{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,26]],"date-time":"2026-02-26T19:20:31Z","timestamp":1772133631786,"version":"3.50.1"},"reference-count":50,"publisher":"American Chemical Society (ACS)","issue":"3","license":[{"start":{"date-parts":[[2019,12,12]],"date-time":"2019-12-12T00:00:00Z","timestamp":1576108800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2019,12,12]],"date-time":"2019-12-12T00:00:00Z","timestamp":1576108800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2019,12,12]],"date-time":"2019-12-12T00:00:00Z","timestamp":1576108800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["EXC 2008\/1 ? 390540038"],"award-info":[{"award-number":["EXC 2008\/1 ? 390540038"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["LE 2934\/1-1"],"award-info":[{"award-number":["LE 2934\/1-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["SPP 1927"],"award-info":[{"award-number":["SPP 1927"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006188","name":"Einstein Stiftung Berlin","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100006188","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2020,1,22]]},"DOI":"10.1021\/jacs.9b11506","type":"journal-article","created":{"date-parts":[[2019,12,12]],"date-time":"2019-12-12T18:30:35Z","timestamp":1576175435000},"page":"1457-1464","source":"Crossref","is-referenced-by-count":29,"title":["Formyltetrahydrofolate Decarbonylase Synthesizes the Active Site CO Ligand of O\n                    <sub>2<\/sub>\n                    -Tolerant [NiFe] Hydrogenase"],"prefix":"10.1021","volume":"142","author":[{"given":"Anne-Christine","family":"Schulz","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie, Physikalische Chemie, Technische Universit\u00e4t Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4141-7836","authenticated-orcid":true,"given":"Stefan","family":"Frielingsdorf","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie, Physikalische Chemie, Technische Universit\u00e4t Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2595-9448","authenticated-orcid":true,"given":"Phillip","family":"Pommerening","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie, Organische Chemie, Technische Universit\u00e4t Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6601-6473","authenticated-orcid":true,"given":"Lars","family":"Lauterbach","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie, Physikalische Chemie, Technische Universit\u00e4t Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4849-1323","authenticated-orcid":true,"given":"Giovanni","family":"Bistoni","sequence":"additional","affiliation":[{"name":"Department of Molecular Theory and Spectroscopy, Max Planck Institut f\u00fcr Kohlenforschung, Kaiser-Wilhelm Platz 1, 45470 M\u00fclheim an der Ruhr, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4691-0547","authenticated-orcid":true,"given":"Frank","family":"Neese","sequence":"additional","affiliation":[{"name":"Department of Molecular Theory and Spectroscopy, Max Planck Institut f\u00fcr Kohlenforschung, Kaiser-Wilhelm Platz 1, 45470 M\u00fclheim an der Ruhr, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1487-9218","authenticated-orcid":true,"given":"Martin","family":"Oestreich","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie, Organische Chemie, Technische Universit\u00e4t Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4550-5128","authenticated-orcid":true,"given":"Oliver","family":"Lenz","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie, Physikalische Chemie, Technische Universit\u00e4t Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2019,12,12]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1021\/cr4005814"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1016\/S0065-2911(06)51001-X"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1039\/C6FD00209A"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1126\/science.1241859"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1126\/science.1080972"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1016\/j.febslet.2007.06.028"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.M112.376947"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/bi400302v"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1007\/s10534-019-00173-9"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.M111.309351"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1016\/j.febslet.2013.06.055"},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"61","DOI":"10.1515\/9783110336733.61","volume-title":"Biohydrogen","author":"Lenz O.","year":"2015"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1007\/s002030050667"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1614656113"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1007\/BF02173769"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1038\/s42003-019-0631-z"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1128\/JB.182.10.2716-2724.2000"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1038\/nbt1183-784"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1016\/S1389-1723(00)88049-4"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/acs.biochem.8b00760"},{"key":"ref21\/cit21","volume-title":"Hemoglobin and myoglobin in their reactions with ligands","author":"Antonini E.","year":"1971"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/ja1012273"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1038\/nchembio.1311"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1107\/S1399004715002928"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.M313934200"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.M707627200"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1016\/j.pep.2010.04.003"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1016\/j.cbi.2008.09.007"},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"24728","DOI":"10.1016\/S0021-9258(17)31452-7","volume":"269","author":"Schirch D.","year":"1994","journal-title":"J. Biol. Chem."},{"key":"ref30\/cit30","unstructured":"Buhrke, T. Der H\n                      2\n                      -Sensor von\n                      Ralstonia eutropha\n                      : Struktur-Funktions-Beziehungen einer neuartigen [NiFe]-Hydrogenase. Ph.D. Thesis, Humboldt-Universit\u00e4t zu Berlin, Berlin, 2002."},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1007\/s00018-008-8082-6"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1006\/jmbi.2001.4671"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.21759"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1021\/j100096a001"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.81"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1063\/1.4939030"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1371\/journal.pone.0045850"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1111\/febs.14664"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1007\/978-94-017-9269-1_3"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/cr400461p"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1016\/j.bbrc.2005.08.020"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1016\/S0006-291X(71)80076-1"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1111\/j.1574-6968.1994.tb06783.x"},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"21466","DOI":"10.1016\/S0021-9258(20)80559-6","volume":"268","author":"Wray J. W.","year":"1993","journal-title":"J. Biol. Chem."},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1021\/cs400637t"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201003419"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1093\/nar\/25.17.3389"},{"key":"ref50\/cit50","doi-asserted-by":"crossref","first-page":"698","DOI":"10.1242\/jeb.37.4.698","volume":"37","author":"Wittenberg J. B.","year":"1960","journal-title":"J. Exp. Biol."},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1126\/science.144.3620.860"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1016\/0010-406X(66)90344-6"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.9b11506","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,16]],"date-time":"2023-04-16T22:18:54Z","timestamp":1681683534000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.9b11506"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,12,12]]},"references-count":50,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2020,1,22]]}},"alternative-id":["10.1021\/jacs.9b11506"],"URL":"https:\/\/doi.org\/10.1021\/jacs.9b11506","relation":{"has-review":[{"id-type":"doi","id":"10.3410\/f.737076140.793570738","asserted-by":"object"}]},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,12,12]]}}}