635","volume":"47","author":"Jambor","year":"2008","journal-title":"Angew. Chem., Int.\nEd."},{"key":"2026090114394080200_cit3c","doi-asserted-by":"publisher","first-page":"2321","DOI":"10.1039\/c3cc49651a","volume":"50","author":"Hadlington","year":"2014","journal-title":"Chem. Commun."},{"key":"2026090114394080200_cit4a","doi-asserted-by":"publisher","first-page":"347","DOI":"10.1016\/S0010-8545(01)00321-6","volume":"215","author":"Fa\u0308ssler","year":"2001","journal-title":"Coord. Chem. Rev."},{"key":"2026090114394080200_cit4b","doi-asserted-by":"publisher","first-page":"3630","DOI":"10.1002\/anie.201001630","volume":"50","author":"Scharfe","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090114394080200_cit5a","doi-asserted-by":"crossref","first-page":"188","DOI":"10.1002\/3527602445.ch2e","volume-title":"Molecular clusters\nof the main group elements","author":"Wiberg","year":"2004"},{"key":"2026090114394080200_cit5b","doi-asserted-by":"publisher","first-page":"217","DOI":"10.1016\/S0010-8545(97)00012-X","volume":"163","author":"Wiberg","year":"1997","journal-title":"Coord. Chem. Rev."},{"key":"2026090114394080200_cit6","doi-asserted-by":"publisher","first-page":"745","DOI":"10.1039\/B516379J","volume":"36","author":"Schnepf","year":"2007","journal-title":"Chem. Soc. Rev."},{"key":"2026090114394080200_cit7a","doi-asserted-by":"publisher","first-page":"693","DOI":"10.1002\/(SICI)1099-0682(200004)2000:4&lt;693::AID-EJIC693&gt;3.0.CO;2-J","author":"Agustin","year":"2000","journal-title":"Eur. J. Inorg. Chem."},{"key":"2026090114394080200_cit7b","doi-asserted-by":"publisher","first-page":"445","DOI":"10.1002\/anie.200390135","volume":"42","author":"Filippou","year":"2003","journal-title":"Angew.\nChem., Int. Ed."},{"key":"2026090114394080200_cit7c","doi-asserted-by":"publisher","first-page":"5622","DOI":"10.1021\/om020583g","volume":"21","author":"Eichler","year":"2002","journal-title":"Organometallics"},{"key":"2026090114394080200_cit7d","doi-asserted-by":"publisher","first-page":"6316","DOI":"10.1021\/om200912x","volume":"30","author":"Lei","year":"2011","journal-title":"Organometallics"},{"key":"2026090114394080200_cit7e","doi-asserted-by":"publisher","first-page":"6695","DOI":"10.1002\/chem.201203511","volume":"19","author":"Wagner","year":"2013","journal-title":"Chem. - Eur. J."},{"key":"2026090114394080200_cit8","doi-asserted-by":"publisher","first-page":"767","DOI":"10.1002\/anie.197607671","volume":"15","author":"Jonas","year":"1976","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"2026090114394080200_cit9","doi-asserted-by":"publisher","first-page":"6132","DOI":"10.1002\/anie.200701353","volume":"46","author":"Brennessel","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090114394080200_cit10","doi-asserted-by":"publisher","first-page":"9076","DOI":"10.1021\/ic301240u","volume":"51","author":"Brennessel","year":"2012","journal-title":"Inorg. Chem."},{"key":"2026090114394080200_cit11","doi-asserted-by":"publisher","first-page":"3167","DOI":"10.1021\/ic052110i","volume":"45","author":"Ellis","year":"2006","journal-title":"Inorg. Chem."},{"key":"2026090114394080200_cit12","doi-asserted-by":"publisher","first-page":"12770","DOI":"10.1002\/chem.200901472","volume":"15","author":"Pyykko\u0308","year":"2009","journal-title":"Chem. - Eur. J."},{"key":"2026090114394080200_cit13","doi-asserted-by":"publisher","first-page":"265","DOI":"10.1016\/0022-328X(89)87114-1","volume":"363","author":"Puff","year":"1989","journal-title":"J. Organomet. Chem."