{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T23:14:24Z","timestamp":1788477264905,"version":"build-2803163510"},"reference-count":43,"publisher":"American Chemical Society (ACS)","issue":"23","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Org. Chem."],"published-print":{"date-parts":[[2002,11,1]]},"DOI":"10.1021\/jo025581k","type":"journal-article","created":{"date-parts":[[2002,11,8]],"date-time":"2002-11-08T05:54:33Z","timestamp":1036734873000},"page":"7937-7945","source":"Crossref","is-referenced-by-count":43,"title":["Model Compound Studies of the \u03b2-O-4 Linkage in Lignin:\u2009 Absolute Rate Expressions for \u03b2-Scission of Phenoxyl Radical from 1-Phenyl-2-phenoxyethanol-1-yl Radical"],"prefix":"10.1021","volume":"67","author":[{"given":"Pramod H.","family":"Kandanarachchi","sequence":"first","affiliation":[{"name":"Pacific Northwest National Laboratory, Fundamental Science Division, 902 Battelle Boulevard, Richland, Washington 99352"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tom","family":"Autrey","sequence":"additional","affiliation":[{"name":"Pacific Northwest National Laboratory, Fundamental Science Division, 902 Battelle Boulevard, Richland, Washington 99352"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"James A.","family":"Franz","sequence":"additional","affiliation":[{"name":"Pacific Northwest National Laboratory, Fundamental Science Division, 902 Battelle Boulevard, Richland, Washington 99352"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2002,10,25]]},"reference":[{"key":"jo025581kb00001\/jo025581kb00001_1","volume-title":"The Chemistry of Lignin","author":"Pearl I. A.","year":"1967"},{"key":"jo025581kb00001\/jo025581kb00001_2","doi-asserted-by":"crossref","first-page":"169","DOI":"10.1007\/BF00365615","volume":"11","author":"Adler E.","year":"1977","journal-title":"Wood Sci. Technol."},{"key":"jo025581kb00002\/jo025581kb00002_1","doi-asserted-by":"crossref","first-page":"1376","DOI":"10.1021\/jo991479k","volume":"65","author":"Britt P. F.","year":"2000","journal-title":"J. Org. Chem."},{"key":"jo025581kb00003\/jo025581kb00003_1","doi-asserted-by":"crossref","first-page":"153","DOI":"10.1016\/S0165-2370(99)00082-0","volume":"54","author":"Dorrestigin E.","year":"2000","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"jo025581kb00003\/jo025581kb00003_2","first-page":"7","volume":"1267","author":"Dorrestijin E.","year":"1999","journal-title":"Eur. J. Org. Chem."},{"key":"jo025581kb00004\/jo025581kb00004_1","doi-asserted-by":"crossref","first-page":"2079","DOI":"10.1139\/v95-256","volume":"73","author":"Huang D.","year":"1995","journal-title":"Can. J. Chem."},{"key":"jo025581kb00005\/jo025581kb00005_1","doi-asserted-by":"crossref","first-page":"104","DOI":"10.1139\/v91-016","volume":"69","author":"Johnston L. J.","year":"1991","journal-title":"Can. J. Chem."},{"key":"jo025581kb00006\/jo025581kb00006_1","doi-asserted-by":"crossref","first-page":"397","DOI":"10.1080\/02773819108051083","volume":"11","author":"Schmidt J. A.","year":"1991","journal-title":"J. Wood. Chem. Technol."},{"key":"jo025581kb00007\/jo025581kb00007_1","doi-asserted-by":"crossref","first-page":"397","DOI":"10.1080\/02773819308020520","volume":"13","author":"Schmidt J. A.","year":"1993","journal-title":"J. Wood. Chem. Technol."},{"key":"jo025581kb00008\/jo025581kb00008_1","doi-asserted-by":"crossref","first-page":"271","DOI":"10.1163\/156856792X00182","volume":"17","author":"Shkrob I. A.","year":"1992","journal-title":"Res. Chem. Intermed."},{"key":"jo025581kb00009\/jo025581kb00009_1","doi-asserted-by":"crossref","first-page":"263","DOI":"10.1007\/BF03052257","volume":"9","author":"Argyropoulos D. S.","year":"1995","journal-title":"Res. Chem. Intermed."