{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T08:15:12Z","timestamp":1791188112881,"version":"4.1.0"},"reference-count":76,"publisher":"American Chemical Society (ACS)","issue":"13","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Org. Chem."],"published-print":{"date-parts":[[2013,7,5]]},"DOI":"10.1021\/jo400927y","type":"journal-article","created":{"date-parts":[[2013,6,3]],"date-time":"2013-06-03T17:59:33Z","timestamp":1370282373000},"page":"6677-6687","source":"Crossref","is-referenced-by-count":49,"title":["Chloroform as a Hydrogen Atom Donor in Barton Reductive Decarboxylation Reactions"],"prefix":"10.1021","volume":"78","author":[{"given":"Junming","family":"Ho","sequence":"first","affiliation":[{"name":"ARC Centre of Excellence for Free-Radical Chemistry and Biotechnology, Research School of Chemistry, Australian National University, Canberra, ACT, Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingjing","family":"Zheng","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Supercomputing Institute, and Chemical Theory Center, University of Minnesota, Minneapolis, Minnesota 55455-0431, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rub\u00e9n","family":"Meana-Pa\u00f1eda","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Supercomputing Institute, and Chemical Theory Center, University of Minnesota, Minneapolis, Minnesota 55455-0431, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Donald G.","family":"Truhlar","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Supercomputing Institute, and Chemical Theory Center, University of Minnesota, Minneapolis, Minnesota 55455-0431, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eun Jung","family":"Ko","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Biosciences, University of Queensland, Brisbane 4072, Queensland, Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"G. Paul","family":"Savage","sequence":"additional","affiliation":[{"name":"CSIRO Materials Science and Engineering, Clayton South, 3169 Victoria, Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Craig M.","family":"Williams","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Biosciences, University of Queensland, Brisbane 4072, Queensland, Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michelle L.","family":"Coote","sequence":"additional","affiliation":[{"name":"ARC Centre of Excellence for Free-Radical Chemistry and Biotechnology, Research School of Chemistry, Australian National University, Canberra, ACT, Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"John","family":"Tsanaktsidis","sequence":"additional","affiliation":[{"name":"CSIRO Materials Science and Engineering, Clayton South, 3169 Victoria, Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2013,6,24]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"crossref","first-page":"5030","DOI":"10.1039\/c1cs15093f","volume":"40","author":"Rodr\u00edguez N.","year":"2011","journal-title":"Chem. Soc. Rev."},{"key":"ref2\/cit2","doi-asserted-by":"crossref","first-page":"6868","DOI":"10.1021\/ja00856a047","volume":"97","author":"Logue M. W.","year":"1975","journal-title":"J. Am. Chem. Soc."},{"key":"ref3\/cit3","doi-asserted-by":"crossref","first-page":"1298","DOI":"10.1039\/C39840001298","author":"Barton D. H. R.","year":"1984","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"939","DOI":"10.1039\/c39830000939","author":"Barton D. H. R.","year":"1983","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref5\/cit5","doi-asserted-by":"crossref","first-page":"2061","DOI":"10.1071\/CH9862061","volume":"39","author":"Della E. W.","year":"1986","journal-title":"Aust. J. Chem."},{"key":"ref6\/cit6","doi-asserted-by":"crossref","first-page":"501","DOI":"10.1055\/s-1995-3961","volume":"1995","author":"Eaton P. E.","year":"1995","journal-title":"Synthesis"},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"5244","DOI":"10.1039\/b714526h","author":"Yoshimi Y.","year":"2007","journal-title":"Chem. Commun."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"3563","DOI":"10.1016\/j.tet.2009.01.103","volume":"65","author":"Saraiva M. c. F.","year":"2009","journal-title":"Tetrahedron"},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"7083","DOI":"10.1016\/S0040-4020(01)88249-1","volume":"48","author":"Barton D. H. R.","year":"1992","journal-title":"Tetrahedron"},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"809","DOI":"10.1002\/poc.1836","volume":"24","author":"Fraind A.","year":"2011","journal-title":"J. Phys. Org. Chem."