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The Department of Energy Technical Reports, April 18\u201321,2005.http:\/\/www.sc.doe.gov\/bes\/reports\/list.html."},{"key":"ref1\/cit1b","doi-asserted-by":"crossref","first-page":"6668","DOI":"10.1021\/jp0268462","volume":"107","author":"Adams D. M.","year":"2003","journal-title":"J. Phys. Chem. B"},{"key":"ref1\/cit1c","doi-asserted-by":"crossref","first-page":"2834","DOI":"10.1021\/jp066952u","volume":"111","author":"Kamat P. V.","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref1\/cit1d","doi-asserted-by":"crossref","first-page":"52","DOI":"10.1002\/anie.200602373","volume":"46","author":"Armaroli V.","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref1\/cit1e","doi-asserted-by":"crossref","first-page":"411","DOI":"10.1021\/cr00011a004","volume":"92","author":"Koval C. A.","year":"1992","journal-title":"Chem. Rev."},{"key":"ref1\/cit1f","doi-asserted-by":"crossref","first-page":"6900","DOI":"10.1021\/ic051118p","volume":"44","author":"Lewis N. S.","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref2\/cit2a","doi-asserted-by":"crossref","first-page":"143","DOI":"10.1146\/annurev.physchem.58.052306.144054","volume":"58","author":"Duncan W. R.","year":"2007","journal-title":"Annu. Rev. Phys. Chem."},{"key":"ref2\/cit2b","doi-asserted-by":"crossref","first-page":"441","DOI":"10.1021\/ct050141x","volume":"2","author":"Persson P.","year":"2006","journal-title":"J. Chem. Theory Comput."},{"key":"ref2\/cit2c","doi-asserted-by":"crossref","first-page":"20513","DOI":"10.1021\/jp064045j","volume":"110","author":"Lundqvist M. J.","year":"2006","journal-title":"J. Phys. Chem. B"},{"key":"ref3\/cit3a","doi-asserted-by":"crossref","first-page":"6841","DOI":"10.1021\/ic0508371","volume":"44","author":"Gr\u00e4tzel M.","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref3\/cit3b","doi-asserted-by":"crossref","first-page":"347","DOI":"10.1016\/S0010-8545(98)00189-1","volume":"177","author":"Kalyanasundaram K.","year":"1998","journal-title":"Coord. Chem. Rev."},{"key":"ref3\/cit3c","doi-asserted-by":"crossref","first-page":"193","DOI":"10.1146\/annurev.physchem.52.1.193","volume":"52","author":"Nozik A. J.","year":"2001","journal-title":"Annu. Rev. Phys. Chem."},{"key":"ref3\/cit3d","first-page":"6852","volume":"45","author":"Meyer G. J.","year":"2006","journal-title":"Inorg. Chem."},{"key":"ref3\/cit3e","doi-asserted-by":"crossref","first-page":"737","DOI":"10.1038\/353737a0","volume":"353","author":"O\u2019Reagan B.","year":"1991","journal-title":"Nature"},{"key":"ref4\/cit4a","doi-asserted-by":"crossref","first-page":"5259","DOI":"10.1021\/jp069005u","volume":"111","author":"Tachikawa T.","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref4\/cit4b","doi-asserted-by":"crossref","first-page":"341","DOI":"10.1021\/cr00017a016","volume":"93","author":"Fox M. A.","year":"1993","journal-title":"Chem. Rev."},{"key":"ref4\/cit4c","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1038\/238037a0","volume":"238","author":"Fujishima A.","year":"1972","journal-title":"Nature"},{"key":"ref5\/cit5a","doi-asserted-by":"crossref","first-page":"11449","DOI":"10.1021\/jp001763b","volume":"104","author":"Cummins D.","year":"2000","journal-title":"J. Phys. Chem. B"},{"key":"ref5\/cit5b","doi-asserted-by":"crossref","first-page":"3966","DOI":"10.1021\/ic034145t","volume":"42","author":"Biancardo M.","year":"2003","journal-title":"Inorg. Chem."},{"key":"ref5\/cit5c","doi-asserted-by":"crossref","first-page":"1231","DOI":"10.1021\/nl049484d","volume":"4","author":"Choi S. Y.","year":"2004","journal-title":"Nano Lett."