},{"key":"jo025581kb00010\/jo025581kb00010_1","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1163\/156856792X00056","volume":"17","author":"Wan J. K. S.","year":"1992","journal-title":"Res. Chem. Intermed."},{"key":"jo025581kb00011\/jo025581kb00011_1","doi-asserted-by":"crossref","unstructured":"Scaiano, J. C.; Netto-Ferreira, J. C.; Wintgens, V.J. Photochem. Phtobiol.A:\u2009 Chem.1991,59, 265.","DOI":"10.1016\/1010-6030(91)87014-M"},{"key":"jo025581kb00012\/jo025581kb00012_1","doi-asserted-by":"crossref","first-page":"2197","DOI":"10.1021\/jo00006a043","volume":"56","author":"Autrey T.","year":"1991","journal-title":"J. Org. Chem."},{"key":"jo025581kb00013\/jo025581kb00013_1","volume-title":"Thermochemical Kinetics","author":"Benson S. W.","year":"1976","edition":"2"},{"key":"jo025581kb00015\/jo025581kb00015_1","doi-asserted-by":"crossref","first-page":"268","DOI":"10.1021\/ja00183a040","volume":"111","author":"Franz J. A.","year":"1989","journal-title":"J. Am. Chem. Soc."},{"key":"jo025581kb00016\/jo025581kb00016_1","doi-asserted-by":"crossref","first-page":"19","DOI":"10.1021\/jo00351a004","volume":"51","author":"Franz J. A.","year":"1986","journal-title":"J. Org. Chem."},{"key":"jo025581kb00017\/jo025581kb00017_1","doi-asserted-by":"crossref","first-page":"1052","DOI":"10.1021\/ja00029a038","volume":"114","author":"Alnajjar M. S.","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"jo025581kb00018\/jo025581kb00018_1","doi-asserted-by":"crossref","first-page":"3375","DOI":"10.1039\/TF9666203375","volume":"62","author":"Porter G.","year":"1966","journal-title":"Trans. Faraday. Soc."},{"key":"jo025581kb00019\/jo025581kb00019_1","doi-asserted-by":"crossref","first-page":"5466","DOI":"10.1021\/ja00997a037","volume":"89","author":"Yang N. C.","year":"1967","journal-title":"J. Am. Chem. Soc."},{"key":"jo025581kb00020\/jo025581kb00020_1","doi-asserted-by":"crossref","first-page":"873","DOI":"10.1039\/TF9646000873","volume":"60","author":"Beckett A.","year":"1964","journal-title":"Trans Faraday Soc."},{"key":"jo025581kb00020\/jo025581kb00020_2","doi-asserted-by":"crossref","first-page":"6824","DOI":"10.1021\/ja01052a048","volume":"91","author":"Cohen S. G.","year":"1969","journal-title":"J. Am. Chem. Soc."},{"key":"jo025581kb00021\/jo025581kb00021_1","doi-asserted-by":"crossref","first-page":"13368","DOI":"10.1021\/j100152a049","volume":"97","author":"The","year":"1993","journal-title":"J. Phys. Chem."},{"key":"jo025581kb00022\/jo025581kb00022_1","doi-asserted-by":"crossref","first-page":"1827","DOI":"10.1021\/ja00501a033","volume":"101","author":"Cohen S. G.","year":"1979","journal-title":"J. Am. Chem. Soc."},{"key":"jo025581kb00022\/jo025581kb00022_2","doi-asserted-by":"crossref","first-page":"3060","DOI":"10.1021\/ja01069a018","volume":"86","author":"Cohen S. G.","year":"1964","journal-title":"J. Am. Chem. Soc."},{"key":"jo025581kb00023\/jo025581kb00023_1","doi-asserted-by":"crossref","first-page":"2102","DOI":"10.1021\/jo00978a010","volume":"37","author":"Lewis F. D.","year":"1972","journal-title":"J. Org. Chem."},{"key":"jo025581kb00023\/jo025581kb00023_2","doi-asserted-by":"crossref","first-page":"7727","DOI":"10.1021\/ja00284a041","volume":"108","author":"Wagner P. J.","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"jo025581kb00024\/jo025581kb00024_1","doi-asserted-by":"crossref","first-page":"9824","DOI":"10.1021\/ja991412e","volume":"121","author":"Franz J. A.","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"jo025581kb00025\/jo025581kb00025_1","doi-asserted-by":"crossref","first-page":"2130","DOI":"10.1002\/hlca.19780610620","volume":"61","author":"Schuh H. H.","year":"1978","journal-title":"Helv. Chim. Acta"},{"key":"jo025581kb00025\/jo025581kb00025_2","doi-asserted-by":"crossref","first-page":"2283","DOI":"10.1021\/j100615a022","volume":"78","author":"Ghai R. K.","year":"1974","journal-title":"J. Phys. Chem."