{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T03:15:04Z","timestamp":1789614904612,"version":"build-2803163510"},"reference-count":39,"publisher":"American Chemical Society (ACS)","issue":"4","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Org. Chem."],"published-print":{"date-parts":[[2006,2,1]]},"DOI":"10.1021\/jo052123d","type":"journal-article","created":{"date-parts":[[2006,2,10]],"date-time":"2006-02-10T05:39:48Z","timestamp":1139549988000},"page":"1480-1492","source":"Crossref","is-referenced-by-count":55,"title":["Methoxy-Substituted Stilbenes, Styrenes, and 1-Arylpropenes:\u2009 Photophysical Properties and Photoadditions of Alcohols"],"prefix":"10.1021","volume":"71","author":[{"given":"Jeffrey C.","family":"Roberts","sequence":"first","affiliation":[{"name":"Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada B3H 4J3"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"James A.","family":"Pincock","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada B3H 4J3"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2006,1,26]]},"reference":[{"key":"jo052123db00001\/jo052123db00001_1","doi-asserted-by":"crossref","unstructured":"(a) Saltiel, J.; Charlton, J. L. InRearrangements in Ground and Excited States; de Mayo, P., Ed.; Academic Press:\u2009 New York, 1980; Vol. 3, pp 25\u221289.","DOI":"10.1016\/B978-0-12-481303-8.50007-X"},{"key":"jo052123db00001\/jo052123db00001_2","volume-title":"Photochromism, Molecules and Systems","author":"Saltiel J.","year":"1990"},{"key":"jo052123db00001\/jo052123db00001_3","doi-asserted-by":"crossref","first-page":"436","DOI":"10.1021\/cr00003a007","volume":"91","author":"Waldeck D. H.","year":"1991","journal-title":"Chem. Rev."},{"key":"jo052123db00001\/jo052123db00001_4","first-page":"117","volume":"19","author":"G\u00f6rner H.","year":"1995","journal-title":"J. Adv. Photochem."},{"key":"jo052123db00002\/jo052123db00002_1","first-page":"3101","volume":"26","author":"G\u00fcsten H.","year":"1968","journal-title":"Tetrahedron Lett."},{"key":"jo052123db00003\/jo052123db00003_1","doi-asserted-by":"crossref","first-page":"2465","DOI":"10.1021\/ja00059a047","volume":"115","author":"Saltiel J.","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"jo052123db00004\/jo052123db00004_1","doi-asserted-by":"crossref","first-page":"18","DOI":"10.1021\/ja01003a004","volume":"90","author":"Gegiou D. S.","year":"1968","journal-title":"J. Am. Chem. Soc."},{"key":"jo052123db00005\/jo052123db00005_1","first-page":"3918","volume":"90","author":"Gegiou D. S.","year":"1968","journal-title":"J. Am. Chem. Soc."},{"key":"jo052123db00006\/jo052123db00006_1","doi-asserted-by":"crossref","first-page":"4760","DOI":"10.1021\/ja01019a064","volume":"90","author":"Saltiel J. S.","year":"1968","journal-title":"J. Am. Chem. Soc."},{"key":"jo052123db00007\/jo052123db00007_1","first-page":"3835","volume":"119","author":"Lewis F. D.","year":"1997","journal-title":"J. Am. Chem. Soc."},{"key":"jo052123db00007\/jo052123db00007_2","first-page":"12053","volume":"121","author":"Lewis F. D.","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"jo052123db00007\/jo052123db00007_3","first-page":"291","volume":"105","author":"Lewis F. D.","year":"2001","journal-title":"J. Phys. Chem. A."},{"key":"jo052123db00007\/jo052123db00007_4","first-page":"4696","volume":"105","author":"Lewis F. D.","year":"2001","journal-title":"J. Phys. Chem. A."},{"key":"jo052123db00007\/jo052123db00007_5","doi-asserted-by":"crossref","first-page":"8153","DOI":"10.1021\/jp0017083","volume":"104","author":"Lewis F. D.","year":"2000","journal-title":"J. Phys. Chem. A."},{"key":"jo052123db00008\/jo052123db00008_1","first-page":"4045","volume":"125","author":"Lewis F. D.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"jo052123db00008\/jo052123db00008_2","doi-asserted-by":"crossref","first-page":"668","DOI":"10.1039\/b403661a","volume":"3","author":"Crompton E. M.","year":"2004","journal-title":"Photochem. Photobiol. Sci."},{"key":"jo052123db00008\/jo052123db00008_3","doi-asserted-by":"crossref","first-page":"2451","DOI":"10.1021\/jp044942s","volume":"109","author":"Lewis F. D.","year":"2005","journal-title":"J. Phys. Chem. A"},{"key":"jo052123db00009\/jo052123db00009_1","first-page":"4282","volume":"69","author":"Roberts J. C.","year":"2004","journal-title":"J. Org. Chem."},{"key":"jo052123db00010\/jo052123db00010_1","volume":"81","author":"Earlier","year":"2003","journal-title":"Can. J. Chem."