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Chem."},{"key":"ref46\/cit46a","unstructured":"aAt \u221235 \u00b0C, the ratio of the rate constants may be estimated askendo\/kexo= exp(\u2212\u0394\u0394E\/RT) = exp(2300 cal mol\u20131\/(238 K \u00d7 1.987 cal mol\u20131K\u20131) \u2248 130."},{"key":"ref46\/cit46b","unstructured":"bNote that X-ray structural analysis of the crystalline white product resulting from the reaction between MeOSty donor and oCA acceptor at room temperature under air revealed hydrated cycloaddition product in exo-configuration (Figure S6). It indicates that a significant amount of the exoadduct forms at higher temperatures; that is, the difference of the energies of transition state leading to exo- and endoisomers is not very high."},{"key":"ref51\/cit51","doi-asserted-by":"crossref","first-page":"2559","DOI":"10.1021\/ja0211611","volume":"125","author":"Ganesan V.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref53\/cit53","volume-title":"SHELXTL","author":"Sheldrick G. 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