{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T03:31:33Z","timestamp":1792467093803,"version":"4.5.0"},"reference-count":43,"publisher":"American Chemical Society (ACS)","issue":"15","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Langmuir"],"published-print":{"date-parts":[[2008,8,1]]},"DOI":"10.1021\/la800462u","type":"journal-article","created":{"date-parts":[[2008,7,12]],"date-time":"2008-07-12T05:01:05Z","timestamp":1215838865000},"page":"7931-7938","source":"Crossref","is-referenced-by-count":79,"title":["One-Step Photochemical Attachment of NHS-Terminated Monolayers onto Silicon Surfaces and Subsequent Functionalization"],"prefix":"10.1021","volume":"24","author":[{"given":"Menglong","family":"Yang","sequence":"first","affiliation":[{"name":"Laboratory of Organic Chemistry, Wageningen University and Research Center, Dreijenplein 8, 6703 HB Wageningen, The Netherlands, Department of Organic Chemistry, Radboud University Nijmegen, Toernooiveld 1, 6525 ED Nijmegen, The Netherlands, and Agrotechnology and Food Innovations, Wageningen University and Research Center, Bornsesteeg 59, 6708 PD Wageningen, The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rosalie L. M.","family":"Teeuwen","sequence":"additional","affiliation":[{"name":"Laboratory of Organic Chemistry, Wageningen University and Research Center, Dreijenplein 8, 6703 HB Wageningen, The Netherlands, Department of Organic Chemistry, Radboud University Nijmegen, Toernooiveld 1, 6525 ED Nijmegen, The Netherlands, and Agrotechnology and Food Innovations, Wageningen University and Research Center, Bornsesteeg 59, 6708 PD Wageningen, The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marcel","family":"Giesbers","sequence":"additional","affiliation":[{"name":"Laboratory of Organic Chemistry, Wageningen University and Research Center, Dreijenplein 8, 6703 HB Wageningen, The Netherlands, Department of Organic Chemistry, Radboud University Nijmegen, Toernooiveld 1, 6525 ED Nijmegen, The Netherlands, and Agrotechnology and Food Innovations, Wageningen University and Research Center, Bornsesteeg 59, 6708 PD Wageningen, The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jacob","family":"Baggerman","sequence":"additional","affiliation":[{"name":"Laboratory of Organic Chemistry, Wageningen University and Research Center, Dreijenplein 8, 6703 HB Wageningen, The Netherlands, Department of Organic Chemistry, Radboud University Nijmegen, Toernooiveld 1, 6525 ED Nijmegen, The Netherlands, and Agrotechnology and Food Innovations, Wageningen University and Research Center, Bornsesteeg 59, 6708 PD Wageningen, The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ahmed","family":"Arafat","sequence":"additional","affiliation":[{"name":"Laboratory of Organic Chemistry, Wageningen University and Research Center, Dreijenplein 8, 6703 HB Wageningen, The Netherlands, Department of Organic Chemistry, Radboud University Nijmegen, Toernooiveld 1, 6525 ED Nijmegen, The Netherlands, and Agrotechnology and Food Innovations, Wageningen University and Research Center, Bornsesteeg 59, 6708 PD Wageningen, The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Frits A.","family":"de Wolf","sequence":"additional","affiliation":[{"name":"Laboratory of Organic Chemistry, Wageningen University and Research Center, Dreijenplein 8, 6703 HB Wageningen, The Netherlands, Department of Organic Chemistry, Radboud University Nijmegen, Toernooiveld 1, 6525 ED Nijmegen, The Netherlands, and Agrotechnology and Food Innovations, Wageningen University and Research Center, Bornsesteeg 59, 6708 PD