{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T21:06:57Z","timestamp":1761512817813},"reference-count":108,"publisher":"American Chemical Society (ACS)","issue":"45","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Phys. Chem. B"],"published-print":{"date-parts":[[2010,11,18]]},"DOI":"10.1021\/jp101849m","type":"journal-article","created":{"date-parts":[[2010,6,7]],"date-time":"2010-06-07T11:58:57Z","timestamp":1275911937000},"page":"14495-14504","source":"Crossref","is-referenced-by-count":35,"title":["Photoinduced Processes in Self-Assembled Porphyrin\/Perylene Bisimide Metallosupramolecular Boxes"],"prefix":"10.1021","volume":"114","author":[{"given":"M. Teresa","family":"Indelli","sequence":"first","affiliation":[{"name":"Dipartimento di Chimica, Universit\u00e0 di Ferrara, 44100 Ferrara, Italy, ISOF-CNR, Sezione di Ferrara, 44100 Ferrara, Italy, Centro di Ricerca Interuniversitario per la Conversione Chimica dell\u2019Energia Solare, Sezione di Ferrara, 44100 Ferrara, Italy, Dipartimento di Scienze Chimiche, Universit\u00e0 di Trieste, 34127, Trieste, Italy, and Institut f\u00fcr Organische Chemie and R\u00f6ntgen Research Center for Complex Material Systems, Universit\u00e4t W\u00fcrzburg, 97074 W\u00fcrzburg, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Claudio","family":"Chiorboli","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Universit\u00e0 di Ferrara, 44100 Ferrara, Italy, ISOF-CNR, Sezione di Ferrara, 44100 Ferrara, Italy, Centro di Ricerca Interuniversitario per la Conversione Chimica dell\u2019Energia Solare, Sezione di Ferrara, 44100 Ferrara, Italy, Dipartimento di Scienze Chimiche, Universit\u00e0 di Trieste, 34127, Trieste, Italy, and Institut f\u00fcr Organische Chemie and R\u00f6ntgen Research Center for Complex Material Systems, Universit\u00e4t W\u00fcrzburg, 97074 W\u00fcrzburg, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Franco","family":"Scandola","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Universit\u00e0 di Ferrara, 44100 Ferrara, Italy, ISOF-CNR, Sezione di Ferrara, 44100 Ferrara, Italy, Centro di Ricerca Interuniversitario per la Conversione Chimica dell\u2019Energia Solare, Sezione di Ferrara, 44100 Ferrara, Italy, Dipartimento di Scienze Chimiche, Universit\u00e0 di Trieste, 34127, Trieste, Italy, and Institut f\u00fcr Organische Chemie and R\u00f6ntgen Research Center for Complex Material Systems, Universit\u00e4t W\u00fcrzburg, 97074 W\u00fcrzburg, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Elisabetta","family":"Iengo","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Universit\u00e0 di Ferrara, 44100 Ferrara, Italy, ISOF-CNR, Sezione di Ferrara, 44100 Ferrara, Italy, Centro di Ricerca Interuniversitario per la Conversione Chimica dell\u2019Energia Solare, Sezione di Ferrara, 44100 Ferrara, Italy, Dipartimento di Scienze Chimiche, Universit\u00e0 di Trieste, 34127, Trieste, Italy, and Institut f\u00fcr Organische Chemie and R\u00f6ntgen Research Center for Complex Material Systems, Universit\u00e4t W\u00fcrzburg, 97074 W\u00fcrzburg, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peter","family":"Osswald","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Universit\u00e0 di Ferrara, 44100 Ferrara, Italy, ISOF-CNR, Sezione di Ferrara, 44100 Ferrara, Italy, Centro di Ricerca Interuniversitario per la Conversione Chimica dell\u2019Energia Solare, Sezione di Ferrara, 44100 Ferrara, Italy, Dipartimento di Scienze Chimiche, Universit\u00e0 di Trieste, 34127, Trieste, Italy, and Institut f\u00fcr Organische Chemie and R\u00f6ntgen Research Center for Complex Material Systems, Universit\u00e4t W\u00fcrzburg, 97074 