{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T17:54:01Z","timestamp":1791568441797,"version":"4.3.4"},"reference-count":56,"publisher":"American Chemical Society (ACS)","issue":"7","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Phys. Chem. B"],"published-print":{"date-parts":[[2013,2,21]]},"DOI":"10.1021\/jp312425m","type":"journal-article","created":{"date-parts":[[2013,1,23]],"date-time":"2013-01-23T21:19:46Z","timestamp":1358975986000},"page":"2221-2230","source":"Crossref","is-referenced-by-count":50,"title":["Raman and ROA Spectra of (\u2212)- and (+)-2-Br-Hexahelicene: Experimental and DFT Studies of a \u03c0-Conjugated Chiral System"],"prefix":"10.1021","volume":"117","author":[{"given":"Christian","family":"Johannessen","sequence":"first","affiliation":[{"name":"Faculty of Life Sciences and Manchester Institute of Biotechnology, John Garside Building, University of Manchester, 131 Princess Street, Manchester M1 7DN, U.K."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ewan W.","family":"Blanch","sequence":"additional","affiliation":[{"name":"Faculty of Life Sciences and Manchester Institute of Biotechnology, John Garside Building, University of Manchester, 131 Princess Street, Manchester M1 7DN, U.K."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Claudio","family":"Villani","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica e Tecnologia del Farmaco, Universit\u00e0 degli Studi \u201cLa Sapienza\u201d, P.le Aldo Moro 5, 00185 Roma, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergio","family":"Abbate","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze Biomediche e Biotecnologie, Universit\u00e0 di Brescia, Viale Europa 11, 25123 Brescia, Italy"},{"name":"CNISM Consorzio Interuniversitario per le Scienze Fisiche della Materia, Via della Vasca Navale, 84, 00146 Roma, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Giovanna","family":"Longhi","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze Biomediche e Biotecnologie, Universit\u00e0 di Brescia, Viale Europa 11, 25123 Brescia, Italy"},{"name":"CNISM Consorzio Interuniversitario per le Scienze Fisiche della Materia, Via della Vasca Navale, 84, 00146 Roma, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nisha R.","family":"Agarwal","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Materiali e Ingegneria Chimica \u201cG. Natta\u201d \u2212 Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano, Italy"},{"name":"Consorzio Interuniversitario per la Scienza e Tecnologia dei Materiali (INSTM), Unit\u00e0 di Ricerca del Politecnico di Milano (Dip. CMIC), Piazza Leonardo da Vinci 32, 20133 Milano, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matteo","family":"Tommasini","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Materiali e Ingegneria Chimica \u201cG. Natta\u201d \u2212 Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano, Italy"},{"name":"Consorzio Interuniversitario per la Scienza e Tecnologia dei Materiali (INSTM), Unit\u00e0 di Ricerca del Politecnico di Milano (Dip. CMIC), Piazza Leonardo da Vinci 32, 20133 Milano, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David A.","family":"Lightner","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Nevada, Reno, Nevada 89557, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2013,2,7]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"crossref","first-page":"649","DOI":"10.1002\/anie.197406491","volume":"13","author":"Martin R. H.","year":"1974","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref2\/cit2","doi-asserted-by":"crossref","first-page":"495","DOI":"10.1351\/pac200678020495","volume":"78","author":"Star\u00fd I.","year":"2006","journal-title":"Pure Appl. Chem."},{"key":"ref3\/cit3","doi-asserted-by":"crossref","first-page":"853","DOI":"10.1002\/ejoc.201001110","author":"Ryb\u00e1cek J.","year":"2011","journal-title":"Eur. J. Org. Chem."},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"11752","DOI":"10.1021\/jp0456537","volume":"108","author":"Lebon F.","year":"2004","journal-title":"J. Phys. Chem. A"},{"key":"ref5\/cit5","doi-asserted-by":"crossref","first-page":"3183","DOI":"10.1021\/ja809396f","volume":"131","author":"Graule S.","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref6\/cit6","doi-asserted-by":"crossref","first-page":"1921","DOI":"10.1002\/1521-3773(20000602)39:11<1921::AID-ANIE1921>3.0.CO;2-F","volume":"39","author":"Katz T. J.","year":"2000","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"264","DOI":"10.1021\/ja973366t","volume":"120","author":"Lovinger A. J.","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"913","DOI":"10.1126\/science.282.5390.913","volume":"282","author":"Verbiest T.","year":"1998","journal-title":"Science"},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"1574","DOI":"10.1039\/b9pp00015a","volume":"8","author":"Passeri R.","year":"2009","journal-title":"Photochem. Photobiol. Sci."