{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T04:58:40Z","timestamp":1785473920178,"version":"3.56.0"},"reference-count":50,"publisher":"American Chemical Society (ACS)","issue":"7","license":[{"start":{"date-parts":[[2026,6,11]],"date-time":"2026-06-11T00:00:00Z","timestamp":1781136000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100010127","name":"J?rgen Manchot Stiftung","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/100010127","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"German Research Council","doi-asserted-by":"publisher","award":["EXC-2033-390677874-RE-SOLV"],"award-info":[{"award-number":["EXC-2033-390677874-RE-SOLV"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"German Research Council","doi-asserted-by":"publisher","award":["Ga 619\/13-3"],"award-info":[{"award-number":["Ga 619\/13-3"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,7,27]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Here, we describe the merging of titanocene-catalyzed radical arylation with electro-organic synthesis that combines the advantages of both fields. The critical mechanistic issue of the titanocene-catalyzed radical arylation, the efficiency of rearomatization by a proton-coupled electron transfer, can be efficiently resolved via a radical polar crossover. This is achieved in a unique manner by consecutive paired galvanostatic electrolysis through a decoupling of the electron and proton transfer steps by spatially separating the critical redox processes, the anodic oxidation of the radical \u03c3-complex to the cationic \u03c3-complex, and the mild in situ preparation of the active catalyst by cathodic reduction of Cp2TiCl2.<\/jats:p>","DOI":"10.1021\/jacsau.6c00215","type":"journal-article","created":{"date-parts":[[2026,6,11]],"date-time":"2026-06-11T15:37:58Z","timestamp":1781192278000},"page":"3694-3702","source":"Crossref","is-referenced-by-count":0,"title":["Generalization of\nTitanocene-Catalyzed Arylation of\nEpoxides through Radical Polar Crossover by Consecutive Paired Electrolysis"],"prefix":"10.1021","volume":"6","author":[{"given":"Niklas","family":"Schmickler","sequence":"first","affiliation":[{"name":"Universita\u0308t Bonn , , Gerhard-Domagk-Stra\u00dfe 1 , ,","place":["Bonn, Germany, 53121"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Darryl F.","family":"Nater","sequence":"additional","affiliation":[{"name":"Waldvogel Max-Planck-Institute for Chemical Energy Conversion , , Stiftstra\u00dfe 34\u221236 , ,","place":["Mu\u0308lheim an der Ruhr, Germany, 45470"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7949-9638","authenticated-orcid":true,"given":"Siegfried R.","family":"Waldvogel","sequence":"additional","affiliation":[{"name":"Waldvogel Max-Planck-Institute for Chemical Energy Conversion , , Stiftstra\u00dfe 34\u221236 , ,","place":["Mu\u0308lheim an der Ruhr, Germany, 45470"]},{"name":"Karlsruhe Institute of Technology , , Kaiserstra\u00dfe 12 , ,","place":["Karlsruhe, Germany, 76131"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2622-6369","authenticated-orcid":true,"given":"Andreas","family":"Gansa\u0308uer","sequence":"additional","affiliation":[{"name":"Universita\u0308t Bonn , , Gerhard-Domagk-Stra\u00dfe 1 , ,","place":["Bonn, Germany, 53121"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,6,11]]},"reference":[{"key":"2026073100174230400_cit1a","doi-asserted-by":"publisher","first-page":"12386","DOI":"10.1039\/D0SC01848A","article-title":"Electro-organic synthesis \u2013\na 21st century technique","volume":"11","author":"Pollok","year":"2020","journal-title":"Chem. 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