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"342","DOI":"10.1021\/ar9703443","volume":"32","author":"Laarhoven L. J.","year":"1999","journal-title":"Acc. Chem. Res."},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"10645","DOI":"10.1021\/ja00148a006","volume":"117","author":"Zavitsas A. A.","year":"1995","journal-title":"J. Am. Chem. Soc."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"7288","DOI":"10.1021\/jo061033l","volume":"71","author":"Escoubet S.","year":"2006","journal-title":"J. Org. Chem."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"5559","DOI":"10.1016\/S0032-3861(03)00581-0","volume":"44","author":"Henr\u00edquez C.","year":"2003","journal-title":"Polymer"},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"159","DOI":"10.1016\/S0166-1280(98)00314-5","volume":"460","author":"Maung N.","year":"1999","journal-title":"THEOCHEM"},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"5098","DOI":"10.1021\/jo070336s","volume":"72","author":"Jin J.","year":"2007","journal-title":"J. Org. Chem."},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"1944","DOI":"10.1021\/ol200290m","volume":"13","author":"Ko E. J.","year":"2011","journal-title":"Org. Lett."},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"471","DOI":"10.15227\/orgsyn.089.0471","volume":"89","author":"Ko E. J.","year":"2012","journal-title":"Org. Synth."},{"key":"ref19\/cit19","doi-asserted-by":"crossref","DOI":"10.1201\/9781420007282","volume-title":"Handbook of bond dissociation energies in organic compounds","author":"Luo Y.-R.","year":"2007"},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"4849","DOI":"10.1063\/1.1544731","volume":"118","author":"Henry D. J.","year":"2003","journal-title":"J. Chem. Phys."},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"7211","DOI":"10.1021\/jp048092s","volume":"108","author":"Beare K. D.","year":"2004","journal-title":"J. Phys. Chem. A"},{"key":"ref22\/cit22","doi-asserted-by":"crossref","first-page":"11683","DOI":"10.1021\/jp073974n","volume":"111","author":"Merrick J. P.","year":"2007","journal-title":"J. Phys. Chem. A"},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"6378","DOI":"10.1021\/jp810292n","volume":"113","author":"Marenich A. V.","year":"2009","journal-title":"J. Phys. Chem. B"},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1007\/s00214-007-0310-x","volume":"120","author":"Zhao Y.","year":"2008","journal-title":"Theor. Chem. Acc."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","unstructured":"Fernandez-Ramos, A.; Ellingson, B. A.; Garrett, B. C.; Truhlar, D. G.InReviews in Computational Chemistry;Lipkowitz, K. B.; Cundari, T. R., Eds.Wiley-VCH:Hoboken, NJ, pp125\u2013232, 2007; Vol.23.","DOI":"10.1002\/9780470116449.ch3"},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"2408","DOI":"10.1021\/ja00059a041","volume":"115","author":"Liu Y.-P.","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"3019","DOI":"10.1021\/j150621a001","volume":"85","author":"Skodje R. T.","year":"1981","journal-title":"J. Phys. Chem."},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"7806","DOI":"10.1021\/ja00070a029","volume":"115","author":"Liu Y.-P.","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"1491","DOI":"10.1063\/1.1329893","volume":"114","author":"Fernandez-Ramos A.","year":"2001","journal-title":"J. Chem. Phys."},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"1063","DOI":"10.1021\/ct050153i","volume":"1","author":"Fernandez-Ramos A.","year":"2005","journal-title":"J. Chem. Theory Comput."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"922","DOI":"10.1063\/1.454172","volume":"88","author":"Page M.","year":"1988","journal-title":"J. Chem. Phys."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"317","DOI":"10.1007\/s002140050267","volume":"97","author":"Vill\u00e0 J.","year":"1997","journal-title":"Theor. Chem. Acc."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"2872","DOI":"10.1021\/ct100326h","volume":"6","author":"Alecu I. M.","year":"2010","journal-title":"J. Chem. Theory Comput."},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"813","DOI":"10.1007\/s00214-007-0328-0","volume":"118","author":"Fernandez-Ramos A.","year":"2007","journal-title":"Theor. Chem. Acc."},{"key":"ref35\/cit35","unstructured":"Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery, Jr., J. A.; Peralta, J. E.; Ogliaro, F.; Bearpark, M.; Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. N.