{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,30]],"date-time":"2026-10-30T09:57:52Z","timestamp":1793354272095,"version":"4.5.0"},"reference-count":92,"publisher":"American Chemical Society (ACS)","issue":"1","funder":[{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["CHE-1664799"],"award-info":[{"award-number":["CHE-1664799"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100004349","name":"BASF","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100004349","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000148","name":"Division of Electrical, Communications and Cyber Systems","doi-asserted-by":"publisher","award":["ECCS-1449291"],"award-info":[{"award-number":["ECCS-1449291"]}],"id":[{"id":"10.13039\/100000148","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000861","name":"Burroughs Wellcome Fund","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100000861","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["P41GM103393"],"award-info":[{"award-number":["P41GM103393"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2019,1,9]]},"DOI":"10.1021\/jacs.8b10775","type":"journal-article","created":{"date-parts":[[2018,12,4]],"date-time":"2018-12-04T19:02:33Z","timestamp":1543950153000},"page":"431-440","source":"Crossref","is-referenced-by-count":42,"title":["Anthracene as a Launchpad for a Phosphinidene Sulfide and for Generation of a Phosphorus\u2013Sulfur Material Having the Composition P<sub>2<\/sub>S, a Vulcanized Red Phosphorus That Is Yellow"],"prefix":"10.1021","volume":"141","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7445-5663","authenticated-orcid":true,"given":"Wesley J.","family":"Transue","sequence":"first","affiliation":[{"name":"Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthew","family":"Nava","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7094-1266","authenticated-orcid":true,"given":"Maxwell W.","family":"Terban","sequence":"additional","affiliation":[{"name":"Max Planck Institute for Solid State Research, Stuttgart 70569, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5081-3099","authenticated-orcid":true,"given":"Matthew W.","family":"Greenberg","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Columbia University, New York, New York 10027, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0936-9432","authenticated-orcid":true,"given":"Gang","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Queen\u2019s University, Kingston, Ontario K7L3N6, Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elizabeth S.","family":"Foreman","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chantal L.","family":"Mustoe","sequence":"additional","affiliation":[{"name":"Chemistry Department, University of British Columbia, Vancouver, British Columbia V6T1Z1, Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pierre","family":"Kennepohl","sequence":"additional","affiliation":[{"name":"Chemistry Department, University of British Columbia, Vancouver, British Columbia V6T1Z1, Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5502-3267","authenticated-orcid":true,"given":"Jonathan S.","family":"Owen","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Columbia University, New York, New York 10027, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Simon J. L.","family":"Billinge","sequence":"additional","affiliation":[{"name":"Department of Applied Physics & Applied Mathematics, Columbia University, New York, New York 10027, United States"},{"name":"Condensed Matter Physics and Materials Science Department, Brookhaven National Laboratory, Upton, New York 11973, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9342-0191","authenticated-orcid":true,"given":"Heather J.","family":"Kulik","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2568-3269","authenticated-orcid":true,"given":"Christopher C.","family":"Cummins","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2018,12,4]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)71146-4"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.5b00529"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1021\/jo00246a031"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1021\/ja306902j"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b05464"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b03910"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1804035115"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/ja507922x"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b10545"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC06516G"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC04506A"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/om500828n"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201611196"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201705198"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19951281212"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1246\/cl.1993.1715"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1080\/10426509908546235"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(99)00779-6"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1021\/ja00768a071"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1007\/BF00621420"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1524\/zpch.1966.49.1_2.022"},{"key":"ref22\/cit22","first-page":"4517","author":"Vincent H.","year":"1972","journal-title":"Bull. Soc. Chim. Fr."