{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,7]],"date-time":"2026-05-07T02:51:35Z","timestamp":1778122295478,"version":"3.51.4"},"reference-count":51,"publisher":"American Chemical Society (ACS)","issue":"3","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Crystal Growth &amp; Design"],"published-print":{"date-parts":[[2008,3,1]]},"DOI":"10.1021\/cg7010315","type":"journal-article","created":{"date-parts":[[2008,2,8]],"date-time":"2008-02-08T06:01:30Z","timestamp":1202450490000},"page":"782-785","source":"Crossref","is-referenced-by-count":56,"title":["An Infinite Two-Dimensional Hybrid Water\u2212Chloride Network, Self-Assembled in a Hydrophobic Terpyridine Iron(II) Matrix"],"prefix":"10.1021","volume":"8","author":[{"given":"Ricardo R.","family":"Fernandes","sequence":"first","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Complexo I, Instituto Superior T\u00e9cnico, TU-Lisbon, Av. Rovisco Pais, 1049-001 Lisbon, Portugal, and Universidade Lus\u00f3fona de Humanidades e Tecnologias, Av. do Campo Grande, 376, 1749-024, Lisbon, Portugal"}]},{"given":"Alexander M.","family":"Kirillov","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Complexo I, Instituto Superior T\u00e9cnico, TU-Lisbon, Av. Rovisco Pais, 1049-001 Lisbon, Portugal, and Universidade Lus\u00f3fona de Humanidades e Tecnologias, Av. do Campo Grande, 376, 1749-024, Lisbon, Portugal"}]},{"given":"M. F\u00e1tima C. Guedes","family":"da Silva","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Complexo I, Instituto Superior T\u00e9cnico, TU-Lisbon, Av. Rovisco Pais, 1049-001 Lisbon, Portugal, and Universidade Lus\u00f3fona de Humanidades e Tecnologias, Av. do Campo Grande, 376, 1749-024, Lisbon, Portugal"}]},{"given":"Zhen","family":"Ma","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Complexo I, Instituto Superior T\u00e9cnico, TU-Lisbon, Av. Rovisco Pais, 1049-001 Lisbon, Portugal, and Universidade Lus\u00f3fona de Humanidades e Tecnologias, Av. do Campo Grande, 376, 1749-024, Lisbon, Portugal"}]},{"given":"Jos\u00e9 A. L.","family":"da Silva","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Complexo I, Instituto Superior T\u00e9cnico, TU-Lisbon, Av. Rovisco Pais, 1049-001 Lisbon, Portugal, and Universidade Lus\u00f3fona de Humanidades e Tecnologias, Av. do Campo Grande, 376, 1749-024, Lisbon, Portugal"}]},{"given":"Jo\u00e3o J. R. Fra\u00fasto","family":"da Silva","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Complexo I, Instituto Superior T\u00e9cnico, TU-Lisbon, Av. Rovisco Pais, 1049-001 Lisbon, Portugal, and Universidade Lus\u00f3fona de Humanidades e Tecnologias, Av. do Campo Grande, 376, 1749-024, Lisbon, Portugal"}]},{"given":"Armando J. L.","family":"Pombeiro","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Complexo I, Instituto Superior T\u00e9cnico, TU-Lisbon, Av. Rovisco Pais, 1049-001 Lisbon, Portugal, and Universidade Lus\u00f3fona de Humanidades e Tecnologias, Av. do Campo Grande, 376, 1749-024, Lisbon, Portugal"}]}],"member":"316","published-online":{"date-parts":[[2008,2,8]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"crossref","first-page":"32","DOI":"10.1002\/anie.200501839","volume":"45","author":"Mascal M.","year":"2006","journal-title":"Angew. Chem., Int. 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B."},{"key":"ref3\/cit3b","doi-asserted-by":"crossref","first-page":"7036","DOI":"10.1063\/1.1360200","volume":"114","author":"Tobias D. J.","year":"2001","journal-title":"J. Chem. Phys."},{"key":"ref3\/cit3c","doi-asserted-by":"crossref","first-page":"503","DOI":"10.1021\/jp9729425","volume":"102","author":"Choi J. H.","year":"1998","journal-title":"J. Phys. Chem. A."},{"key":"ref3\/cit3d","doi-asserted-by":"crossref","first-page":"9703","DOI":"10.1021\/jp960779s","volume":"100","author":"Xantheas S. S.","year":"1996","journal-title":"J. Phys. Chem."},{"key":"ref3\/cit3e","doi-asserted-by":"crossref","first-page":"9344","DOI":"10.1063\/1.467965","volume":"101","author":"Markovich G.","year":"1994","journal-title":"J. Chem. Phys."},{"key":"ref3\/cit3f","doi-asserted-by":"crossref","first-page":"2851","DOI":"10.1063\/1.467231","volume":"100","author":"Combariza J. E.","year":"1994","journal-title":"J. Chem. Phys."},{"key":"ref3\/cit3g","doi-asserted-by":"crossref","first-page":"1954","DOI":"10.1063\/1.460992","volume":"95","author":"Perera L.","year":"1991","journal-title":"J. Chem. Phys."