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Chem."},{"key":"ol047698wb00020\/ol047698wb00020_1","unstructured":"For\n                      3\n                      :\u2009 [\u03b1]\n                      22\n                      D\n                      = \u221266 (\n                      c\n                      1.0, CHCl\n                      3\n                      ). Mp:\u2009 > 150 \u00b0C.\n                      1\n                      H NMR (CD\n                      2\n                      Cl\n                      2\n                      , 400 MHz):\u2009 \u03b4 13.61 (s, 1 H), 8.68 (d,\n                      J\n                      = 4 Hz, 1 H), 8.09 (t,\n                      J\n                      = 5 Hz, 2 H), 7.64 (s, 1 H), 7.46 (dd,\n                      J\n                      = 10, 2 Hz, 1 H), 7.41 (d,\n                      J\n                      = 5 Hz, 1 H), 7.37 (s, 2 H), 7.19 (d,\n                      J\n                      = 7 Hz, 1 H), 7.12 (t,\n                      J\n                      = 7 Hz, 1 H), 7.00 (m, 2 H), 6.83 (d,\n                      J\n                      = 10 Hz, 2 H), 4.78 (d,\n                      J\n                      = 9 Hz, 1 H), 4.30 (m, 1 H), 4.04 (s, 3 H), 3.99 (m, 1 H), 3.69 (m, 1 H), 3.58\u22123.48 (m, 4 H), 3.39 (m, 1 H), 3.30 (m, 1 H), 3.20 (m, 2 H), 2.65 (t,\n                      J\n                      = 9 Hz, 1 H), 2.29 (m, 1 H), 2.19 (m, 1 H), 2.08 (m, 3 H), 1.91 (m, 3 H), 1.75 (m, 4 H), 1.38 (m, 1 H), 1.01 (t,\n                      J\n                      = 8 Hz, 3 H) ppm.\n                      13\n                      C NMR (CD\n                      2\n                      Cl\n                      2\n                      , 400 Hz):\u2009 \u03b4 170.61, 162.67, 162.33, 159.86, 155.55, 145.43, 143.50, 131.51, 127.37, 126.83, 124.63, 123.73, 118.83, 118.10, 117.80, 100.76, 71.98, 59.73, 58.89, 56.98, 49.75, 49.52, 48.03, 47.70, 35.22, 30.02, 28.38, 25.48, 24.98, 24.11, 23.80, 18.98, 11.50 ppm.\n                      19\n                      F NMR (CD\n                      2\n                      Cl\n                      2\n                      , 400 Hz): \u221276.06 ppm. FTIR (cm\n                      -\n                      1\n                      , film):\u2009 1660, 1461, 1415, 1187, 1129, 983, 825, 756. HRMS calcd for [C\n                      37\n                      H\n                      43\n                      N\n                      6\n                      O\n                      3\n                      + H\n                      +\n                      ], 619.3396; found, 619.3386."}],"container-title":["Organic Letters"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ol047698w","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,10,17]],"date-time":"2021-10-17T03:10:11Z","timestamp":1634440211000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/ol047698w"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2004,11,26]]},"references-count":35,"journal-issue":{"issue":"26","published-print":{"date-parts":[[2004,12,1]]}},"alternative-id":["10.1021\/ol047698w"],"URL":"https:\/\/doi.org\/10.1021\/ol047698w","relation":{},"ISSN":["1523-7060","1523-7052"],"issn-type":[{"value":"1523-7060","type":"print"},{"value":"1523-7052","type":"electronic"}],"subject":[],"published":{"date-parts":[[2004,11,26]]}}}