},{"key":"2026090114394080200_cit14","doi-asserted-by":"publisher","first-page":"29","DOI":"10.1016\/0022-328X(93)80063-H","volume":"448","author":"Schneider-Koglin","year":"1993","journal-title":"J. Organomet. Chem."},{"key":"2026090114394080200_cit15","doi-asserted-by":"publisher","first-page":"9115","DOI":"10.1002\/anie.200802657","volume":"47","author":"Nguyen","year":"2008","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026090114394080200_cit16","doi-asserted-by":"publisher","first-page":"4798","DOI":"10.1021\/ja036308i","volume":"126","author":"Dai","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"2026090114394080200_cit17","doi-asserted-by":"publisher","first-page":"10205","DOI":"10.1021\/ic8015782","volume":"47","author":"Lei","year":"2008","journal-title":"Inorg. Chem."},{"key":"2026090114394080200_cit19a","doi-asserted-by":"publisher","first-page":"1060","DOI":"10.1039\/DT9730001060","author":"Weaver","year":"1973","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"2026090114394080200_cit19b","doi-asserted-by":"publisher","first-page":"257","DOI":"10.1016\/0022-328X(84)80196-5","volume":"267","author":"Curnow","year":"1984","journal-title":"J. Organomet. Chem."},{"key":"2026090114394080200_cit19c","doi-asserted-by":"publisher","first-page":"379","DOI":"10.1016\/0022-328X(90)85383-A","volume":"388","author":"Curnow","year":"1990","journal-title":"J. Organomet.\nChem."},{"key":"2026090114394080200_cit20a","doi-asserted-by":"publisher","first-page":"319","DOI":"10.1016\/0022-5088(86)90692-2","volume":"119","author":"Dwight","year":"1986","journal-title":"J. Less-Common\nMet."},{"key":"2026090114394080200_cit20b","doi-asserted-by":"publisher","first-page":"11127","DOI":"10.1088\/0953-8984\/6\/50\/020","volume":"6","author":"Go\u0308rlich","year":"1994","journal-title":"J. Phys.: Condens. Matter"},{"key":"2026090114394080200_cit21","doi-asserted-by":"publisher","first-page":"L3","DOI":"10.1016\/S0925-8388(99)00820-8","volume":"302","author":"Salamakha","year":"2000","journal-title":"J. Alloys Compd."},{"key":"2026090114394080200_cit22a","doi-asserted-by":"publisher","first-page":"12000","DOI":"10.1002\/chem.201201786","volume":"18","author":"Hlukhyy","year":"2012","journal-title":"Chem. - Eur. J."},{"key":"2026090114394080200_cit22b","doi-asserted-by":"publisher","first-page":"2864","DOI":"10.1002\/zaac.201400379","volume":"640","author":"He","year":"2014","journal-title":"Z. Anorg. Allg.\nChem."},{"key":"2026090114394080200_cit23a","doi-asserted-by":"publisher","first-page":"11626","DOI":"10.1021\/ja035711m","volume":"125","author":"Pu","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"2026090114394080200_cit23b","doi-asserted-by":"publisher","first-page":"13150","DOI":"10.1021\/ja1051236","volume":"132","author":"Wang","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"2026090114394080200_cit24a","doi-asserted-by":"publisher","first-page":"3098","DOI":"10.1103\/PhysRevA.38.3098","volume":"38","author":"Becke","year":"1988","journal-title":"Phys. Rev. A: At., Mol., Opt. Phys."},{"key":"2026090114394080200_cit24b","doi-asserted-by":"publisher","first-page":"8822","DOI":"10.1103\/PhysRevB.33.8822","volume":"33","author":"Perdew","year":"1986","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"2026090114394080200_cit24c","doi-asserted-by":"publisher","first-page":"5829","DOI":"10.1063\/1.467146","volume":"100","author":"Scha\u0308fer","year":"1994","journal-title":"J. Chem. Phys."