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B"},{"key":"ref51\/cit51a","unstructured":"aInoue, Y.; Takehiko, W.Advances in Supramolecular Chemistry;JAI Press Inc.:Greenwich, 1997; Vol.4, pp55\u221296."},{"key":"ref51\/cit51b","doi-asserted-by":"crossref","first-page":"4997","DOI":"10.1021\/ol0616079","volume":"22","author":"Nakashima H.","year":"2006","journal-title":"Org. Lett."},{"key":"ref52\/cit52","unstructured":"In the absence of alcohols, the various factors governing the magnitude of the entropy of activation for guest complexation by CD are rather difficult to visualize, because \u0394Sass\u29e7and \u0394Sdiss\u29e7are related to the change in randomness on passing from reactants or complex, respectively, to the transition state. In general, the following four terms should contribute to the activation entropy: (a) the freezing of motional degrees of freedom for the guest molecule, (b) the desolvation around the guest molecule and the reorganization of solvent water, (c) the release of water molecules from the CD cavity, and (d) any conformational changes of the CD torus. While the first term will be negative, the other ones are expected to contribute positively to the activation entropy. In the presence of alcohol, the picture is even more complicated, because the inclusion and the release of alcohol molecules by CD can significantly modify this picture. For this reason, we preferred to omit any detailed discussion on the activation entropies."}],"container-title":["The Journal of Physical Chemistry A"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jp8051642","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,7]],"date-time":"2023-03-07T04:56:17Z","timestamp":1678164977000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jp8051642"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2008,8,27]]},"references-count":55,"journal-issue":{"issue":"37","published-print":{"date-parts":[[2008,9,18]]}},"alternative-id":["10.1021\/jp8051642"],"URL":"https:\/\/doi.org\/10.1021\/jp8051642","relation":{},"ISSN":["1089-5639","1520-5215"],"issn-type":[{"value":"1089-5639","type":"print"},{"value":"1520-5215","type":"electronic"}],"subject":[],"published":{"date-parts":[[2008,8,27]]}}}