Wageningen, The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jan C. M.","family":"van Hest","sequence":"additional","affiliation":[{"name":"Laboratory of Organic Chemistry, Wageningen University and Research Center, Dreijenplein 8, 6703 HB Wageningen, The Netherlands, Department of Organic Chemistry, Radboud University Nijmegen, Toernooiveld 1, 6525 ED Nijmegen, The Netherlands, and Agrotechnology and Food Innovations, Wageningen University and Research Center, Bornsesteeg 59, 6708 PD Wageningen, The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Han","family":"Zuilhof","sequence":"additional","affiliation":[{"name":"Laboratory of Organic Chemistry, Wageningen University and Research Center, Dreijenplein 8, 6703 HB Wageningen, The Netherlands, Department of Organic Chemistry, Radboud University Nijmegen, Toernooiveld 1, 6525 ED Nijmegen, The Netherlands, and Agrotechnology and Food Innovations, Wageningen University and Research Center, Bornsesteeg 59, 6708 PD Wageningen, The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2008,7,12]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"crossref","first-page":"84","DOI":"10.1016\/j.aca.2005.10.027","volume":"568","author":"Aswal D. K.","year":"2006","journal-title":"Anal. Chim. Acta"},{"key":"ref1\/cit1b","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1021\/cr0684467","volume":"108","author":"Sassolas A.","year":"2008","journal-title":"Chem. Rev."},{"key":"ref2\/cit2","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1002\/1099-0690(200301)2003:1<17::AID-EJOC17>3.0.CO;2-H","author":"Sullivan T. P.","year":"2003","journal-title":"Eur. J. Org. Chem."},{"key":"ref3\/cit3","doi-asserted-by":"crossref","first-page":"1759","DOI":"10.1021\/la971139z","volume":"14","author":"Sieval A. B.","year":"1998","journal-title":"Langmuir"},{"key":"ref4\/cit4a","doi-asserted-by":"crossref","first-page":"1149","DOI":"10.1016\/S0956-5663(02)00249-X","volume":"18","author":"Wei F.","year":"2003","journal-title":"Biosens. Bioelectron."},{"key":"ref4\/cit4b","doi-asserted-by":"crossref","first-page":"361","DOI":"10.1016\/j.snb.2004.04.006","volume":"101","author":"Liao W.","year":"2004","journal-title":"Sens. Actuators, B"},{"key":"ref4\/cit4c","doi-asserted-by":"crossref","first-page":"445","DOI":"10.1016\/j.snb.2005.06.021","volume":"114","author":"Liao W.","year":"2006","journal-title":"Sens. Actuators, B"},{"key":"ref5\/cit5","doi-asserted-by":"crossref","first-page":"4039","DOI":"10.1021\/la035813q","volume":"20","author":"Liu Y.-J.","year":"2004","journal-title":"Langmuir"},{"key":"ref6\/cit6","unstructured":"Roughness of surface after indirect attachment of NHS due to adsorption thereof."},{"key":"ref7\/cit7a","doi-asserted-by":"crossref","unstructured":"aVoicu, R., Boukherroub, R., Bartzoka, V., Ward, T., Wojtyk, J. T. C., and Wayner, D. D. M.Langmuir2004,20, 11713\u201311720.It has been reported that \u201cno reaction occurs between the carboxyl group and the silicon surface\u201d (detailed study in ref 7b), indicating <0.1 monolayer of upside-down addition (ref 7c), and the observed contact angles (>50\u00b0) obtained under these conditions are then largely attributed to the exposure of the otherwise hidden CH2groups in the alkyl chains.","DOI":"10.1021\/la047886v"},{"key":"ref7\/cit7b","doi-asserted-by":"crossref","first-page":"153","DOI":"10.1021\/la052145v","volume":"22","author":"Faucheux A.","year":"2006","journal-title":"Langmuir"},{"key":"ref7\/cit7c","unstructured":"cAllongue, P.Personal communication."