{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T16:37:41Z","timestamp":1792773461408,"version":"4.5.0"},"reference-count":89,"publisher":"American Chemical Society (ACS)","license":[{"start":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T00:00:00Z","timestamp":1792713600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001823","name":"Ministerstvo ??kolstv??, Ml??de??e a Telov??chovy","doi-asserted-by":"publisher","award":["LM2023066"],"award-info":[{"award-number":["LM2023066"]}],"id":[{"id":"10.13039\/501100001823","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001824","name":"Grantov?? Agentura Cesk?? 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Here, we demonstrate that nanoceria efficiently drives the spontaneous, dark hydrolysis of sulfonylureas (amidosulfuron, metsulfuron-methyl, and nicosulfuron) via surface acid\u2013base chemistry under ambient conditions. By combining liquid chromatography\u2013mass spectrometry (LC-HRMS) with density functional theory (DFT) calculations, we show that the degradation proceeds through urea N\u2013C bond cleavage. While the experimental identification of the degradation products confirms the overall hydrolytic pathway, DFT calculations are used to provide unique insights into the specific mechanism, proposing that the reaction is initiated by lattice-oxygen nucleophilic attack leading preferentially to sulfonyl-side N\u2013C bond cleavage. Crucially, solid-state 31P MAS NMR spectroscopy using a trimethylphosphine oxide probe explicitly mapped the distribution and strength of surface Lewis and Br\u00f8nsted acidic sites (oxygen vacancies and bridging hydroxyls). This provides a molecular-level link between ceria defect structures and their unique interfacial reactivity, highlighting the potential of tailored ceria surfaces to drive spontaneous chemical transformations without external energy inputs.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c04712","type":"journal-article","created":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T15:01:57Z","timestamp":1792767717000},"source":"Crossref","is-referenced-by-count":0,"title":["Nanoceria\nas an Acid\u2013Base Catalyst for Interfacial\nHydrolysis of Sulfonylureas: A Combined 31P MAS NMR and\nDFT Study"],"prefix":"10.1021","author":[{"given":"Jan","family":"C\u030cundrle","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry of the Czech Academy of Sciences , ,","place":["Husinec-R\u030cez\u030c, Czechia, 250 68"]},{"name":"Jan Evangelista Purkyne University in U\u0301sti\u0301 nad Labem , , Pasteurova 3632\/15 , ,","place":["U\u0301sti\u0301 nad Labem, Czechia, 400 96"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin","family":"S\u030ct\u2019astny\u0301","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry of the Czech Academy of Sciences , ,","place":["Husinec-R\u030cez\u030c, Czechia, 250 68"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tereza","family":"Dus\u030ckova\u0301","sequence":"additional","affiliation":[{"name":"Jan Evangelista Purkyne University in U\u0301sti\u0301 nad Labem , , Pasteurova 3632\/15 , ,","place":["U\u0301sti\u0301 nad Labem, Czechia, 400 96"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dmytro","family":"Bavol","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry of the Czech Academy of Sciences , ,","place":["Husinec-R\u030cez\u030c, Czechia, 250 68"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniela","family":"Popelkova\u0301","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry of the Czech Academy of Sciences , ,","place":["Husinec-R\u030cez\u030c, Czechia, 250 68"]},{"name":"Charles University Prague , , ,","place":["Vestec, Czech Republic, 252 50"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0282-4196","authenticated-orcid":true,"given":"Jakub","family":"Ederer","sequence":"additional","affiliation":[{"name":"Jan Evangelista Purkyne University in U\u0301sti\u0301 nad Labem , , Pasteurova 3632\/15 , ,","place":["U\u0301sti\u0301 nad Labem, Czechia, 400 96"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nusrat Jahan","family":"Rifat","sequence":"additional","affiliation":[{"name":"Louisiana State University , , , ,","place":["Baton Rouge, Louisiana, United States, 70803"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6406-7832","authenticated-orcid":true,"given":"Ye","family":"Xu","sequence":"additional","affiliation":[{"name":"Louisiana State University , , , ,","place":["Baton Rouge, Louisiana, United States, 70803"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5509-2139","authenticated-orcid":true,"given":"Jir\u030ci\u0301","family":"Henych","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry of the Czech Academy of Sciences , ,","place":["Husinec-R\u030cez\u030c, Czechia, 250 68"]},{"name":"Jan Evangelista Purkyne University in U\u0301sti\u0301 nad Labem , , Pasteurova 3632\/15 , ,","place":["U\u0301sti\u0301 nad Labem, Czechia, 400 96"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,23]]},"reference":[{"issue":"22","key":"2026102311014969600_cit1","doi-asserted-by":"publisher","first-page":"6253","DOI":"10.1021\/jf025575p","article-title":"Hydrolysis of Sulfonylurea Herbicides in Soils and\nAqueous Solutions: A Review","volume":"50","author":"Sarmah","year":"2002","journal-title":"J. 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Ed."},{"issue":"21","key":"2026102311014969600_cit25","doi-asserted-by":"publisher","first-page":"4826","DOI":"10.1002\/cctc.201801220","article-title":"An Unusual Two-Step\nHydrolysis of Nerve Agents by a Nanozyme","volume":"10","author":"Khulbe","year":"2018","journal-title":"ChemCatChem"},{"issue":"9","key":"2026102311014969600_cit26","doi-asserted-by":"publisher","first-page":"3485","DOI":"10.1039\/D2EN00173J","article-title":"How the Surface\nChemical Properties of Nanoceria Are Related to Its Enzyme-like, Antiviral\nand Degradation Activity","volume":"9","author":"Henych","year":"2022","journal-title":"Environ. Sci. Nano"},{"issue":"4","key":"2026102311014969600_cit27","doi-asserted-by":"publisher","first-page":"2298","DOI":"10.1021\/acs.inorgchem.3c04367","article-title":"Ceria-Catalyzed Hydrolytic Cleavage\nof Sulfonamides","volume":"63","author":"Henych","year":"2024","journal-title":"Inorg. 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