{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T04:13:35Z","timestamp":1788149615036,"version":"build-2803163510"},"reference-count":111,"publisher":"American Chemical Society (ACS)","issue":"8","license":[{"start":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T00:00:00Z","timestamp":1785110400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,24]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Arene ring-opening (ARO) reaction via C\u2013C bond cleavage remains a formidable challenge due to the exceptional thermodynamic stability of aromatic frameworks. Inspired by enzymatic lignin degradation in nature, we report an oxidative strategy that enables arene ring-opening of benzylic alcohols under mild conditions. Using hydrogen peroxide as oxidant and 2-nitro-4-(trifluoromethyl)benzeneseleninic acid as the catalyst, we achieved the efficient conversion of benzylic alcohols into muconolactone or muconic acid derivatives, which contain multiple functional handles enabling diverse downstream derivatizations. Both of the exocyclic C\u2013C bonds and the arene ring C\u2013C bonds in benzylic alcohols were cleaved through the present Se-catalytic tandem oxidation and rearrangement processes.<\/jats:p>","DOI":"10.1021\/jacsau.6c00681","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T13:09:47Z","timestamp":1785848987000},"page":"4572-4581","source":"Crossref","is-referenced-by-count":0,"title":["Oxidative Arene Ring-Opening\nof Benzylic Alcohols"],"prefix":"10.1021","volume":"6","author":[{"given":"Ming-Hui","family":"Zhu","sequence":"first","affiliation":[{"name":"Peking University , , ,","place":["Beijing, China, 100191"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zengrui","family":"Cheng","sequence":"additional","affiliation":[{"name":"Peking University , , ,","place":["Beijing, China, 100191"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen-Jie","family":"Shen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences , ,","place":["Shanghai, China, 200032"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yilei","family":"Huang","sequence":"additional","affiliation":[{"name":"Peking University , , ,","place":["Beijing, China, 100191"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6782-327X","authenticated-orcid":true,"given":"Zhibin","family":"Hu","sequence":"additional","affiliation":[{"name":"Peking University , , ,","place":["Beijing, China, 100191"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4586-8359","authenticated-orcid":true,"given":"Shu-Li","family":"You","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences , ,","place":["Shanghai, China, 200032"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0290-9034","authenticated-orcid":true,"given":"Ning","family":"Jiao","sequence":"additional","affiliation":[{"name":"Peking University , , ,","place":["Beijing, China, 100191"]},{"name":"State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences , ,","place":["Shanghai, China, 200032"]},{"name":"Laboratory for Synthetic Chemistry and Chemical Biology Limited, Health@InnoHK, Innovation and Technology Commission , Units 1503-1511, 15\/F., Building 17W , , ,","place":["Kowloon, Hong Kong SAR, China, 999077"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,27]]},"reference":[{"key":"2026083023162585000_cit1","doi-asserted-by":"publisher","first-page":"2305","DOI":"10.1039\/C4CS00496E","article-title":"Substitution of alcohols by N-nucleophiles\nvia transition metal-catalyzed dehydrogenation","volume":"44","author":"Yang","year":"2015","journal-title":"Chem. 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