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Here, we report the first combined catalyst system composed of hydrotalcite-supported palladium and solid acid aluminum-exchanged montmorillonite for the direct alkylation of benzene promoted by slurry-phase interparticle hydrogen transfer at 150 \u00b0C. The combination of the two catalytic particles showed excellent activity and achieved the maximum benzene conversion of 21% and target product selectivity of 84% in the reaction of n-heptane and benzene. Our results, thus, provide a feasible strategy to design efficient liquid-phase reaction systems employing simple physical mixing of two catalytic particles.<\/jats:p>","DOI":"10.1021\/jacsau.0c00070","type":"journal-article","created":{"date-parts":[[2021,1,20]],"date-time":"2021-01-20T14:41:33Z","timestamp":1611153693000},"page":"124-129","source":"Crossref","is-referenced-by-count":32,"title":["Dehydrogenative Coupling of Alkanes and Benzene Enhanced\nby Slurry-Phase Interparticle Hydrogen Transfer"],"prefix":"10.1021","volume":"1","author":[{"given":"Moe","family":"Takabatake","sequence":"first","affiliation":[{"name":"Tokyo Institute of Technology , , ,","place":["Yokohama, Japan, 226-8502"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ayako","family":"Hashimoto","sequence":"additional","affiliation":[{"name":"National Institute for Materials Science , , ,","place":["Tsukuba, Japan, 305-0047"]},{"name":"Japan Science and Technology Agency (JST) , , ,","place":["Saitama, Japan, 332-0012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4084-3603","authenticated-orcid":true,"given":"Wang-Jae","family":"Chun","sequence":"additional","affiliation":[{"name":"International Christian University , , ,","place":["Tokyo, Japan, 181-8585"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masayuki","family":"Nambo","sequence":"additional","affiliation":[{"name":"Tokyo Institute of Technology , , ,","place":["Yokohama, Japan, 226-8502"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuichi","family":"Manaka","sequence":"additional","affiliation":[{"name":"Tokyo Institute of Technology , , ,","place":["Yokohama, Japan, 226-8502"]},{"name":"National Institute of Advanced Industrial Science and Technology (AIST) , , ,","place":["Fukushima, Japan, 963-0298"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0066-5139","authenticated-orcid":true,"given":"Ken","family":"Motokura","sequence":"additional","affiliation":[{"name":"Tokyo Institute of Technology , , ,","place":["Yokohama, Japan, 226-8502"]},{"name":"Japan Science and Technology Agency (JST) , , ,","place":["Saitama, Japan, 332-0012"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2021,1,20]]},"reference":[{"key":"2026090122214246800_cit1","doi-asserted-by":"publisher","first-page":"494","DOI":"10.1016\/j.apcatb.2017.05.085","article-title":"Recent Progress for Direct Synthesis\nof Dimethyl Ether from Syngas on the Heterogeneous Bifunctional Hybrid\nCatalysts","volume":"217","author":"Saravanan","year":"2017","journal-title":"Appl. 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Am. Chem. Soc."},{"key":"2026090122214246800_cit8","doi-asserted-by":"publisher","first-page":"11549","DOI":"10.1002\/chem.201402545","article-title":"Palladium Nanoparticles Bonded to Two-Dimensional Iron Oxide Graphene\nNanosheets: A Synergistic and Highly Reusable Catalyst for the Tsuji-Trost\nReaction in Water and Air","volume":"20","author":"Liu","year":"2014","journal-title":"Chem. - Eur. J."},{"key":"2026090122214246800_cit9","doi-asserted-by":"publisher","first-page":"19","DOI":"10.1016\/j.jcat.2015.02.011","article-title":"Spatial\nArrangement and Acid Strength Effects on Acid-Base\nCooperatively Catalyzed Aldol Condensation on Aminosilica Materials","volume":"325","author":"Lauwaert","year":"2015","journal-title":"J. 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A: Chem."},{"key":"2026090122214246800_cit30","doi-asserted-by":"publisher","first-page":"278","DOI":"10.1016\/j.micromeso.2007.05.002","article-title":"Influence\nof Aluminum\nContent, Crystallinity and Crystallite Size of Zeolite Pd\/H-ZSM-5\non the Catalytic Performance in the Dehydroalkylation of Toluene with\nEthane","volume":"109","author":"Bressel","year":"2008","journal-title":"Microporous Mesoporous Mater."