W\u00fcrzburg, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Frank","family":"W\u00fcrthner","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Universit\u00e0 di Ferrara, 44100 Ferrara, Italy, ISOF-CNR, Sezione di Ferrara, 44100 Ferrara, Italy, Centro di Ricerca Interuniversitario per la Conversione Chimica dell\u2019Energia Solare, Sezione di Ferrara, 44100 Ferrara, Italy, Dipartimento di Scienze Chimiche, Universit\u00e0 di Trieste, 34127, Trieste, Italy, and Institut f\u00fcr Organische Chemie and R\u00f6ntgen Research Center for Complex Material Systems, Universit\u00e4t W\u00fcrzburg, 97074 W\u00fcrzburg, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2010,6,7]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"crossref","first-page":"1096","DOI":"10.1002\/anie.199510961","volume":"34","author":"Anderson S.","year":"1995","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"ref1\/cit1b","doi-asserted-by":"crossref","first-page":"11181","DOI":"10.1021\/ja961612f","volume":"118","author":"Hsiao J.-S.","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"ref1\/cit1c","doi-asserted-by":"crossref","first-page":"8604","DOI":"10.1021\/ja991255j","volume":"121","author":"Kuciauskas D.","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"ref1\/cit1d","doi-asserted-by":"crossref","first-page":"150","DOI":"10.1002\/anie.200301665","volume":"43","author":"Choi M.-S.","year":"2004","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref1\/cit1e","doi-asserted-by":"crossref","first-page":"6130","DOI":"10.1021\/jp038036b","volume":"108","author":"Imahori H.","year":"2004","journal-title":"J. Phys. Chem. B."},{"key":"ref1\/cit1f","doi-asserted-by":"crossref","first-page":"831","DOI":"10.1039\/b618854k","volume":"36","author":"Nakamura Y.","year":"2007","journal-title":"Chem. Soc. Rev."},{"key":"ref1\/cit1g","doi-asserted-by":"crossref","first-page":"582","DOI":"10.1002\/chem.200701271","volume":"14","author":"Hori T.","year":"2008","journal-title":"Chem.\u2014Eur. J."},{"key":"ref2\/cit2a","doi-asserted-by":"crossref","first-page":"435","DOI":"10.1021\/cr00011a005","volume":"92","author":"Wasielewski M. R.","year":"1992","journal-title":"Chem. Rev."},{"key":"ref2\/cit2b","doi-asserted-by":"crossref","first-page":"41","DOI":"10.1039\/cs9962500041","author":"Harriman A.","year":"1996","journal-title":"Chem. Soc. Rev."},{"key":"ref2\/cit2c","doi-asserted-by":"crossref","first-page":"40","DOI":"10.1021\/ar9801301","volume":"34","author":"Gust D.","year":"2001","journal-title":"Acc. Chem. Res."},{"key":"ref2\/cit2d","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1039\/b308983e","volume":"33","author":"Baranoff E.","year":"2004","journal-title":"Chem. Soc. Rev."},{"key":"ref2\/cit2e","doi-asserted-by":"crossref","first-page":"541","DOI":"10.1021\/jp036382n","volume":"108","author":"Guldi D. M.","year":"2004","journal-title":"J. Phys. Chem. A"},{"key":"ref2\/cit2f","doi-asserted-by":"crossref","first-page":"5051","DOI":"10.1021\/jo060225d","volume":"71","author":"Wasielewski M. R.","year":"2006","journal-title":"J. Org. Chem."},{"key":"ref2\/cit2g","doi-asserted-by":"crossref","first-page":"2283","DOI":"10.1039\/b801198m","volume":"10","author":"Fukuzumi S.","year":"2008","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref2\/cit2h","doi-asserted-by":"crossref","first-page":"541","DOI":"10.1021\/jp036382n","volume":"108","author":"Guldi D. M.","year":"2004","journal-title":"J. Phys. Chem. A"},{"key":"ref2\/cit2i","doi-asserted-by":"crossref","first-page":"1910","DOI":"10.1021\/ar9001735","volume":"42","author":"Wasielewski M. R.","year":"2009","journal-title":"Acc. Chem. Res."},{"key":"ref3\/cit3a","doi-asserted-by":"crossref","first-page":"2751","DOI":"10.1021\/cr0000426","volume":"101","author":"Burrell A. K.","year":"2001","journal-title":"Chem. Rev."