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, N. J.; Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Zakrzewski, V. G.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Dapprich, S.; Daniels, A. D.; Farkas, \u00d6.; Foresman, J. B.; Ortiz, J. V.; Cioslowski, J.; Fox, D. J.;Gaussian 09, revision A.1;Gaussian, Inc.:Wallingford, CT, 2009."},{"key":"ref36\/cit36","unstructured":"MOLPRO version 2009.1 is a package of ab initio programs written by:Werner, H.J.; P. J. K., R.Lindh; Manby, F. R.; M.Sch\u00fctz; Celani, P.; Korona, T.; Mitrushenkov, A.; Rauhut, G.; Adler, T. B.; Amos, R. D.; Bernhardsson, A.; Berning, A.; Cooper, D. L.; Deegan, M. J. O.; Dobbyn, A. J.; Eckert, F.; Goll, E.; Hampel, C.; Hetzer, G.; Hrenar, T.; Knizia, G.; C.K\u00f6ppl; Liu, Y.; Lloyd, A. W.; Mata, R. A.; May, A. J.; McNicholas, S. J.; Meyer, W.; Mura, M. E.; Nicklass, A.; Palmieri, P.; K.Pfl\u00fcger; Pitzer, R.; Reiher, M.; Schumann, U.; Stoll, H.; Stone, A. J.; Tarroni, R.; Thorsteinsson, T.; Wang, M.; Wolf, A.MOLPRO, version 2009.1."},{"key":"ref37\/cit37","volume-title":"POLYRATE","author":"Zheng J. Z., S.","year":"2010"},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"376","DOI":"10.1021\/jo00288a073","volume":"55","author":"Dauben W. G.","year":"1990","journal-title":"J. Org. Chem."},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"2461","DOI":"10.1016\/S0040-4039(01)80425-1","volume":"30","author":"Dauben W. G.","year":"1989","journal-title":"Tetrahedron Lett."},{"key":"ref40\/cit40","doi-asserted-by":"crossref","first-page":"9699","DOI":"10.1021\/ja00143a013","volume":"117","author":"Aveline B. M.","year":"1995","journal-title":"J. Am. Chem. Soc."},{"key":"ref41\/cit41","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1039\/f29767200087","volume":"72","author":"Frith P. G.","year":"1976","journal-title":"J. Chem. Soc., Faraday Trans."},{"key":"ref42\/cit42","doi-asserted-by":"crossref","first-page":"1615","DOI":"10.1016\/S0040-4039(00)95373-5","volume":"28","author":"Newcomb M.","year":"1987","journal-title":"Tetrahedron Lett."},{"key":"ref43\/cit43","doi-asserted-by":"crossref","first-page":"3901","DOI":"10.1016\/S0040-4020(01)97173-X","volume":"41","author":"Barton D. H. R.","year":"1985","journal-title":"Tetrahedron"},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"1413","DOI":"10.1021\/cr00097a001","volume":"89","author":"Crich D.","year":"1989","journal-title":"Chem. Rev."},{"key":"ref45\/cit45","first-page":"263","volume":"10","author":"Tuan N. Q.","year":"1977","journal-title":"Radiat. Phys. Chem."},{"key":"ref46\/cit46","unstructured":"Coote, M. L.; Lin, C. Y.; Zipse, H.InCarbon-Centered Free Radicals and Radical Cations: Structure, Reactivity, and Dynamics;Forbes, M. D. E., Ed.John Wiley & Sons, Inc.:Hoboken, NJ, 2010; Vol.3, pp83\u2013104."},{"key":"ref47\/cit47","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1039\/a804291h","volume":"28","author":"Roberts B. P.","year":"1999","journal-title":"Chem. Soc. Rev."},{"key":"ref48\/cit48","doi-asserted-by":"crossref","first-page":"2719","DOI":"10.1039\/p29960002719","author":"Roberts B. P.","year":"1996","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"ref49\/cit49","doi-asserted-by":"crossref","first-page":"2155","DOI":"10.1039\/P29940002155","author":"Roberts B. P.","year":"1994","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"ref50\/cit50","doi-asserted-by":"crossref","first-page":"135","DOI":"10.1002\/poc.610040303","volume":"4","author":"Pross A.","year":"1991","journal-title":"J. Phys. Org. Chem."},{"key":"ref51\/cit51","first-page":"99","volume":"21","author":"Pross A.","year":"1985","journal-title":"Adv. Phys. Org. Chem."},{"key":"ref52\/cit52","doi-asserted-by":"crossref","first-page":"363","DOI":"10.1021\/ar00094a001","volume":"16","author":"Pross A.","year":"1983","journal-title":"Acc. Chem. Res."},{"key":"ref53\/cit53","doi-asserted-by":"crossref","first-page":"197","DOI":"10.1002\/9780470171943.ch4","volume":"15","author":"Shaik S. S.","year":"1985","journal-title":"Prog. Phys. Org. Chem."},{"key":"ref54\/cit54","volume-title":"Theoretical and Physical Principles of Organic Reactivity","author":"Pross A.","year":"1995"},{"key":"ref55\/cit55","unstructured":"NIST Chemistry WebBook, NIST Standard Reference Database Number 69;Linstrom, P. J.; Mallard, W. G., Eds.National Institute of Standards and Technology:Gaithersburg, MD,20899,http:\/\/webbook.nist.gov(retrieved June 12, 2012) ."