},{"key":"ref23\/cit23","first-page":"499","author":"Vincent H.","year":"1973","journal-title":"Bull. Soc. Chim. Fr., Partie 1"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1039\/dt9810001459"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.81"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.1327"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1063\/1.3382344"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.21759"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1063\/1.2148954"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198403201"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19871200727"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198803021"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19951280413"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1021\/om050617v"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1021\/om020933z"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT02648C"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200901472"},{"key":"ref38\/cit38","volume-title":"NBO 6.0","author":"Glendening E. D.","year":"2013"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.48.3733"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/jo00335a013"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)86268-1"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1021\/ja00047a034"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1046\/j.1365-8711.2001.04429.x"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1063\/1.3562374"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1063\/1.4827099"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19971300607"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1055\/sos-SD-040-00445"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19891220310"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1021\/om950979a"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1039\/B608276A"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1063\/1.4827520"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC03000F"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1021\/j100154a018"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1016\/0166-1280(82)80195-4"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1021\/cr000039m"},{"key":"ref57\/cit57","first-page":"165","volume":"135","author":"Boulouch R.","year":"1902","journal-title":"Compt. Rend."},{"key":"ref58\/cit58","first-page":"1029","author":"Monteil Y.","year":"1975","journal-title":"Bull. Soc. Chim. Fr., Partie 1"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19794570110"},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.1007\/BF02645186"},{"key":"ref61\/cit61","unstructured":"Schneider, A.; F\u00f6rthmann, R. Process for the manufacture of tetraphosphorus disulfide. US3387936A, 1968."},{"key":"ref62\/cit62","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1976-0520"},{"key":"ref63\/cit63","doi-asserted-by":"publisher","DOI":"10.1016\/0584-8539(67)80153-3"},{"key":"ref64\/cit64","volume-title":"The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules","author":"Lin-Vien D.","year":"1991"},{"key":"ref65\/cit65","doi-asserted-by":"publisher","DOI":"10.1021\/ic50005a049"},{"key":"ref66\/cit66","doi-asserted-by":"publisher","DOI":"10.1002\/jrs.1250190508"},{"key":"ref67\/cit67","doi-asserted-by":"publisher","DOI":"10.1016\/0038-1098(84)90833-0"},{"key":"ref68\/cit68","doi-asserted-by":"publisher","DOI":"10.1007\/BF01729950"},{"key":"ref69\/cit69","doi-asserted-by":"publisher","DOI":"10.1021\/j100338a086"},{"key":"ref70\/cit70","doi-asserted-by":"publisher","DOI":"10.1039\/b919118f"},{"key":"ref71\/cit71","doi-asserted-by":"publisher","DOI":"10.1039\/dt9890000809"},{"key":"ref72\/cit72","doi-asserted-by":"publisher","DOI":"10.1021\/j100360a032"},{"key":"ref73\/cit73","doi-asserted-by":"publisher","DOI":"10.1021\/j100368a075"},{"key":"ref74\/cit74","doi-asserted-by":"publisher","DOI":"10.1063\/1.1677259"},{"key":"ref75\/cit75","doi-asserted-by":"publisher","DOI":"10.1021\/j100700a027"},{"key":"ref76\/cit76","first-page":"2166","volume":"61","author":"Klimov V. D.","year":"1991","journal-title":"Zh. Obshch. Khim."},{"key":"ref78\/cit78","doi-asserted-by":"publisher","DOI":"10.1016\/0368-2048(94)02129-5"},{"key":"ref79\/cit79","doi-asserted-by":"publisher","DOI":"10.1002\/macp.1994.021950524"},{"key":"ref80\/cit80","doi-asserted-by":"publisher","DOI":"10.1111\/maps.12811"},{"key":"ref81\/cit81","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200601885"},{"key":"ref82\/cit82","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740869001853"},{"key":"ref83\/cit83","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.218.2.132.20664"},{"key":"ref84\/cit84","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19946201028"},{"key":"ref85\/cit85","doi-asserted-by":"publisher","DOI":"10.1016\/0022-3093(88)90225-6"},{"key":"ref86\/cit86","doi-asserted-by":"publisher","DOI":"10.1016\/0022-3093(89)90059-8"},{"key":"ref87\/cit87","unstructured":"Verrall, D. J.; Elliott, S. R. Neutron and X-ray Scattering: Complementary Techniques; Institute of Physics Conference Series; IOP Publishing Ltd.: Canterbury, England, 1990; Vol. 101; pp 87\u201395."},{"key":"ref88\/cit88","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.63.2574"},{"key":"ref89\/cit89","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(96)00758-0"},{"key":"ref90\/cit90","doi-asserted-by":"publisher","DOI":"10.1080\/00268970009483339"},{"key":"ref91\/cit91","doi-asserted-by":"crossref","unstructured":"Morigaki, K.; Kugler, S.; Shimakawa, K. Amorphous Semiconductors; Materials for Electronic and Optoelectronic Applications; Wiley-Blackwell: West Sussex, UK, 2017; pp 157\u2013229.","DOI":"10.1002\/9781118758236"},{"key":"ref92\/cit92","doi-asserted-by":"crossref","unstructured":"Madelung, O. Semiconductors: Data Handbook; Springer, Berlin, 2004; pp 613\u2013633.","DOI":"10.1007\/978-3-642-18865-7_26"},{"key":"ref93\/cit93","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC09003J"},{"key":"ref94\/cit94","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201603331"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.8b10775","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,28]],"date-time":"2023-04-28T01:12:20Z","timestamp":1682644340000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.8b10775"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,12,4]]},"references-count":92,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2019,1,9]]}},"alternative-id":["10.1021\/jacs.8b10775"],"URL":"https:\/\/doi.org\/10.1021\/jacs.8b10775","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,12,4]]}}}