},{"key":"ref5\/cit5d","doi-asserted-by":"crossref","first-page":"5017","DOI":"10.1021\/ja00090a069","volume":"116","author":"Marguerettaz X.","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"ref6\/cit6","doi-asserted-by":"crossref","first-page":"1283","DOI":"10.1016\/j.ccr.2004.03.016","volume":"248","author":"Galoppini E.","year":"2004","journal-title":"Coord. Chem. Rev."},{"key":"ref7\/cit7a","doi-asserted-by":"crossref","first-page":"25383","DOI":"10.1021\/jp064436y","volume":"110","author":"Ernstorfer R.","year":"2006","journal-title":"J. Phys. Chem. B"},{"key":"ref7\/cit7b","doi-asserted-by":"crossref","first-page":"13586","DOI":"10.1021\/jp066892s","volume":"111","author":"Gundlach L.","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref7\/cit7c","doi-asserted-by":"crossref","first-page":"2827","DOI":"10.1021\/jp0679257","volume":"111","author":"Myahkostupov M.","year":"2007","journal-title":"J. Phys. Chem. 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Commun."},{"key":"ref8\/cit8o","doi-asserted-by":"crossref","first-page":"410","DOI":"10.1021\/jp055365q","volume":"110","author":"Luo L.","year":"2006","journal-title":"J. Phys. Chem. B"},{"key":"ref8\/cit8p","doi-asserted-by":"crossref","first-page":"3528","DOI":"10.1021\/jp067290b","volume":"111","author":"Eu S.","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref8\/cit8q","doi-asserted-by":"crossref","first-page":"11726","DOI":"10.1021\/jp072927s","volume":"111","author":"Huijser A.","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref8\/cit8r","doi-asserted-by":"crossref","first-page":"11760","DOI":"10.1021\/jp0750598","volume":"111","author":"Campbell W. M.","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref8\/cit8s","doi-asserted-by":"crossref","first-page":"13618","DOI":"10.1021\/jp0726079","volume":"111","author":"Kira A.","year":"2007","journal-title":"J. Phys. Chem. 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Photobiol."},{"key":"ref13\/cit13","unstructured":"The length of the sensitizer-anchoring unit is here defined as the distance between the Zn(II) metal center and the midpoint between the two oxygen atoms of the C\u2212OH bond on the isophthalic acid unit, as shown in Figure2. Due to the unknown binding nature of each Ipa\u2212rod linkers, i.e., at what angle(s) the sensitizers bind with respect to the plane of the metal oxide surface, it is not possible to ascertain their orientation at the semiconductor surface. Therefore the length of the rigid-rod anchoring unit, which is here reported, may not correspond to the effective sensitizer\u2212semiconductordistance."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1002\/(SICI)1099-0682(19990202)1999:2<235::AID-EJIC235>3.0.CO;2-N","author":"Chemseddine A.","year":"1999","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref15\/cit15","doi-asserted-by":"crossref","first-page":"6506","DOI":"10.1021\/jp0570317","volume":"110","author":"Taratula O.","year":"2006","journal-title":"J. Phys. Chem. B"},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"11191","DOI":"10.1021\/ja971678q","volume":"119","author":"Strachan J. P.","year":"1997","journal-title":"J. Am. Chem. Soc."},{"key":"ref17\/cit17","volume-title":"Electrochemical Methods: Fundamentals and Applications","author":"Bard A. J.","year":"2001","edition":"2"},{"key":"ref18\/cit18","doi-asserted-by":"crossref","first-page":"9347","DOI":"10.1021\/jp014589f","volume":"106","author":"Kuciauskas D.","year":"2002","journal-title":"J. Phys. Chem. B"},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"827","DOI":"10.1021\/jo00381a022","volume":"52","author":"Lindsey J. S.","year":"1987","journal-title":"J. Org. Chem."