},{"key":"2026090122214246800_cit31","doi-asserted-by":"publisher","first-page":"681","DOI":"10.1002\/cctc.201100445","article-title":"Dehydroalkylation of\nBenzene with Ethane over Pt\/H-MFI in the Presence of Hydrogen Scavengers","volume":"4","author":"Ordomskiy","year":"2012","journal-title":"ChemCatChem"},{"key":"2026090122214246800_cit32","doi-asserted-by":"publisher","first-page":"81","DOI":"10.1016\/0926-860X(92)85067-L","article-title":"Hydrosiomerization of n-pentane over hybrid catalysts containing a supported hydrogenation\ncatalyst","volume":"91","author":"Fujimoto","year":"1992","journal-title":"Appl. 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Soc."},{"key":"2026090122214246800_cit43","doi-asserted-by":"publisher","first-page":"1361","DOI":"10.1039\/C8GC03391A","article-title":"Design of High-Performance Heterogeneous Catalysts\nUsing Hydrotalcite for Selective Organic Transformations","volume":"21","author":"Kaneda","year":"2019","journal-title":"Green Chem."},{"key":"2026090122214246800_cit44","doi-asserted-by":"publisher","first-page":"8228","DOI":"10.1002\/chem.200600317","article-title":"Environmentally Friendly One-Pot\nSynthesis of a-Alkylated Nitriles Using Hydrotalcite-Supported Metal\nSpecies as Multifunctional Solid Catalysts","volume":"12","author":"Motokura","year":"2006","journal-title":"Chem. - Eur. J."},{"key":"2026090122214246800_cit45","doi-asserted-by":"publisher","first-page":"3107","DOI":"10.1021\/jo991868e","article-title":"Tandem One-Pot Palladium-Catalyzed\nReductive and Oxidative Coupling of Benzene and Chlorobenzene","volume":"65","author":"Mukhopadhyay","year":"2000","journal-title":"J. Org. Chem."},{"key":"2026090122214246800_cit46","doi-asserted-by":"publisher","first-page":"2714","DOI":"10.1021\/cr200346z","article-title":"Hydrogen Spillover.\nFacts and Fiction","volume":"112","author":"Prins","year":"2012","journal-title":"Chem. Rev."},{"key":"2026090122214246800_cit47","doi-asserted-by":"publisher","first-page":"197","DOI":"10.1007\/BF02066968","article-title":"Influence\nof the Liquid Phase Vapor\nPressure on the Hydrogen Spillover","volume":"56","author":"Kildibekova","year":"1995","journal-title":"React. Kinet.\nCatal. Lett."},{"key":"2026090122214246800_cit48","doi-asserted-by":"publisher","first-page":"4273","DOI":"10.1021\/jp105923a","article-title":"Effect of Surface\nOxygen Groups and Water on Hydrogen\nSpillover in Pt-Doped Activated Carbon","volume":"115","author":"Li","year":"2011","journal-title":"J. Phys.\nChem. C"},{"key":"2026090122214246800_cit49","doi-asserted-by":"publisher","first-page":"7876","DOI":"10.1021\/acscatal.9b01425","article-title":"Understanding\nHeterolytic H2 Cleavage and Water-Assisted Hydrogen Spillover\non Fe3O4(001)-Supported Single Palladium Atoms","volume":"9","author":"Doudin","year":"2019","journal-title":"ACS Catal."},{"key":"2026090122214246800_cit50","doi-asserted-by":"publisher","first-page":"68","DOI":"10.1038\/nature20782","article-title":"Catalyst\nSupport Effects on Hydrogen\nSpillover","volume":"541","author":"Karim","year":"2017","journal-title":"Nature"}],"container-title":["JACS Au"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacsau.0c00070","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jaaucr\/article-pdf\/1\/2\/124\/12307238\/au0c00070.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jaaucr\/article-pdf\/1\/2\/124\/12307238\/au0c00070.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T02:21:48Z","timestamp":1788315708000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jaaucr\/article\/1\/2\/124\/1268074\/Dehydrogenative-Coupling-of-Alkanes-and-Benzene"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,1,20]]},"references-count":50,"journal-issue":{"issue":"2","published-online":{"date-parts":[[2021,1,20]]},"published-print":{"date-parts":[[2021,2,22]]}},"URL":"https:\/\/doi.org\/10.1021\/jacsau.0c00070","relation":{},"ISSN":["2691-3704"],"issn-type":[{"value":"2691-3704","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,1,20]]}}}