},{"key":"ref8\/cit8","doi-asserted-by":"crossref","first-page":"582","DOI":"10.1021\/la0605539","volume":"23","author":"Mendoza S. M.","year":"2007","journal-title":"Langmuir"},{"key":"ref9\/cit9a","doi-asserted-by":"crossref","first-page":"9227","DOI":"10.1021\/la048474p","volume":"20","author":"B\u00f6cking T.","year":"2004","journal-title":"Langmuir"},{"key":"ref9\/cit9b","doi-asserted-by":"crossref","first-page":"6081","DOI":"10.1021\/la015597q","volume":"18","author":"Wojtyk J. T. C.","year":"2002","journal-title":"Langmuir"},{"key":"ref10\/cit10","doi-asserted-by":"crossref","first-page":"e118","DOI":"10.1093\/nar\/gnh113","volume":"32","author":"Yin H. B.","year":"2004","journal-title":"Nucleic Acids Res."},{"key":"ref11\/cit11","unstructured":"Decomposition percentage of the NHS-ester moieties based on detailed XPS analysis of the C narrow spectrum and C\/O ratio in the Supporting Information of ref9a."},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"2514","DOI":"10.1021\/ja045359s","volume":"127","author":"Sun Q.-Y.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref13\/cit13a","doi-asserted-by":"crossref","first-page":"13916","DOI":"10.1021\/ja037445i","volume":"125","author":"De Smet L. C. P. M.","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref13\/cit13b","doi-asserted-by":"crossref","first-page":"1352","DOI":"10.1002\/anie.200352137","volume":"43","author":"Sun Q.-Y.","year":"2004","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref13\/cit13c","doi-asserted-by":"crossref","first-page":"14318","DOI":"10.1021\/ja045777x","volume":"126","author":"Eves B. J.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref13\/cit13d","doi-asserted-by":"crossref","first-page":"24","DOI":"10.1016\/j.apsusc.2005.01.107","volume":"252","author":"De Smet L. C. P. M.","year":"2005","journal-title":"Appl. Surf. Sci."},{"key":"ref13\/cit13e","doi-asserted-by":"crossref","first-page":"8343","DOI":"10.1021\/la701359k","volume":"23","author":"Scheres L.","year":"2007","journal-title":"Langmuir"},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"577","DOI":"10.1016\/S0040-4039(98)02471-X","volume":"40","author":"Macossay J.","year":"1999","journal-title":"Tetrahedron Lett."},{"key":"ref15\/cit15","unstructured":"Frisch, M. J., Trucks, G. W., Schlegel, H. B., Scuseria, G. E., Robb, M. A., Cheeseman, J. R., Montgomery, J. A., Vreven, T., Kudin, K. N., Burant, J. C., Millam, J. M., Iyengar, S. S., Tomasi, J., Barone, V., Mennucci, B., Cossi, M., Scalmani, G., Rega, N., Petersson, G. A., Nakatsuji, H., Hada, M., Ehara, M., Toyota, K., Fukuda, R., Hasegawa, J., Ishida, M., Nakajima, T., Honda, Y., Kitao, O., Nakai, H., Klene, M., Li, X., Knox, J. E., Hratchian, H. P., Cross, J. B., Bakken, V., Adamo, C., Jaramillo, J., Gomperts, R., Stratmann, R. E., Yazyev, O., Austin, A. J., Cammi, R., Pomelli, C., Ochterski, J. W., Ayala, P. Y., Morokuma, K., Voth, G. A., Salvador, P., Dannenberg, J. J., Zakrzewski, V. G., Dapprich, S., Daniels, A. D., Strain, M. C., Farkas, O., Malick, D. K., Rabuck, A. D., Raghavachari, K., Foresman, J. B., Ortiz, J. V., Cui, Q., Baboul, A. G., Clifford, S., Cioslowski, J., Stefanov, B. B., Liu, G., Liashenko, A., Piskorz, P., Komaromi, I., Martin, R. L., Fox, D. J., Keith, T., Al-Laham, M. A., Peng, C. Y., Nanayakkara, A., Challacombe, M., Gill, P. M. W., Johnson, B., Chen, W., Wong, M. W., Gonzalez, C., and Pople, J. A.Gaussian03, revision D.01;Gaussian, Inc.:Wallingford, CT, 2004."},{"key":"ref16\/cit16","unstructured":"Glendening, E. D., Reed, A. E., Carpenter, J. E., and Weinhold, F.NBO, version 3.1."},{"key":"ref17\/cit17a","doi-asserted-by":"crossref","first-page":"20620","DOI":"10.1021\/jp0535689","volume":"109","author":"Guo D.