},{"key":"jo052123db00011\/jo052123db00011_1","volume-title":"rapid trans-cis isomerization does occur during the steady-state irradiation experiments","author":"Although"},{"key":"jo052123db00012\/jo052123db00012_1","first-page":"181","volume":"5","author":"Wan P.","year":"1984","journal-title":"Rev. Chem. Intermed."},{"key":"jo052123db00013\/jo052123db00013_1","doi-asserted-by":"crossref","first-page":"206","DOI":"10.1002\/poc.610040402","volume":"4","author":"McEwen J.","year":"1991","journal-title":"J. Phys. Org. Chem."},{"key":"jo052123db00014\/jo052123db00014_1","doi-asserted-by":"crossref","first-page":"2082","DOI":"10.1139\/v99-210","volume":"77","author":"Cozens F. L.","year":"1999","journal-title":"Can. J. Chem."},{"key":"jo052123db00015\/jo052123db00015_1","first-page":"2154","volume":"2147","author":"Woning J.","year":"1989","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"jo052123db00016\/jo052123db00016_1","first-page":"1721","volume":"54","author":"Muzzucato U.","year":"1982","journal-title":"Pure Appl. Chem."},{"key":"jo052123db00017\/jo052123db00017_1","first-page":"548","volume":"159","author":"Kim S. K.","year":"1989","journal-title":"Chem. Phys. Lett."},{"key":"jo052123db00018\/jo052123db00018_1","first-page":"962","volume":"61","author":"Lippert E. Z.","year":"1957","journal-title":"Elektrochem."},{"key":"jo052123db00018\/jo052123db00018_2","doi-asserted-by":"crossref","first-page":"465","DOI":"10.1246\/bcsj.29.465","volume":"29","author":"Mataga N.","year":"1956","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"jo052123db00019\/jo052123db00019_1","unstructured":"The substantial increase in the dipole moment of thetrans-1dexcited state has been reported previously:\u2009 Hara, M.; Tojo, S.; Majima, T.J. Photochem.Photobiol. A:\u2009 Chem.2004,162, 121\u2212128. However, we note that these authors reported values for other photophysical properties oftrans-1din acetonitrile (\u03c6f= 0.023, \u03c4s= 4 ns) that are not consistent with our measurements. At this time, we have no explanation for these differences."},{"key":"jo052123db00023\/jo052123db00023_1","doi-asserted-by":"crossref","first-page":"317","DOI":"10.1016\/0009-2614(79)87026-8","volume":"63","author":"Condirston D. A.","year":"1979","journal-title":"Chem. Phys. Lett."},{"key":"jo052123db00024\/jo052123db00024_1","first-page":"10485","volume":"116","author":"Lewis F. D.","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"jo052123db00025\/jo052123db00025_1","first-page":"8813","volume":"125","author":"Lewis F. D.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"jo052123db00028\/jo052123db00028_1","first-page":"158","volume":"17","author":"Ts 0.","year":"1990","journal-title":"Prog. Phys. Org. Chem."},{"key":"jo052123db00029\/jo052123db00029_1","first-page":"9","volume-title":"R(3s)) Rydberg states, which react by processes that are characteristic of radical cations. Kropp, P. J. In CRC Handbook of Photochemistry and Photobiology","author":"The","year":"2004"},{"key":"jo052123db00030\/jo052123db00030_1","doi-asserted-by":"crossref","first-page":"1004","DOI":"10.1021\/jo01342a002","volume":"31","author":"Kingsbury C. A.","year":"1966","journal-title":"J. Org. Chem."},{"key":"jo052123db00031\/jo052123db00031_1","doi-asserted-by":"crossref","DOI":"10.1021\/ja00031a041","volume":"114","author":"McClelland","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"jo052123db00032\/jo052123db00032_1","doi-asserted-by":"crossref","first-page":"2316","DOI":"10.1063\/1.455971","volume":"90","author":"Sivakumar N.","year":"1989","journal-title":"J. Chem. Phys."},{"key":"jo052123db00034\/jo052123db00034_1","doi-asserted-by":"crossref","first-page":"1053","DOI":"10.1063\/1.459168","volume":"93","author":"Abrash S.","year":"1990","journal-title":"J. Chem. Phys."},{"key":"jo052123db00034\/jo052123db00034_2","first-page":"8668","volume":"93","author":"Todd D. C.","year":"1990","journal-title":"J. Chem. Phys."}],"container-title":["The Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jo052123d","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,10,17]],"date-time":"2021-10-17T03:31:54Z","timestamp":1634441514000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jo052123d"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2006,1,26]]},"references-count":39,"journal-issue":{"issue":"4","published-print":{"date-parts":[[2006,2,1]]}},"alternative-id":["10.1021\/jo052123d"],"URL":"https:\/\/doi.org\/10.1021\/jo052123d","relation":{},"ISSN":["0022-3263","1520-6904"],"issn-type":[{"value":"0022-3263","type":"print"},{"value":"1520-6904","type":"electronic"}],"subject":[],"published":{"date-parts":[[2006,1,26]]}}}