},{"key":"ref10\/cit10","unstructured":"Moscowitz, A.On Optical Activity- Hexahelicene. Ph.D. Thesis, Harvard University, Cambridge, MA, 1957."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1002\/9780470143506.ch2","volume-title":"Advances in Chemical Physics","author":"Moscowitz A.","year":"1962"},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"161","DOI":"10.1007\/BF01342393","volume":"52","author":"Rosenfeld L.","year":"1928","journal-title":"Z. Phys."},{"key":"ref13\/cit13","doi-asserted-by":"crossref","first-page":"6761","DOI":"10.1021\/ja00828a038","volume":"96","author":"Barron L. D.","year":"1974","journal-title":"J. Am. Chem. Soc."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"293","DOI":"10.1039\/f29757100293","volume":"71","author":"Barron L. D.","year":"1975","journal-title":"J. Chem. Soc., Faraday Trans. 2"},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"124","DOI":"10.1038\/232124a0","volume":"232","author":"Lightner D. A.","year":"1971","journal-title":"Nature (London)"},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"3492","DOI":"10.1021\/ja00765a041","volume":"94","author":"Lightner D. A.","year":"1972","journal-title":"J. Am. Chem. Soc."},{"key":"ref17\/cit17","first-page":"455","volume":"4","author":"Hansen A. E.","year":"1999","journal-title":"Enantiomer"},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"1717","DOI":"10.1021\/ja991960s","volume":"122","author":"Furche E.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"9039","DOI":"10.1039\/b909991c","volume":"11","author":"Abbate S.","year":"2009","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref20\/cit20","doi-asserted-by":"crossref","DOI":"10.1002\/9781119976516","volume-title":"Vibrational Optical Activity \u2013 Principles and Applications","author":"Nafie L. A.","year":"2011"},{"key":"ref21\/cit21","first-page":"97","volume-title":"Circular Dichroism Principles and Applications","author":"Nafie L. A.","year":"2000"},{"key":"ref22\/cit22","volume-title":"Molecular Light Scattering and Optical Activity","author":"Barron L. D.","year":"1982","edition":"2"},{"key":"ref23\/cit23","unstructured":"Barron, L. D.; Hecht, L.Vibrational Raman Optical Activity: From Fundamentals to Biochemical Applications. InCircular Dichroism Principles and Applications;Berova, N.; Nakanishi, K.; Woody, R. W., Eds.Wiley-VCH:New York, 2000; Chapter 23, pp667\u2013701."},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"1111","DOI":"10.1080\/00268977100101091","volume":"20","author":"Barron L. D.","year":"1971","journal-title":"Mol. Phys."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"275","DOI":"10.1002\/9781118120187.ch11","volume-title":"Comprehensive Chiroptical Spectroscopy","volume":"1","author":"Vaccaro P. H.","year":"2012"},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"551","DOI":"10.1080\/00268979709482744","volume":"91","author":"Polavarapu P. L.","year":"1997","journal-title":"Mol. Phys."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"768","DOI":"10.1002\/chir.10145","volume":"14","author":"Polavarapu P. L.","year":"2002","journal-title":"Chirality"},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"8106","DOI":"10.1021\/j100384a024","volume":"94","author":"Polavarapu P. L.","year":"1990","journal-title":"J. Phys. Chem."},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"23","DOI":"10.1016\/0009-2614(82)83545-8","volume":"87","author":"Amos R. D.","year":"1982","journal-title":"Chem. Phys. Lett."},{"key":"ref30\/cit30","unstructured":"Brand, J. C. D.; Speakman, J. C.Molecular Structure. The Physical Approach,2nd ed.Halsted:New York, 1975; p329."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"455","DOI":"10.1080\/00268978000102891","volume":"41","author":"Barnett J. C.","year":"1980","journal-title":"Mol. Phys."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"3302","DOI":"10.1021\/j100322a045","volume":"92","author":"Abbate S.","year":"1988","journal-title":"J. Phys. Chem."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"839","DOI":"10.1080\/00268978200101621","volume":"46","author":"Barron L. D.","year":"1982","journal-title":"Mol. Phys."},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"327","DOI":"10.1080\/00268978800101061","volume":"65","author":"Escribano J. R.","year":"1988","journal-title":"Mol. Phys."