},{"key":"ref56\/cit56","doi-asserted-by":"crossref","first-page":"6358","DOI":"10.1002\/chem.200500265","volume":"11","author":"Shaik S.","year":"2005","journal-title":"Chem.\u2014Eur. J."},{"key":"ref57\/cit57","doi-asserted-by":"crossref","first-page":"7861","DOI":"10.1021\/ja00046a035","volume":"114","author":"Shaik S.","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"ref58\/cit58","doi-asserted-by":"crossref","first-page":"443","DOI":"10.1038\/nchem.327","volume":"1","author":"Shaik S. S.","year":"2009","journal-title":"Nat. Chem."},{"key":"ref59\/cit59","doi-asserted-by":"crossref","first-page":"4689","DOI":"10.1021\/ol035860+","volume":"5","author":"Coote M. L.","year":"2003","journal-title":"Org. Lett."},{"key":"ref60\/cit60","doi-asserted-by":"crossref","first-page":"7558","DOI":"10.1021\/jp052021r","volume":"109","author":"Izgorodina E. I.","year":"2005","journal-title":"J. Phys. Chem. A"},{"key":"ref61\/cit61","doi-asserted-by":"crossref","first-page":"1715","DOI":"10.1021\/jo102368v","volume":"76","author":"Lin C. Y.","year":"2011","journal-title":"J. Org. Chem."},{"key":"ref62\/cit62","doi-asserted-by":"crossref","first-page":"2836","DOI":"10.1021\/ja053130m","volume":"128","author":"Hiberty P. C.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref63\/cit63a","doi-asserted-by":"crossref","first-page":"3140","DOI":"10.1021\/cr050308e","volume":"106","author":"Pu J. G., J.","year":"2006","journal-title":"Chem. Rev."},{"key":"ref63\/cit63b","doi-asserted-by":"crossref","first-page":"660","DOI":"10.1002\/poc.1676","volume":"23","author":"Truhlar D. G.","year":"2010","journal-title":"J. Phys. Org. Chem."},{"key":"ref63\/cit63c","doi-asserted-by":"crossref","first-page":"3781","DOI":"10.1039\/c2ob07170c","volume":"10","author":"Ley D.","year":"2012","journal-title":"Org. Biomol. Chem."},{"key":"ref63\/cit63d","doi-asserted-by":"crossref","first-page":"1300","DOI":"10.1126\/science.1203761","volume":"332","author":"Schreiner P. R.","year":"2011","journal-title":"Science"},{"key":"ref63\/cit63e","doi-asserted-by":"crossref","first-page":"164","DOI":"10.1021\/ja0664279","volume":"129","author":"Shelton G. R.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref64\/cit64","doi-asserted-by":"crossref","first-page":"5030","DOI":"10.1021\/ja00353a029","volume":"105","author":"Engel P. S.","year":"1983","journal-title":"J. Am. Chem. Soc."},{"key":"ref65\/cit65","doi-asserted-by":"crossref","first-page":"1052","DOI":"10.1021\/jo00290a044","volume":"55","author":"Lomas J. S.","year":"1990","journal-title":"J. Org. Chem."},{"key":"ref66\/cit66","doi-asserted-by":"crossref","first-page":"707","DOI":"10.1016\/S0040-4039(01)80288-4","volume":"30","author":"Lomas J. S.","year":"1989","journal-title":"Tetrahedron Lett."},{"key":"ref67\/cit67","doi-asserted-by":"crossref","first-page":"2253","DOI":"10.1021\/ja9831655","volume":"121","author":"Alhambra C.","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"ref68\/cit68","doi-asserted-by":"crossref","first-page":"3093","DOI":"10.1021\/ja0118439","volume":"124","author":"Cui Q.","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"ref69\/cit69","doi-asserted-by":"crossref","first-page":"7504","DOI":"10.1021\/ja00020a009","volume":"113","author":"Truong T. N.","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"ref70\/cit70","doi-asserted-by":"crossref","first-page":"10426","DOI":"10.1021\/ja00075a095","volume":"115","author":"Storer J. W.","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ref71\/cit71","doi-asserted-by":"crossref","first-page":"3160","DOI":"10.1063\/1.472184","volume":"105","author":"Corchado J. C.","year":"1996","journal-title":"J. Chem. Phys."},{"key":"ref72\/cit72","doi-asserted-by":"crossref","first-page":"19389","DOI":"10.1021\/jp9613192","volume":"100","author":"Villa J.","year":"1996","journal-title":"J. Phys. Chem."}],"container-title":["The Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jo400927y","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,5,11]],"date-time":"2024-05-11T16:37:56Z","timestamp":1715445476000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jo400927y"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,6,24]]},"references-count":76,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2013,7,5]]}},"alternative-id":["10.1021\/jo400927y"],"URL":"https:\/\/doi.org\/10.1021\/jo400927y","relation":{},"ISSN":["0022-3263","1520-6904"],"issn-type":[{"value":"0022-3263","type":"print"},{"value":"1520-6904","type":"electronic"}],"subject":[],"published":{"date-parts":[[2013,6,24]]}}}