},{"key":"jo025581kb00025\/jo025581kb00025_3","doi-asserted-by":"crossref","first-page":"522","DOI":"10.1515\/zna-1953-0902","volume":"8","author":"Spernol A.","year":"1953","journal-title":"Naturforsch."},{"issue":"4","key":"jo025581kb00025\/jo025581kb00025_4","doi-asserted-by":"crossref","first-page":"261","DOI":"10.1021\/ed047p261","volume":"47","author":"Edward J. T.","year":"1970","journal-title":"J. Chem. Educ."},{"key":"jo025581kb00026\/jo025581kb00026_1","first-page":"473","volume":"235","author":"Taylor G.","year":"1954","journal-title":"Proc. R. Soc. London A"},{"key":"jo025581kb00026\/jo025581kb00026_2","doi-asserted-by":"crossref","first-page":"393","DOI":"10.1098\/rspa.1974.0026","volume":"336","author":"Pratt K. C.","year":"1974","journal-title":"Proc. R. Soc. London A"},{"key":"jo025581kb00026\/jo025581kb00026_3","doi-asserted-by":"crossref","first-page":"3467","DOI":"10.1021\/j100462a032","volume":"84","author":"Huggenberger C.","year":"1980","journal-title":"J. Phys. Chem."},{"key":"jo025581kb00027\/jo025581kb00027_1","doi-asserted-by":"crossref","first-page":"5948","DOI":"10.1021\/jp004291+","volume":"105","author":"Autrey T.","year":"2001","journal-title":"J. Phys. Chem. A"},{"key":"jo025581kb00030\/jo025581kb00030_1","doi-asserted-by":"crossref","first-page":"253","DOI":"10.1016\/0047-2670(86)87013-7","volume":"32","author":"Scaiano J. C.","year":"1986","journal-title":"J. Photochem."},{"key":"jo025581kb00030\/jo025581kb00030_2","doi-asserted-by":"crossref","first-page":"89","DOI":"10.1021\/jo00288a019","volume":"55","author":"Netto-Fereira J. C.","year":"1990","journal-title":"J. Org. Chem."},{"key":"jo025581kb00031\/jo025581kb00031_1","volume-title":"Gaussian 98, revision A.7","author":"Frisch M. J.","year":"1998"},{"issue":"21","key":"jo025581kb00032\/jo025581kb00032_1","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1021\/ja00021a038","volume":"113","author":"Tanner D. D.","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"jo025581kb00034\/jo025581kb00034_1","doi-asserted-by":"crossref","first-page":"503","DOI":"10.1021\/jo00263a050","volume":"54","author":"Suleman N. K.","year":"1989","journal-title":"J. Org. Chem."},{"key":"jo025581kb00035\/jo025581kb00035_1","doi-asserted-by":"crossref","first-page":"231","DOI":"10.1021\/jo00890a018","volume":"40","author":"Seebach D.","year":"1975","journal-title":"J. Org. Chem."},{"key":"jo025581kb00035\/jo025581kb00035_2","doi-asserted-by":"crossref","first-page":"3553","DOI":"10.1021\/jo00822a019","volume":"36","author":"Corey E. J.","year":"1971","journal-title":"J. Org. Chem."}],"container-title":["The Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jo025581k","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,13]],"date-time":"2023-03-13T12:09:42Z","timestamp":1678709382000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jo025581k"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2002,10,25]]},"references-count":43,"journal-issue":{"issue":"23","published-print":{"date-parts":[[2002,11,1]]}},"alternative-id":["10.1021\/jo025581k"],"URL":"https:\/\/doi.org\/10.1021\/jo025581k","relation":{},"ISSN":["0022-3263","1520-6904"],"issn-type":[{"value":"0022-3263","type":"print"},{"value":"1520-6904","type":"electronic"}],"subject":[],"published":{"date-parts":[[2002,10,25]]}}}