},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"63","DOI":"10.1080\/00268976800100051","volume":"14","author":"Buckingham A. D.","year":"1968","journal-title":"Mol. Phys."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"137","DOI":"10.1016\/S0022-2860(99)00431-7","volume":"521","author":"Castiglioni C.","year":"2000","journal-title":"J. Mol. Struct."},{"key":"ref37\/cit37","volume-title":"Molecular Quantum Electrodynamics","author":"Craig D. P.","year":"1984"},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"2425","DOI":"10.1098\/rsta.2004.1448","volume":"362","author":"Castiglioni C.","year":"2004","journal-title":"Philos. Trans. R. Soc. London"},{"key":"ref39\/cit39","first-page":"1","volume":"571","author":"Xu Z.","year":"2011","journal-title":"Nat. Commun."},{"key":"ref40\/cit40","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1002\/9781118120187.ch6","volume-title":"Comprehensive Chiroptical Spectroscopy","volume":"1","author":"Hug W.","year":"2012"},{"key":"ref41\/cit41","unstructured":"Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.Gaussian 09, revision A.02;Gaussian, Inc.:Wallingford, CT, 2009."},{"key":"ref42\/cit42","doi-asserted-by":"crossref","first-page":"1261","DOI":"10.1002\/jcc.21151","volume":"30","author":"Li\u00e9geois V.","year":"2009","journal-title":"J. Comput. Chem."},{"key":"ref43\/cit43","doi-asserted-by":"crossref","first-page":"628","DOI":"10.1016\/j.ssc.2009.12.033","volume":"150","author":"Thomsen C.","year":"2010","journal-title":"Solid State Commun."},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"9973","DOI":"10.1002\/anie.201104345","volume":"50","author":"Merten C.","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref45\/cit45","doi-asserted-by":"crossref","first-page":"375","DOI":"10.1002\/jrs.1250210609","volume":"21","author":"Barron L. D.","year":"1990","journal-title":"J. Raman Spectrosc."},{"key":"ref46\/cit46","doi-asserted-by":"crossref","first-page":"169","DOI":"10.1016\/j.ijms.2008.07.035","volume":"280","author":"Kubala D.","year":"2009","journal-title":"Int. J. Mass Spectrom."},{"key":"ref47\/cit47","doi-asserted-by":"crossref","first-page":"2049","DOI":"10.1002\/cphc.200900255","volume":"10","author":"Luber S.","year":"2009","journal-title":"ChemPhysChem"},{"key":"ref48\/cit48","doi-asserted-by":"crossref","first-page":"3306","DOI":"10.1021\/jp0128473","volume":"106","author":"Negri F.","year":"2002","journal-title":"J. Phys. Chem. A"},{"key":"ref49\/cit49","doi-asserted-by":"crossref","DOI":"10.1007\/3-540-39947-X","volume-title":"Carbon Nanotubes","author":"Dresselhaus M. S.","year":"2001"},{"key":"ref50\/cit50","doi-asserted-by":"crossref","first-page":"8193","DOI":"10.1016\/j.chemphys.2004.02.018","volume":"301","author":"Di Donato E.","year":"2004","journal-title":"Chem. Phys."},{"key":"ref51\/cit51","volume-title":"Chemical Applications of Spectroscopy-Techniques of Organic Chemistry","volume":"9","author":"Jones R. N.","year":"1956"},{"key":"ref52\/cit52","doi-asserted-by":"crossref","first-page":"1326","DOI":"10.1126\/science.1225621","volume":"337","author":"Gross L.","year":"2012","journal-title":"Science"},{"key":"ref53\/cit53","doi-asserted-by":"crossref","first-page":"15079","DOI":"10.1021\/jp207706p","volume":"115","author":"Profant V.","year":"2011","journal-title":"J. Phys. Chem. B"},{"key":"ref54\/cit54","doi-asserted-by":"crossref","first-page":"10185","DOI":"10.1039\/b913660f","volume":"11","author":"Tommasini M.","year":"2009","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref55\/cit55","doi-asserted-by":"crossref","first-page":"11889","DOI":"10.1063\/1.1710853","volume":"120","author":"Negri F.","year":"2004","journal-title":"J. Chem. Phys."},{"key":"ref56\/cit56","doi-asserted-by":"crossref","first-page":"7372","DOI":"10.1021\/jp304576g","volume":"116","author":"Nakai Y.","year":"2012","journal-title":"J. Phys. Chem. A"}],"container-title":["The Journal of Physical Chemistry B"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jp312425m","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,5,5]],"date-time":"2024-05-05T04:20:06Z","timestamp":1714882806000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jp312425m"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,2,7]]},"references-count":56,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2013,2,21]]}},"alternative-id":["10.1021\/jp312425m"],"URL":"https:\/\/doi.org\/10.1021\/jp312425m","relation":{},"ISSN":["1520-6106","1520-5207"],"issn-type":[{"value":"1520-6106","type":"print"},{"value":"1520-5207","type":"electronic"}],"subject":[],"published":{"date-parts":[[2013,2,7]]}}}