{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:47:33Z","timestamp":1792784853104,"version":"4.5.0"},"reference-count":54,"publisher":"American Chemical Society (ACS)","issue":"9","license":[{"start":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T00:00:00Z","timestamp":1786665600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"name":"Anusandhan National Research Foundation (ANRF), Government of India","award":["CRG\/2023\/003045"],"award-info":[{"award-number":["CRG\/2023\/003045"]}],"id":[{"id":"https:\/\/ror.org\/036h6g940","id-type":"ROR","asserted-by":"crossref"}]},{"name":"DST-FIST","award":["SR\/FST\/CS-I\/2020\/158"],"award-info":[{"award-number":["SR\/FST\/CS-I\/2020\/158"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,28]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Electricity-controlled, diversity-oriented selective synthesis is a powerful strategy for accessing structurally distinct potential organic molecules. However, achieving this transformation remains a significant challenge in synthetic chemistry. Herein, we report a metal- and external-oxidant-free electrochemical strategy that enables the highly selective synthesis of CF3-tethered pyrazolines and pyrazoles (&amp;gt;45 examples) from readily available N-allyl-N\u2019-benzylidenesulfonohydrazides and CF3SO2Na. This protocol operates via a tandem sequence involving regioselective radical trifluoromethylation, annulation, and oxidation. Notably, precise control over product selectivity is achieved simply by modulating the applied current under constant-current electrolysis conditions. As a result, N-sulfonyl pyrazolines, N-sulfonyl pyrazoles, and N\u2013H pyrazoles are selectively synthesized from the same starting materials. The method features broad substrate scope and functional-group tolerance, including derivatives of fragrances, pharmaceuticals, and natural products. Electricity serves as the sole reagent, with H2 as a benign byproduct, demonstrating the protocol\u2019s high sustainability. Mechanistic investigations support a radical-mediated pathway involving a \u2022CF3-radical. Interestingly, electron-rich heteroaryl-substituted sulfonohydrazides preferentially undergo C\u2013H trifluoromethylation of the heteroaryl moiety rather than annulation. This observation highlights the differential reactivity of the \u2022CF3 radical toward (hetero)aryl-substituted N-allylsulfonohydrazides.<\/jats:p>","DOI":"10.1021\/jacsau.6c00788","type":"journal-article","created":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T22:01:25Z","timestamp":1786744885000},"page":"5118-5129","source":"Crossref","is-referenced-by-count":1,"title":["Electricity-Controlled\nDivergent Synthesis of CF3-Tethered Pyrazolines\nand Pyrazoles via Tandem Radical\nTrifluoromethylation and Annulation"],"prefix":"10.1021","volume":"6","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7939-5241","authenticated-orcid":true,"given":"Paramita","family":"Pattanayak","sequence":"first","affiliation":[{"name":"Birla Institute of Technology and Science, Pilani , , Hyderabad Campus, Jawahar Nagar, Kapra Mandal , , ,","place":["Hyderabad, Telangana, India, 500078"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yogesh K.","family":"Girase","sequence":"additional","affiliation":[{"name":"Birla Institute of Technology and Science, Pilani , , Hyderabad Campus, Jawahar Nagar, Kapra Mandal , , ,","place":["Hyderabad, Telangana, India, 500078"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6342-0166","authenticated-orcid":true,"given":"Tanmay","family":"Chatterjee","sequence":"additional","affiliation":[{"name":"Birla Institute of Technology and Science, Pilani , , Hyderabad Campus, Jawahar Nagar, Kapra Mandal , , ,","place":["Hyderabad, Telangana, India, 500078"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,14]]},"reference":[{"key":"2026092808084514900_cit1","doi-asserted-by":"publisher","first-page":"44247","DOI":"10.1039\/D0RA09198G","article-title":"Prescribed Drugs Containing Nitrogen Heterocycles:\nAn Overview","volume":"10","author":"Heravi","year":"2020","journal-title":"RSC Adv."},{"key":"2026092808084514900_cit2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2024.116838","article-title":"Nitrogen-Containing Heterocyclic\nDrug Products Approved by the FDA in 2023: Synthesis and Biological\nActivity","volume":"279","author":"Luo","year":"2024","journal-title":"Eur. 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