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The bromide-containing product was further converted into chloride and azide derivatives, demonstrating its utility as a chiral building block.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01914","type":"journal-article","created":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T20:01:49Z","timestamp":1793131309000},"source":"Crossref","is-referenced-by-count":0,"title":["Enantioselective Synthesis of Halogenated Adamantane-Based Amino Acid Derivatives via Rhodium-Catalyzed C\u2013H Bond Amination"],"prefix":"10.1021","author":[{"given":"Ayana","family":"Sakura","sequence":"first","affiliation":[{"name":"Graduate School of Science, Chiba University , , Yayoi-cho, Inage-ku , ,","place":["Chiba, Japan, 263-8522"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yumiko","family":"Koseki","sequence":"additional","affiliation":[{"name":"Graduate School of Science, Chiba University , , Yayoi-cho, Inage-ku , ,","place":["Chiba, Japan, 263-8522"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daiki","family":"Noguchi","sequence":"additional","affiliation":[{"name":"Graduate School of Science, Chiba University , , Yayoi-cho, Inage-ku , ,","place":["Chiba, Japan, 263-8522"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5130-9479","authenticated-orcid":true,"given":"Kazuhiro","family":"Yoshida","sequence":"additional","affiliation":[{"name":"Graduate School of Science, Chiba University , , Yayoi-cho, Inage-ku , ,","place":["Chiba, Japan, 263-8522"]},{"name":"Chiba University , , Yayoi-cho, Inage-ku , ,","place":["Chiba, Japan, 263-8522"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,27]]},"reference":[{"key":"2026102716014294100_cit1a","doi-asserted-by":"publisher","first-page":"1949","DOI":"10.1016\/j.ejmech.2011.01.047","article-title":"The many faces of the adamantyl group in drug design","volume":"46","author":"Liu","year":"2011","journal-title":"Eur. 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