},{"key":"ref3\/cit3b","doi-asserted-by":"crossref","first-page":"2323","DOI":"10.1039\/a904209a","author":"Anderson H. L.","year":"1999","journal-title":"Chem. Commun."},{"key":"ref3\/cit3c","unstructured":"cGust, D.; Moore, T. A.; Moore, A. L.InElectron Transfer in Chemistry;Balzani, V., Ed.Wiley-VCH:Weinheim, 2001; Vol.III, Part2, Chapter 2, pp273\u2212336."},{"key":"ref3\/cit3d","doi-asserted-by":"crossref","first-page":"57","DOI":"10.1021\/ar970264z","volume":"35","author":"Holten D.","year":"2002","journal-title":"Acc. Chem. Res."},{"key":"ref3\/cit3e","doi-asserted-by":"crossref","first-page":"735","DOI":"10.1021\/ar030242e","volume":"37","author":"Kim D.","year":"2004","journal-title":"Acc. Chem. Res."},{"key":"ref3\/cit3f","doi-asserted-by":"crossref","first-page":"582","DOI":"10.1002\/chem.200701271","volume":"14","author":"Hori T.","year":"2008","journal-title":"Chem.\u2014Eur. J."},{"key":"ref3\/cit3g","doi-asserted-by":"crossref","first-page":"8011","DOI":"10.1021\/jp902183g","volume":"113","author":"Song H.","year":"2009","journal-title":"J. Phys. Chem. B"},{"key":"ref4\/cit4a","unstructured":"aChambron, J.C.; Heitz, V.; Sauvage, J. P.InThe Porphyrin Handbook;Kadish, K.; Smith, K. M.; Guillard, R., Eds.Academic Press:San Diego, CA, 2000; Vol.6, pp1\u221242."},{"key":"ref4\/cit4b","doi-asserted-by":"crossref","first-page":"133","DOI":"10.1016\/S0010-8545(99)00211-8","volume":"198","author":"Imamura T.","year":"2000","journal-title":"Coord. Chem. Rev."},{"key":"ref4\/cit4c","doi-asserted-by":"crossref","first-page":"213","DOI":"10.1016\/S0898-8838(02)53006-3","volume":"53","author":"Baldini L.","year":"2002","journal-title":"Adv. Inorg. Chem."},{"key":"ref4\/cit4d","doi-asserted-by":"crossref","first-page":"113","DOI":"10.1016\/S0010-8545(99)00207-6","volume":"204","author":"Wojaczy\u00f1ski J.","year":"2000","journal-title":"Coord. Chem. Rev."},{"key":"ref4\/cit4e","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1007\/b98166","volume":"245","author":"Drain C. M.","year":"2005","journal-title":"Top. Curr. Chem."},{"key":"ref4\/cit4f","volume-title":"Structure Bonding Non-Covalent Multi-Porphyrin Assemblies","volume":"121","author":"Mingos D. M. P.","year":"2006"},{"key":"ref4\/cit4g","doi-asserted-by":"crossref","first-page":"4214","DOI":"10.1002\/chem.200800026","volume":"14","author":"Flamigni L.","year":"2008","journal-title":"Chem.\u2014Eur. J."},{"key":"ref4\/cit4h","doi-asserted-by":"crossref","first-page":"8263","DOI":"10.1021\/ic900887q","volume":"48","author":"Beyler M.","year":"2009","journal-title":"Inorg. Chem."},{"key":"ref4\/cit4i","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1021\/ja8045712","volume":"131","author":"Nagata N.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref5\/cit5a","doi-asserted-by":"crossref","first-page":"841","DOI":"10.1021\/ar040240+","volume":"39","author":"Iengo E.","year":"2006","journal-title":"Acc. Chem. Res."},{"key":"ref5\/cit5b","doi-asserted-by":"crossref","first-page":"105","DOI":"10.1007\/430_025","volume":"121","author":"Iengo E.","year":"2006","journal-title":"Struct. Bonding (Berlin)"},{"key":"ref6\/cit6a","doi-asserted-by":"crossref","first-page":"3147","DOI":"10.1002\/anie.200462762","volume":"44","author":"Huber V.","year":"2005","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref6\/cit6b","doi-asserted-by":"crossref","first-page":"1007","DOI":"10.1002\/smll.200600497","volume":"3","author":"Huber V.","year":"2007","journal-title":"Small"},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"1003","DOI":"10.1021\/ja016162s","volume":"124","author":"Iengo E.","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"9752","DOI":"10.1021\/ic051210l","volume":"44","author":"Iengo E.","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"1514","DOI":"10.1002\/cphc.200600065","volume":"7","author":"Prodi A.","year":"2006","journal-title":"Chem. Phys. Chem."