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Polar solvents favor the formation of SN1 products, while nonpolar solvents favor SN2 products. Trichloroethylene was identified as the solvent most likely to give SN2 products in both C- and O-glycosylation reactions.<\/jats:p>","DOI":"10.1021\/ol501471c","type":"journal-article","created":{"date-parts":[[2014,7,3]],"date-time":"2014-07-03T12:32:29Z","timestamp":1404390749000},"page":"3684-3687","source":"Crossref","is-referenced-by-count":39,"title":["Solvent Effects in the Nucleophilic Substitutions\nof Tetrahydropyran Acetals Promoted by Trimethylsilyl Trifluoromethanesulfonate:\nTrichloroethylene as Solvent for Stereoselective\n                    <i>C<\/i>\n                    - and\n                    <i>O<\/i>\n                    -Glycosylations"],"prefix":"10.1021","volume":"16","author":[{"given":"Joanna C.","family":"Kendale","sequence":"first","affiliation":[{"name":"New York University , , , ,","place":["New York, New York, United States, 10003"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elizabeth M.","family":"Valenti\u0301n","sequence":"additional","affiliation":[{"name":"New York University , , , ,","place":["New York, New York, United States, 10003"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"K. 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