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However, the key challenge lies in how to reconcile robust performance with efficient depolymerization under mild conditions. This perspective highlights that precise ring-opening (co)polymerization (PROP), enabled by advanced catalytic strategies to exert exacting control over polymer chain architecture, represents a powerful and promising approach. We systematically illustrate how PROP facilitates the rational design of polymers by tailoring molecular parameters such as molecular weight\/dispersity, stereoregularity, and copolymer sequence. This structural precision governs key aggregation state characteristics, including crystallinity, chain packing, and conformational behavior, etc., thereby directly modulating macroscopic material properties and enabling designed recyclability. By summarizing recent PROP-driven advancements, we present a bottom-up synthetic strategy that links polymer microstructure and macroscopic properties. 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