},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"1471","DOI":"10.1016\/j.ccr.2006.01.019","volume":"250","author":"Scandola F.","year":"2006","journal-title":"Coord. Chem. Rev."},{"key":"ref11\/cit11a","doi-asserted-by":"crossref","first-page":"63","DOI":"10.1126\/science.257.5066.63","volume":"257","author":"O\u2019Neil M. P.","year":"1992","journal-title":"Science"},{"key":"ref11\/cit11b","doi-asserted-by":"crossref","first-page":"6767","DOI":"10.1021\/ja9600789","volume":"118","author":"Greenfield S. R.","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11c","doi-asserted-by":"crossref","first-page":"7802","DOI":"10.1021\/ja001298w","volume":"122","author":"Miller S. E.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11d","doi-asserted-by":"crossref","first-page":"5563","DOI":"10.1021\/ja000219d","volume":"122","author":"Hayes T.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11e","doi-asserted-by":"crossref","first-page":"7877","DOI":"10.1021\/ja010330z","volume":"123","author":"Davis W. B.","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11f","doi-asserted-by":"crossref","first-page":"5577","DOI":"10.1021\/ja0398215","volume":"126","author":"Weiss E. A.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref11\/cit11g","doi-asserted-by":"crossref","first-page":"11919","DOI":"10.1021\/ja903903q","volume":"131","author":"Bullock J. E.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref12\/cit12a","doi-asserted-by":"crossref","first-page":"514","DOI":"10.1021\/ar040126r","volume":"38","author":"De Schryver F. C.","year":"2005","journal-title":"Acc. Chem. Res."},{"key":"ref12\/cit12b","doi-asserted-by":"crossref","first-page":"1564","DOI":"10.1039\/B401630K","author":"W\u00fcrthner F.","year":"2004","journal-title":"Chem. Commun."},{"key":"ref13\/cit13a","doi-asserted-by":"crossref","first-page":"894","DOI":"10.1002\/1521-3765(20010216)7:4<894::AID-CHEM894>3.0.CO;2-N","volume":"7","author":"W\u00fcrthner F.","year":"2001","journal-title":"Chem.\u2014Eur. J."},{"key":"ref13\/cit13b","doi-asserted-by":"crossref","first-page":"240","DOI":"10.1039\/b208582h","volume":"1","author":"W\u00fcrthner F.","year":"2003","journal-title":"Org. Biomol. Chem."},{"key":"ref13\/cit13c","doi-asserted-by":"crossref","first-page":"6719","DOI":"10.1021\/ja0448216","volume":"127","author":"Sautter A.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref13\/cit13d","doi-asserted-by":"crossref","first-page":"3870","DOI":"10.1021\/ja058007+","volume":"128","author":"Hippius C.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref13\/cit13e","first-page":"433","volume":"13","author":"Chen Z.","year":"2007","journal-title":"Chem.\u2014Eur. J."},{"key":"ref13\/cit13f","doi-asserted-by":"crossref","first-page":"6719","DOI":"10.1021\/ja900684h","volume":"131","author":"Kaiser T. E.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref14\/cit14a","doi-asserted-by":"crossref","first-page":"8530","DOI":"10.1021\/ja026422l","volume":"124","author":"Giaimo J. M.","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"ref14\/cit14b","doi-asserted-by":"crossref","first-page":"970","DOI":"10.1021\/jp044796q","volume":"109","author":"Fuller M. J.","year":"2005","journal-title":"J. Phys. Chem A"},{"key":"ref14\/cit14c","doi-asserted-by":"crossref","first-page":"12268","DOI":"10.1021\/ja0460514","volume":"126","author":"Rybtchinski B.