},{"key":"2026090114394080200_cit24d","doi-asserted-by":"publisher","first-page":"1057","DOI":"10.1039\/b515623h","volume":"8","author":"Weigend","year":"2006","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2026090114394080200_cit24e","doi-asserted-by":"publisher","first-page":"1456","DOI":"10.1002\/jcc.21759","volume":"32","author":"Grimme","year":"2011","journal-title":"J. Comput. Chem."},{"key":"2026090114394080200_cit24f","doi-asserted-by":"publisher","first-page":"154104","DOI":"10.1063\/1.3382344","volume":"132","author":"Grimme","year":"2010","journal-title":"J. Chem. Phys."},{"key":"2026090114394080200_cit25a","doi-asserted-by":"publisher","first-page":"8943","DOI":"10.1063\/1.478813","volume":"110","author":"van Lenthe","year":"1999","journal-title":"J. Chem. Phys."},{"key":"2026090114394080200_cit25b","doi-asserted-by":"publisher","first-page":"403","DOI":"10.1080\/00268970010018431","volume":"99","author":"Handy","year":"2001","journal-title":"Mol.\nPhys."},{"key":"2026090114394080200_cit25c","doi-asserted-by":"publisher","first-page":"3865","DOI":"10.1103\/PhysRevLett.77.3865","volume":"77","author":"Perdew","year":"1996","journal-title":"Phys. Rev. Lett."},{"key":"2026090114394080200_cit25d","doi-asserted-by":"publisher","first-page":"2467","DOI":"10.1080\/0026897042000275017","volume":"102","author":"Swart","year":"2004","journal-title":"Mol. Phys."},{"key":"2026090114394080200_cit26a","doi-asserted-by":"publisher","first-page":"4576","DOI":"10.1103\/PhysRevB.60.4576","volume":"60","author":"Lippens","year":"1999","journal-title":"Phys. Rev. B: Condens. Matter\nMater. Phys."},{"key":"2026090114394080200_cit26b","doi-asserted-by":"publisher","first-page":"677","DOI":"10.1515\/znb-2006-0607","volume":"61","author":"Po\u0308ttgen","year":"2006","journal-title":"Z. Naturforsch.,\nB: J. Chem. Sci."},{"key":"2026090114394080200_cit27","doi-asserted-by":"publisher","first-page":"9132","DOI":"10.1021\/ic060983m","volume":"45","author":"Spikes","year":"2006","journal-title":"Inorg. Chem."},{"key":"2026090114394080200_cit28a","doi-asserted-by":"publisher","first-page":"700","DOI":"10.1002\/1521-3765(20020201)8:3&lt;700::AID-CHEM700&gt;3.0.CO;2-C","volume":"8","author":"Krossing","year":"2002","journal-title":"Chem. - Eur. J."},{"key":"2026090114394080200_cit28b","doi-asserted-by":"publisher","first-page":"1970","DOI":"10.1039\/c2cc15291f","volume":"48","author":"Forfar","year":"2012","journal-title":"Chem. Commun."},{"key":"2026090114394080200_cit28c","doi-asserted-by":"publisher","first-page":"4392","DOI":"10.1002\/anie.201411451","volume":"54","author":"Spitzer","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090114394080200_cit29","doi-asserted-by":"publisher","first-page":"8481","DOI":"10.1021\/ic101068a","volume":"49","author":"Merrill","year":"2010","journal-title":"Inorg. Chem."},{"key":"2026090114394080200_cit30","doi-asserted-by":"publisher","first-page":"5933","DOI":"10.1039\/C5DT03792A","volume":"45","author":"Krebs","year":"2016","journal-title":"Dalton. Trans."},{"key":"2026090114394080200_cit31","doi-asserted-by":"publisher","first-page":"7729","DOI":"10.1002\/anie.200502865","volume":"44","author":"Fox","year":"2005","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090114394080200_cit32a","doi-asserted-by":"publisher","first-page":"2321","DOI":"10.1002\/ejic.200300744","author":"Nikolova","year":"2004","journal-title":"Eur.\nJ. Inorg. Chem."},{"key":"2026090114394080200_cit32b","doi-asserted-by":"publisher","first-page":"1813","DOI":"10.1021\/om049177i","volume":"24","author":"Garci\u0301a","year":"2005","journal-title":"Organometallics"},{"key":"2026090114394080200_cit32c","doi-asserted-by":"publisher","first-page":"8854","DOI":"10.1002\/chem.201000656","volume":"16","author":"McPartlin","year":"2010","journal-title":"Chem. - Eur. J."