{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,19]],"date-time":"2025-09-19T07:31:18Z","timestamp":1758267078851,"version":"3.40.5"},"reference-count":35,"publisher":"American Chemical Society (ACS)","issue":"6","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Org. Chem."],"published-print":{"date-parts":[[2009,3,20]]},"DOI":"10.1021\/jo8022318","type":"journal-article","created":{"date-parts":[[2009,2,24]],"date-time":"2009-02-24T20:40:59Z","timestamp":1235508059000},"page":"2311-2320","source":"Crossref","is-referenced-by-count":10,"title":["Comparison of an Internally Coordinated 2-Pentenyllithium with Its 4-Sila Analog. Structure and Dynamic Behavior: Unexpected <sup>13<\/sup>C<sup>7<\/sup>Li Spin Coupling"],"prefix":"10.1021","volume":"74","author":[{"given":"Gideon","family":"Fraenkel","sequence":"first","affiliation":[{"name":"Department of Chemistry, The Ohio State University, Columbus, Ohio 43210 and The Ohio State University, Newark Campus, Newark, Ohio 43055"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jos\u00e9","family":"Cabral","sequence":"additional","affiliation":[{"name":"Department of Chemistry, The Ohio State University, Columbus, Ohio 43210 and The Ohio State University, Newark Campus, Newark, Ohio 43055"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiao","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemistry, The Ohio State University, Columbus, Ohio 43210 and The Ohio State University, Newark Campus, Newark, Ohio 43055"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Albert","family":"Chow","sequence":"additional","affiliation":[{"name":"Department of Chemistry, The Ohio State University, Columbus, Ohio 43210 and The Ohio State University, Newark Campus, Newark, Ohio 43055"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2009,2,24]]},"reference":[{"key":"ref1\/cit1","unstructured":"Clayden, J. InOrganolithiums, Selectivity for Synthesis;Pergamon:Amsterdam, 2006; Chapter 6, pp273\u2212337."},{"key":"ref2\/cit2a","doi-asserted-by":"crossref","first-page":"5828","DOI":"10.1021\/ja960440j","volume":"118","author":"Fraenkel G.","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"ref2\/cit2b","doi-asserted-by":"crossref","first-page":"3571","DOI":"10.1021\/ja963083l","volume":"119","author":"Fraenkel G.","year":"1997","journal-title":"J. Am. Chem. Soc."},{"key":"ref2\/cit2c","doi-asserted-by":"crossref","first-page":"3983","DOI":"10.1021\/ja030370y","volume":"126","author":"Fraenkel G.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref3\/cit3a","doi-asserted-by":"crossref","first-page":"3422","DOI":"10.1002\/cber.19821151018","volume":"115","author":"Koster E.","year":"1982","journal-title":"Chem. Ber."},{"key":"ref3\/cit3b","doi-asserted-by":"crossref","first-page":"299","DOI":"10.1016\/S0022-328X(00)99358-6","volume":"322","author":"Schumann U.","year":"1987","journal-title":"J. Organomet. Chem."},{"key":"ref3\/cit3c","doi-asserted-by":"crossref","first-page":"84","DOI":"10.1002\/ange.19860980112","volume":"98","author":"Boche G.","year":"1986","journal-title":"Angew. Chem."},{"key":"ref3\/cit3d","doi-asserted-by":"crossref","first-page":"4307","DOI":"10.1021\/ja00031a004","volume":"114","author":"Boche G.","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"ref3\/cit3e","doi-asserted-by":"crossref","first-page":"1501","DOI":"10.1002\/anie.199315013","volume":"32","author":"Weiss E.","year":"1993","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"ref4\/cit4a","first-page":"382","volume":"112","author":"Fraenkel G.","year":"1990","journal-title":"J. Am. Chem. Soc."},{"key":"ref4\/cit4b","doi-asserted-by":"crossref","first-page":"1302","DOI":"10.1021\/jo982196f","volume":"64","author":"Fraenkel G.","year":"1990","journal-title":"J. Org. Chem."},{"key":"ref5\/cit5a","doi-asserted-by":"crossref","first-page":"797","DOI":"10.1021\/ja01005a047","volume":"90","author":"West P.","year":"1968","journal-title":"J. Am. Chem. Soc."},{"key":"ref5\/cit5b","doi-asserted-by":"crossref","first-page":"5459","DOI":"10.1021\/ja00513a001","volume":"101","author":"Thompson T. B.","year":"1979","journal-title":"J. Am. Chem. Soc."