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref14\/cit14d","doi-asserted-by":"crossref","first-page":"1782","DOI":"10.1021\/ja057031k","volume":"128","author":"Tauber M. J.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref14\/cit14e","doi-asserted-by":"crossref","first-page":"14966","DOI":"10.1021\/ja807027w","volume":"130","author":"Baram J.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref14\/cit14f","doi-asserted-by":"crossref","first-page":"14365","DOI":"10.1021\/ja903938g","volume":"131","author":"Krieg E.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref15\/cit15a","doi-asserted-by":"crossref","first-page":"724","DOI":"10.1021\/jp046133e","volume":"109","author":"Yan P.","year":"2005","journal-title":"J. Phys. Chem. B"},{"key":"ref15\/cit15b","doi-asserted-by":"crossref","first-page":"84","DOI":"10.1126\/science.1126524","volume":"313","author":"Bhosale S.","year":"2006","journal-title":"Science"},{"key":"ref15\/cit15c","doi-asserted-by":"crossref","first-page":"4861","DOI":"10.1021\/jp068877t","volume":"111","author":"Flors C.","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref15\/cit15d","doi-asserted-by":"crossref","first-page":"921","DOI":"10.1002\/anie.200703749","volume":"47","author":"Perez-Velasco A.","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref15\/cit15e","doi-asserted-by":"crossref","first-page":"8617","DOI":"10.1021\/jp805949r","volume":"112","author":"Veldman D.","year":"2008","journal-title":"J. Phys. Chem. A"},{"key":"ref15\/cit15f","doi-asserted-by":"crossref","first-page":"5846","DOI":"10.1021\/jp8022524","volume":"112","author":"Veldman D.","year":"2008","journal-title":"J. Phys. Chem A"},{"key":"ref16\/cit16a","doi-asserted-by":"crossref","first-page":"8284","DOI":"10.1021\/ja039820c","volume":"126","author":"Ahrens M. J.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref16\/cit16b","doi-asserted-by":"crossref","first-page":"10810","DOI":"10.1021\/ja047176b","volume":"126","author":"Li X. Y.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref16\/cit16c","doi-asserted-by":"crossref","first-page":"3173","DOI":"10.1021\/ja0664741","volume":"129","author":"Kelley R. F.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref17\/cit17a","doi-asserted-by":"crossref","first-page":"6634","DOI":"10.1021\/jo0007940","volume":"65","author":"Miller M. A.","year":"2000","journal-title":"J. Org. Chem."},{"key":"ref17\/cit17b","doi-asserted-by":"crossref","first-page":"8237","DOI":"10.1021\/jp010335i","volume":"105","author":"Prathapan S.","year":"2001","journal-title":"J. Phys. Chem. B"},{"key":"ref17\/cit17c","doi-asserted-by":"crossref","first-page":"8249","DOI":"10.1021\/jp010336a","volume":"105","author":"Yang S. I.","year":"2001","journal-title":"J. Phys. Chem. B"},{"key":"ref17\/cit17d","doi-asserted-by":"crossref","first-page":"2420","DOI":"10.1039\/b102741g","volume":"11","author":"Yang S.","year":"2001","journal-title":"J. Mater. Chem."},{"key":"ref18\/cit18a","doi-asserted-by":"crossref","first-page":"2401","DOI":"10.1021\/ol049206l","volume":"6","author":"You C.-C.","year":"2004","journal-title":"Org. Lett."},{"key":"ref18\/cit18b","doi-asserted-by":"crossref","first-page":"3376","DOI":"10.1021\/jp7109516","volume":"112","author":"Ghirotti M.","year":"2008","journal-title":"J. Phys. Chem. A"},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"3658","DOI":"10.1021\/jp045163e","volume":"109","author":"Xiao S.","year":"2005","journal-title":"J. Phys. Chem. B"},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"1454","DOI":"10.1021\/ja045379u","volume":"127","author":"Prodi A.