-J.","year":"2005","journal-title":"J. Phys. Chem. B"},{"key":"ref17\/cit17b","doi-asserted-by":"crossref","first-page":"3709","DOI":"10.1021\/ac000472w","volume":"72","author":"Duhachek S. D.","year":"2000","journal-title":"Anal. Chem."},{"key":"ref18\/cit18a","doi-asserted-by":"crossref","first-page":"5145","DOI":"10.1021\/j100223a018","volume":"86","author":"Snyder R. G.","year":"1982","journal-title":"J. Phys. Chem."},{"key":"ref18\/cit18b","doi-asserted-by":"crossref","first-page":"3559","DOI":"10.1021\/ja00246a011","volume":"109","author":"Porter M. D.","year":"1987","journal-title":"J. Am. Chem. Soc."},{"key":"ref19\/cit19","unstructured":"As observable with our XPS set-up. See for highly detailed other XPS analyses of organic monolayers on silicon:"},{"key":"ref19\/cit19a","doi-asserted-by":"crossref","first-page":"7871","DOI":"10.1021\/ja0430797","volume":"127","author":"Wallart X.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref19\/cit19b","doi-asserted-by":"crossref","first-page":"3930","DOI":"10.1021\/jp047199c","volume":"109","author":"Webb L. J.","year":"2005","journal-title":"J. Phys. Chem. B"},{"key":"ref19\/cit19c","doi-asserted-by":"crossref","first-page":"23450","DOI":"10.1021\/jp063366s","volume":"110","author":"Webb L. J.","year":"2006","journal-title":"J. Phys. Chem. B"},{"key":"ref20\/cit20","volume-title":"Surface Analysis by Auger and X-ray Photoelectron Spectroscopy","author":"Brigss D.","year":"2003"},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"104","DOI":"10.1016\/S0031-8914(34)90011-2","volume":"1","author":"Koopmans T.","year":"1933","journal-title":"Physica"},{"key":"ref22\/cit22","doi-asserted-by":"crossref","first-page":"182","DOI":"10.1021\/jp074023c","volume":"112","author":"Tielens F.","year":"2008","journal-title":"J. Phys. Chem. C"},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"1103","DOI":"10.1021\/cr0300789","volume":"105","author":"Love J. C.","year":"2005","journal-title":"Chem. Rev."},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"6282","DOI":"10.1002\/anie.200500633","volume":"44","author":"Onclin S.","year":"2005","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref25\/cit25a","doi-asserted-by":"crossref","first-page":"8600","DOI":"10.1021\/ja0483746","volume":"126","author":"Arafat A.","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref25\/cit25b","doi-asserted-by":"crossref","first-page":"6233","DOI":"10.1021\/la7007045","volume":"23","author":"Arafat A.","year":"2007","journal-title":"Langmuir"},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"4007","DOI":"10.1021\/la704002y","volume":"24","author":"Rosso M.","year":"2008","journal-title":"Langmuir"},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"16866","DOI":"10.1021\/jp0535240","volume":"109","author":"Liu Z.","year":"2005","journal-title":"J. Phys. Chem. B"}],"container-title":["Langmuir"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/la800462u","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,10]],"date-time":"2023-03-10T02:18:31Z","timestamp":1678414711000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/la800462u"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2008,7,12]]},"references-count":43,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2008,8,1]]}},"alternative-id":["10.1021\/la800462u"],"URL":"https:\/\/doi.org\/10.1021\/la800462u","relation":{},"ISSN":["0743-7463","1520-5827"],"issn-type":[{"value":"0743-7463","type":"print"},{"value":"1520-5827","type":"electronic"}],"subject":[],"published":{"date-parts":[[2008,7,12]]}}}