{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,27]],"date-time":"2026-04-27T20:27:07Z","timestamp":1777321627412,"version":"3.51.4"},"reference-count":58,"publisher":"American Chemical Society (ACS)","issue":"20","license":[{"start":{"date-parts":[[2019,4,5]],"date-time":"2019-04-05T00:00:00Z","timestamp":1554422400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2019,4,5]],"date-time":"2019-04-05T00:00:00Z","timestamp":1554422400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2019,4,5]],"date-time":"2019-04-05T00:00:00Z","timestamp":1554422400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100008530","name":"European Regional Development Fund","doi-asserted-by":"publisher","award":["POCI-01-0145-FEDER-028973"],"award-info":[{"award-number":["POCI-01-0145-FEDER-028973"]}],"id":[{"id":"10.13039\/501100008530","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda??o para a Ci?ncia e a Tecnologia","doi-asserted-by":"publisher","award":["SFRH\/BPD\/86021\/2012"],"award-info":[{"award-number":["SFRH\/BPD\/86021\/2012"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda??o para a Ci?ncia e a Tecnologia","doi-asserted-by":"publisher","award":["POCI-01-0145-FEDER-028973"],"award-info":[{"award-number":["POCI-01-0145-FEDER-028973"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda??o para a Ci?ncia e a Tecnologia","doi-asserted-by":"publisher","award":["UID\/QUI\/0313\/2019"],"award-info":[{"award-number":["UID\/QUI\/0313\/2019"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Phys. Chem. A"],"published-print":{"date-parts":[[2019,5,23]]},"DOI":"10.1021\/acs.jpca.9b01382","type":"journal-article","created":{"date-parts":[[2019,4,5]],"date-time":"2019-04-05T21:16:20Z","timestamp":1554498980000},"page":"4396-4405","source":"Crossref","is-referenced-by-count":31,"title":["Effects of Entangled IR Radiation and Tunneling on the Conformational Interconversion of 2-Cyanophenol"],"prefix":"10.1021","volume":"123","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5953-976X","authenticated-orcid":true,"given":"A. J.","family":"Lopes Jesus","sequence":"first","affiliation":[{"name":"CQC, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal"},{"name":"CQC, Faculty of Pharmacy, University of Coimbra, 3004-295 Coimbra, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8511-1230","authenticated-orcid":true,"given":"Cl\u00e1udio M.","family":"Nunes","sequence":"additional","affiliation":[{"name":"CQC, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5983-7743","authenticated-orcid":true,"given":"I.","family":"Reva","sequence":"additional","affiliation":[{"name":"CQC, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7241-0581","authenticated-orcid":true,"given":"Sandra M. V.","family":"Pinto","sequence":"additional","affiliation":[{"name":"CQC, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal"},{"name":"Scuola Normale Superiore, Piazza dei Cavalieri, 7, I-56124 Pisa, Italy"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8264-6854","authenticated-orcid":true,"given":"R.","family":"Fausto","sequence":"additional","affiliation":[{"name":"CQC, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal"}]}],"member":"316","published-online":{"date-parts":[[2019,4,5]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1039\/c5cp04061b"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1021\/jp010788n"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1039\/c001705a"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1107\/s0108270196009419"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1023\/b:stuc.0000011245.91971.c1"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1021\/j100628a016"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1562\/2005-07-08-ra-605"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/jp908696k"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/jp010218n"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2003.12.040"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201600668"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1016\/0022-2860(84)80141-6"},{"key":"ref13\/cit13","first-page":"51","volume-title":"Physics and Chemistry at Low Temperatures","author":"Fausto R.","year":"2010"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC01052H"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1063\/1.1733892"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1021\/ja972362l"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1021\/ja903211f"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b08588"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1021\/ja038341a"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/jp5051589"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1021\/jp512302s"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1016\/j.vibspec.2003.07.005"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/jp501448m"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1021\/jp509578c"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1063\/1.4795823"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1021\/jp3076436"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1021\/jp400196b"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/jp411423c"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1039\/c0cp00177e"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1063\/1.3683217"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1063\/1.4954894"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1016\/0301-0104(83)85062-9"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1063\/1.4944528"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b02605"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1063\/1.1521429"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1039\/c6cc01756h"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1021\/ja107531y"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1021\/jp503633m"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1016\/s0009-2614(02)00379-2"},{"key":"ref40\/cit40","unstructured":"Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.  GAUSSIAN 09, Revision D.01; Gaussian, Inc.: Wallingford CT, 2013."},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1103\/physreva.38.3098"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1103\/physrevb.37.785"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1139\/p80-159"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1103\/physrev.46.618"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1063\/1.453520"},{"key":"ref46\/cit46","unstructured":"Zhurko, G. A. C., Version 1.8. http:\/\/www.chemcraftprog.com, 2016 (last accessed on January, 2019)."},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1063\/1.1824881"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1063\/1.3695210"},{"key":"ref49\/cit49","unstructured":"Glendening, E. D.; Reed, A. E.; Carpenter, J. E.; Weinhold, F. NBO, Version 3.1. Gaussian Inc., Pittsburgh,2003"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1021\/jp025713d"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1021\/jp0572737"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1039\/b610962d"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1063\/1.3484943"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1021\/jp105044r"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1039\/b503644e"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1063\/1.3666018"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1063\/1.4754435"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1021\/jp0225065"}],"container-title":["The Journal of Physical Chemistry A"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jpca.9b01382","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,16]],"date-time":"2023-04-16T11:29:17Z","timestamp":1681644557000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.jpca.9b01382"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,4,5]]},"references-count":58,"journal-issue":{"issue":"20","published-print":{"date-parts":[[2019,5,23]]}},"alternative-id":["10.1021\/acs.jpca.9b01382"],"URL":"https:\/\/doi.org\/10.1021\/acs.jpca.9b01382","relation":{},"ISSN":["1089-5639","1520-5215"],"issn-type":[{"value":"1089-5639","type":"print"},{"value":"1520-5215","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,4,5]]}}}