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref21\/cit21","unstructured":"Very recently, a related self-assembled system obtained via coordination of rPBIs to a zinc porphyrin trimer has been reported. In that case, however, the inherent flexibility of the zinc porphyrin trimer was detrimental for the stability of the final adduct:"},{"key":"ref21\/cit21a","doi-asserted-by":"crossref","first-page":"4023","DOI":"10.1039\/b819496c","author":"Oliva A. I.","year":"2009","journal-title":"Dalton Trans."},{"key":"ref22\/cit22","unstructured":"Iengo, E.; Zangrando, E.; Alessio, E.; Scandola, F.; Indelli, M.; Stepanenko, V.; W\u00fcrthner, F.Manuscript in preparation."},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"483","DOI":"10.1021\/ja0284916","volume":"125","author":"Chiorboli C.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref24\/cit24","unstructured":"Among common organic solvents, toluene did not dissolve the assemblies well. Chloroform and dichloromethane are good solvents for these assemblies. Dichloromethane was thus chosen, and the electrochemical potentials were measured in this solvent."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"13637","DOI":"10.1021\/j100153a035","volume":"97","author":"Gust D.","year":"1993","journal-title":"J. Phys. Chem."},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"10407","DOI":"10.1021\/ic800971e","volume":"47","author":"Casanova M.","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref27\/cit27a","doi-asserted-by":"crossref","first-page":"303","DOI":"10.1016\/0143-7208(89)85048-X","volume":"11","author":"Seybold G.","year":"1989","journal-title":"Dyes Pigm."},{"key":"ref27\/cit27b","doi-asserted-by":"crossref","first-page":"338","DOI":"10.1016\/0009-2614(93)85142-B","volume":"213","author":"Gvishi R.","year":"1993","journal-title":"Chem. Phys. Lett."},{"key":"ref27\/cit27c","doi-asserted-by":"crossref","first-page":"1509","DOI":"10.1039\/b813737d","volume":"7","author":"Fron E.","year":"2008","journal-title":"Photochem. Photobiol. Sci."},{"key":"ref28\/cit28","unstructured":"Calculated as the average between the energies of the first vibronic feature of the absorption and emission spectra."},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"6373","DOI":"10.1021\/j100309a012","volume":"91","author":"Ford W. E.","year":"1987","journal-title":"J. Phys. Chem."},{"key":"ref30\/cit30","unstructured":"Because the oxidation process for the free dipyridyl perylene species rPBI is irreversible,(13a)the quoted oxidation potential was taken from the Pt(II)-coordinated reversibly oxidizable compound."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"39","DOI":"10.1007\/b136668","volume":"258","author":"You C.-C.","year":"2005","journal-title":"Top. Curr. Chem."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"2245","DOI":"10.1002\/1521-3765(20010518)7:10<2245::AID-CHEM2245>3.0.CO;2-W","volume":"7","author":"W\u00fcrthner F.","year":"2001","journal-title":"Chem.\u2014Eur. J."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"6616","DOI":"10.1002\/anie.200802007","volume":"47","author":"Berberich M.","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"9752","DOI":"10.1021\/ic051210l","volume":"44","author":"Iengo E.","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"2668","DOI":"10.1002\/(SICI)1521-3765(19990903)5:9<2668::AID-CHEM2668>3.0.CO;2-M","volume":"5","author":"Prodi A.","year":"1999","journal-title":"Chem.\u2014Eur. J."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"6522","DOI":"10.1021\/jp034239o","volume":"107","author":"Liu R.","year":"2003","journal-title":"J. Phys. Chem. A"},{"key":"ref37\/cit37a","doi-asserted-by":"crossref","first-page":"834","DOI":"10.1002\/bbpc.19690730818","volume":"73","author":"Rehm D.","year":"1969","journal-title":"Ber. Bunsen-Ges. Phys. Chem."