},{"key":"ref5\/cit5c","doi-asserted-by":"crossref","first-page":"9067","DOI":"10.1021\/ja00049a044","volume":"114","author":"Cabral J.","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"ref5\/cit5d","doi-asserted-by":"crossref","first-page":"3794","DOI":"10.1021\/ja00193a005","volume":"111","author":"Fraenkel G.","year":"1989","journal-title":"J. Am. Chem. Soc."},{"key":"ref5\/cit5e","doi-asserted-by":"crossref","first-page":"12806","DOI":"10.1021\/ja002248u","volume":"122","author":"Fraenkel G.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ref5\/cit5f","doi-asserted-by":"crossref","first-page":"2582","DOI":"10.1021\/ja00163a016","volume":"112","author":"Fraenkel G.","year":"1990","journal-title":"J. Am. Chem. Soc."},{"key":"ref6\/cit6a","doi-asserted-by":"crossref","first-page":"432","DOI":"10.1021\/ja983047h","volume":"121","author":"Fraenkel G.","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"ref6\/cit6b","first-page":"42","volume":"13","author":"Fraenkel G.","year":"2002","journal-title":"ARKIVOC"},{"key":"ref6\/cit6c","doi-asserted-by":"crossref","first-page":"8211","DOI":"10.1021\/ja060272n","volume":"128","author":"Fraenkel G.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref6\/cit6d","doi-asserted-by":"crossref","first-page":"4140","DOI":"10.1021\/ja0765215","volume":"130","author":"Fraenkel G.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"1551","DOI":"10.1021\/ja00057a048","volume":"115","author":"Fraenkel G.","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ref8\/cit8a","doi-asserted-by":"crossref","first-page":"4563","DOI":"10.1021\/jo00223a027","volume":"50","author":"Fraenkel G.","year":"1985","journal-title":"J. Org. Chem."},{"key":"ref8\/cit8b","doi-asserted-by":"crossref","first-page":"1434","DOI":"10.1039\/c29690001434","author":"Glaze W. H.","year":"1969","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"ref8\/cit8c","doi-asserted-by":"crossref","first-page":"39","DOI":"10.1016\/0022-328X(72)80040-8","volume":"44","author":"Glaze W. H.","year":"1972","journal-title":"J. Organomet. Chem."},{"key":"ref8\/cit8d","doi-asserted-by":"crossref","first-page":"13","DOI":"10.1016\/S0022-328X(00)93497-1","volume":"51","author":"Glaze W. H.","year":"1973","journal-title":"J. Organomet. Chem."},{"key":"ref9\/cit9a","doi-asserted-by":"crossref","first-page":"6300","DOI":"10.1021\/ja00128a020","volume":"117","author":"Fraenkel G.","year":"1995","journal-title":"J. Am. Chem. Soc."},{"key":"ref9\/cit9b","unstructured":"bAbragam, A. InThe Principles of Nuclear Magnetism;Oxford University Press:London, 1961; pp, 309\u2212312."},{"volume-title":"NMR of Chemically Exchanging Systems","year":"1980","author":"Kaplan J. I.","key":"ref10\/cit10a"},{"key":"ref10\/cit10b","doi-asserted-by":"crossref","first-page":"2907","DOI":"10.1021\/ja00764a001","volume":"94","author":"Kaplan J. I.","year":"1972","journal-title":"J. Am. Chem. Soc."},{"key":"ref10\/cit10c","first-page":"1288","volume":"25","author":"Gutowsky H. S.","year":"1957","journal-title":"J. Chem. Phys."},{"key":"ref10\/cit10d","doi-asserted-by":"crossref","first-page":"278","DOI":"10.1063\/1.1744105","volume":"28","author":"Kaplan J. I.","year":"1958","journal-title":"J. Chem. Phys."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"3142","DOI":"10.1039\/b803364a","author":"Solomon S.","year":"2008","journal-title":"Chem. Commun."},{"key":"ref12\/cit12a","doi-asserted-by":"crossref","first-page":"3273","DOI":"10.1139\/v81-483","volume":"59","author":"Kopecky K. R.","year":"1981","journal-title":"Can. J. Chem."},{"key":"ref12\/cit12b","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1021\/jo00202a016","volume":"50","author":"Hart D. J.","year":"1985","journal-title":"J. Org. Chem."}],"container-title":["The Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jo8022318","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,8]],"date-time":"2023-03-08T05:15:20Z","timestamp":1678252520000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jo8022318"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,2,24]]},"references-count":35,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2009,3,20]]}},"alternative-id":["10.1021\/jo8022318"],"URL":"https:\/\/doi.org\/10.1021\/jo8022318","relation":{},"ISSN":["0022-3263","1520-6904"],"issn-type":[{"type":"print","value":"0022-3263"},{"type":"electronic","value":"1520-6904"}],"subject":[],"published":{"date-parts":[[2009,2,24]]}}}