},{"key":"ref20\/cit20","volume-title":"The Porphyrin Handbook","volume":"1","author":"Lindsey J. S.","year":"2000"},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"2974","DOI":"10.1021\/cm9903529","volume":"11","author":"Wagner R. W.","year":"1999","journal-title":"Chem. Mater."},{"key":"ref22\/cit22a","doi-asserted-by":"crossref","first-page":"5111","DOI":"10.1021\/ja01528a024","volume":"81","author":"Thomas D. W.","year":"1959","journal-title":"J. Am. Chem. Soc."},{"key":"ref22\/cit22b","doi-asserted-by":"crossref","first-page":"495","DOI":"10.1002\/jhet.5570030422","volume":"3","author":"Datta-Gupta N.","year":"1966","journal-title":"J. Heterocycl. Chem."},{"key":"ref22\/cit22c","doi-asserted-by":"crossref","first-page":"927","DOI":"10.1002\/jhet.5570060625","volume":"6","author":"Longo F. R.","year":"1969","journal-title":"J. Heterocycl. Chem"},{"key":"ref23\/cit23a","doi-asserted-by":"crossref","first-page":"227","DOI":"10.1016\/S0010-8545(00)80455-5","volume":"33","author":"Deacon G. B.","year":"1980","journal-title":"Coord. Chem. Rev."},{"key":"ref23\/cit23b","doi-asserted-by":"crossref","first-page":"2744","DOI":"10.1021\/la971060u","volume":"14","author":"Finnie K. S.","year":"1998","journal-title":"Langmuir"},{"key":"ref23\/cit23c","doi-asserted-by":"crossref","first-page":"1300","DOI":"10.1021\/jp993583b","volume":"104","author":"Vittadini A.","year":"2000","journal-title":"J. Phys. Chem. B"},{"key":"ref23\/cit23d","doi-asserted-by":"crossref","first-page":"8981","DOI":"10.1021\/jp022656f","volume":"107","author":"Nazeeruddin M. K.","year":"2003","journal-title":"J. Phys. Chem. B"},{"key":"ref24\/cit24","unstructured":"In the classical nomenclature of porphyrin absorption spectra the \u201cSoret\u201d band corresponds to the S0\u2192 S2transition, whereas the Q bands, Q(1,0) and Q(0,0), correspond to the first and lowest vibrational modes of the S0\u2192 S1transition, respectively."},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"5642","DOI":"10.1021\/jp0603637","volume":"110","author":"Sudeep P. K.","year":"2006","journal-title":"J. Phys. Chem. A"},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"222","DOI":"10.1023\/A:1025340804084","volume":"391","author":"Finikova O. S.","year":"2003","journal-title":"Dokl. Chem."},{"key":"ref27\/cit27a","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1016\/S1389-5567(02)00003-5","volume":"3","author":"Aratani N.","year":"2002","journal-title":"J. Photochem. Photobiol., C"},{"key":"ref27\/cit27b","first-page":"1430","author":"Lo C.-F.","year":"2006","journal-title":"Chem. Commun."},{"key":"ref28\/cit28","unstructured":"The Q(0,0)* and Q(1,0)* emission peaks were resolved using OriginLab and integrated to give the \u201cemission quantum efficiency\u201d. The peak of greatest area, i.e., the Q(1,0)* emission peak of ZnTPP\u2212(PE)2\u2212Ipa, was taken as the reference and used to calculate the relative efficiency for all other emission peaks. A similar plot was observed for TiO2(Supporting Information, Figure S-10)."},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"2982","DOI":"10.1021\/ja00713a010","volume":"92","author":"Wolberg A.","year":"1970","journal-title":"J. Am. Chem. Soc."},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"1498","DOI":"10.1021\/jp972890j","volume":"102","author":"Bonh\u00f4te P.","year":"1998","journal-title":"J. Phys. Chem. B"},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"5814","DOI":"10.1021\/jp014192b","volume":"106","author":"Liu G.","year":"2002","journal-title":"J. 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