},{"key":"2026090114394080200_cit32d","doi-asserted-by":"publisher","first-page":"1739","DOI":"10.1002\/zaac.201200116","volume":"638","author":"Almsta\u0308tter","year":"2012","journal-title":"Z. Anorg. Allg. Chem."},{"key":"2026090114394080200_cit32e","doi-asserted-by":"publisher","first-page":"1891","DOI":"10.1039\/C5DT03383G","volume":"45","author":"Velian","year":"2016","journal-title":"Dalton. Trans."},{"key":"2026090114394080200_cit33","doi-asserted-by":"publisher","first-page":"441","DOI":"10.1021\/j100785a001","volume":"68","author":"Bondi","year":"1964","journal-title":"J. Phys. Chem."},{"key":"2026090114394080200_cit34a","doi-asserted-by":"publisher","first-page":"1671","DOI":"10.1002\/anie.201610967","volume":"56","author":"Dielmann","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090114394080200_cit34b","doi-asserted-by":"publisher","first-page":"14592","DOI":"10.1021\/jacs.7b07704","volume":"139","author":"Hennersdorf","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"2026090114394080200_cit35a","doi-asserted-by":"publisher","first-page":"2331","DOI":"10.1016\/S0277-5387(99)00121-7","volume":"18","author":"Di Vaira","year":"1999","journal-title":"Polyhedron"},{"key":"2026090114394080200_cit35b","doi-asserted-by":"publisher","first-page":"732","DOI":"10.1002\/chem.19970030513","volume":"3","author":"Heinze","year":"1997","journal-title":"Chem. - Eur. J."},{"key":"2026090114394080200_cit36a","doi-asserted-by":"publisher","first-page":"5840","DOI":"10.1002\/chem.201705184","volume":"24","author":"Rinn","year":"2018","journal-title":"Chem. - Eur. J."},{"key":"2026090114394080200_cit36b","doi-asserted-by":"publisher","first-page":"4628","DOI":"10.1002\/chem.201406486","volume":"21","author":"Krebs","year":"2015","journal-title":"Chem. - Eur. J."},{"key":"2026090114394080200_cit36c","doi-asserted-by":"publisher","first-page":"4576","DOI":"10.1103\/PhysRevB.60.4576","volume":"60","author":"Lippens","year":"1999","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"2026090114394080200_cit37a","doi-asserted-by":"publisher","first-page":"11314","DOI":"10.1039\/C7CC07029B","volume":"53","author":"Binder","year":"2017","journal-title":"Chem. Commun."},{"key":"2026090114394080200_cit37b","doi-asserted-by":"publisher","first-page":"1022","DOI":"10.3390\/molecules23051022","volume":"23","author":"Binder","year":"2018","journal-title":"Molecules"},{"key":"2026090114394080200_cit37c","doi-asserted-by":"publisher","first-page":"8583","DOI":"10.1021\/ic3011647","volume":"51","author":"Schrenk","year":"2012","journal-title":"Inorg. Chem."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.8b08517","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/140\/41\/13195\/67497417\/jacs.8b08517.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/140\/41\/13195\/67497417\/jacs.8b08517.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T18:39:48Z","timestamp":1788287988000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/140\/41\/13195\/757854\/Synthesis-of-a-Cyclic-Co2Sn2-Cluster-Using-a-Co"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,10,1]]},"references-count":71,"journal-issue":{"issue":"41","published-online":{"date-parts":[[2018,10,1]]},"published-print":{"date-parts":[[2018,10,17]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.8b08517","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,10,1]]}}}