},{"key":"ref37\/cit37b","doi-asserted-by":"crossref","first-page":"93","DOI":"10.1524\/zpch.1982.133.1.093","volume":"133","author":"Weller A.","year":"1982","journal-title":"Z. Phys. Chem."},{"key":"ref38\/cit38","unstructured":"The calculation of the electrostatic work terms requires knowledge of the distance between the donor and the acceptor in the assembly. For PBI\u2212\u2212Zn+, electrostatic work term amounts to 0.14 eV at a center-to-center distance of 11.85 \u00c5.(22)For PBI\u2212\u2212PBI+, the choice of the distance to be used is not obvious. In the highly distorted crystal structure, the two perylene bisimide units are in ap-stacked arrangement with a very short distance (3.9 \u00c5). Because it is not known whether such a geometry is also maintained in solution, this should be taken as a lower limiting value, the maximum being the Zn\u2212Zn distance in the porphyrin metallacycle (13.8 \u00c5). Therefore, the work term for the PBI+\u2212PBI\u2212state may range from 0.12 to 0.42 eV. This translates in a range of energies (1.89\u22121.59 eV) to be used for the PBI+\u2212PBI\u2212state in the energy-level diagram of Figure6."},{"key":"ref39\/cit39","unstructured":"The contribution of the zinc porphyrin radical cation to the overall spectral changes cannot be easily seen. In fact, the radical cation spectrum lacks distinctive features, exhibiting only a weak, broad band around 670 nm."},{"key":"ref40\/cit40","doi-asserted-by":"crossref","first-page":"5507","DOI":"10.1021\/ic010416t","volume":"40","author":"Dixon I. M.","year":"2001","journal-title":"Inorg. Chem."},{"key":"ref41\/cit41","unstructured":"The analogous side-to-face compound involving Zn porphyrin units is not sufficiently stable in solution. However, RuTPP(CO)py and ZnTPP have similar oxidation potentials (0.35 V(20)and 0.42 V(31)vs Fc\/Fc+, respectively)."},{"key":"ref42\/cit42","unstructured":"The work term amounts to 0.14 eV (center-to-center distance of 11.85 \u00c5(22)) for PBI\u2212\u2212Zn+and 0.12 eV (center-to-center distance of 13.8 \u00c5) for PBI\u2212\u2212PBI+."},{"key":"ref43\/cit43","unstructured":"Experimental verification of this possibility is precluded, because nanosecond time-resolved spectroscopy with selective excitation of the perylene bisimide chromophore is not feasible with the available apparatus."},{"key":"ref44\/cit44a","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1002\/andp.19484370105","volume":"2","author":"F\u00f6rster T.","year":"1948","journal-title":"Ann. Phys."},{"key":"ref44\/cit44b","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1039\/DF9592700007","volume":"27","author":"F\u00f6rster T.","year":"1959","journal-title":"Discuss. Faraday Soc."},{"key":"ref45\/cit45","unstructured":"\u03c0-Stacking interactions between perylene bisimide units often give rise to spectral changes due to excitonic coupling.(13, 14)In the spectra of both molecular boxes (Figures3and5), no significant difference with respect to the monomer spectrum of the respective PBI is observed."}],"container-title":["The Journal of Physical Chemistry B"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jp101849m","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,3,27]],"date-time":"2024-03-27T10:33:07Z","timestamp":1711535587000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jp101849m"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,6,7]]},"references-count":108,"journal-issue":{"issue":"45","published-print":{"date-parts":[[2010,11,18]]}},"alternative-id":["10.1021\/jp101849m"],"URL":"https:\/\/doi.org\/10.1021\/jp101849m","relation":{},"ISSN":["1520-6106","1520-5207"],"issn-type":[{"value":"1520-6106","type":"print"},{"value":"1520-5207","type":"electronic"}],"subject":[],"published":{"date-parts":[[2010,6,7]]}}}