},{"key":"ref3\/cit3h","doi-asserted-by":"crossref","first-page":"2481","DOI":"10.1021\/ja00007a021","volume":"113","author":"Dang L. X.","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"ref4\/cit4a","doi-asserted-by":"crossref","first-page":"16362","DOI":"10.1021\/ja055528o","volume":"127","author":"Custelcean R.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref4\/cit4b","doi-asserted-by":"crossref","first-page":"4621","DOI":"10.1002\/ejic.200700462","author":"Kopylovich M. N.","year":"2007","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref4\/cit4c","doi-asserted-by":"crossref","first-page":"7550","DOI":"10.1002\/anie.200603547","volume":"45","author":"Butchard J. R.","year":"2006","journal-title":"Angew. Chem., Int. 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Des."},{"key":"ref5\/cit5f","doi-asserted-by":"crossref","first-page":"743","DOI":"10.1021\/cg0505719","volume":"6","author":"Deshpande M. S.","year":"2006","journal-title":"Cryst. Growth Des."},{"key":"ref6\/cit6a","doi-asserted-by":"crossref","first-page":"2200","DOI":"10.1021\/cg060310e","volume":"6","author":"Karabach Y. Y.","year":"2006","journal-title":"Cryst. Growth Des."},{"key":"ref6\/cit6b","author":"Kirillova M. V.","year":"2008","journal-title":"Inorg. Chim. Acta"},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"380","DOI":"10.1107\/S0108768102003890","volume":"58","author":"Allen F. H.","year":"2002","journal-title":"Acta Crystallogr."},{"key":"ref8\/cit8","unstructured":"The searching algorithm in the ConQuest Version 1.9 (CSD version 5.28, August 2007) constrained to the presence of any terpyridine moiety and at least one crystallization water molecule and one chloride counter ion resulted in 43 analyzable hits from which 40 compounds contain diverse water-chloride aggregates (there are 29 and 11 examples of infinite (mostly 1D) networks and discrete clusters, respectively). See theSupporting Informationfor the CSD refcodes."},{"key":"ref9\/cit9","doi-asserted-by":"crossref","first-page":"246","DOI":"10.1039\/B601166G","volume":"36","author":"Constable E. C.","year":"2007","journal-title":"Chem. Soc. Rev."},{"key":"ref10\/cit10a","doi-asserted-by":"crossref","first-page":"456","DOI":"10.1039\/B703622A","volume":"9","author":"Beves J. E.","year":"2007","journal-title":"CrystEngComm"},{"key":"ref10\/cit10b","doi-asserted-by":"crossref","first-page":"2345","DOI":"10.1021\/ic061927o","volume":"46","author":"Zhou X.-P.","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref10\/cit10c","doi-asserted-by":"crossref","first-page":"588","DOI":"10.1016\/j.ica.2006.08.004","volume":"360","author":"Shi W.-J.","year":"2007","journal-title":"Inorg. Chim. Acta"},{"key":"ref10\/cit10d","doi-asserted-by":"crossref","first-page":"1073","DOI":"10.1039\/b710332h","volume":"9","author":"Beves J. E.","year":"2007","journal-title":"CrystEngComm"},{"key":"ref10\/cit10e","doi-asserted-by":"crossref","first-page":"1185","DOI":"10.1016\/j.inoche.2007.07.005","volume":"10","author":"Beves J. E.","year":"2007","journal-title":"Inorg. Chem. Commun."},{"key":"ref10\/cit10f","doi-asserted-by":"crossref","first-page":"353","DOI":"10.1039\/B702560B","volume":"9","author":"Beves J. E.","year":"2007","journal-title":"CrystEngComm"},{"key":"ref11\/cit11","unstructured":"Synthesis of1: FeCl2\u00b72H2O (82 mg, 0.50 mmol) and 4\u2032-phenyl-2,2\u2032:6\u2032,2\u2033-terpyridine (L) (154 mg, 0.50 mmol) were combined in a THF (20 mL) solution with continuous stirring at room temperature. The resulting deep purple suspension was stirred for 1 h, filtered off, washed with THF (3 \u00d7 15 mL), and dried in vacuo to afford a deep purple solid1(196 mg, 41%).1exhibits a high affinity for water and upon recrystallization gives derivatives with a higher varying content of crystallization water.1is soluble in H2O, MeOH, EtOH, MeCN, CH2Cl2, and CHCl3. mp > 305 \u00b0C (dec.). Elemental analysis. Found: C 52.96, H 3.76, N 8.36. Calcld. for C42H40Cl4Fe2N6O5: C 52.42, H 4.19, N 8.73. FAB+-MS:m\/z: 835 {[FeL2]Cl2\u00b75H2O + H}+, 816 {[FeL2]Cl2\u00b74H2O}+, 796 {[FeL2]Cl2\u00b73H2O \u2013 2H}+, 781 {[FeL2]Cl2\u00b72H2O + H}+, 763 {[FeL2]Cl2\u00b7H2O + H}+, 709 {[FeL2]Cl}+, 674 {[FeL2]}+, 435 {[FeL]Cl2}+, 400 {[FeL]Cl}+, 364 {[FeL] \u2013 H}+, 311 {L \u2013 2H}+. IR (KBr): \u03bdmax\/cm\u20131: 3462 (m br) \u03bd(H2O), 3060 (w), 2968 (w) and 2859 (w) \u03bd(CH), 1656 (m br) \u03b4(H2O), 1611 (s), 1538 (w), 1466 (m), 1416 (s), 1243 (m), 1159 (w), 1058 (m), 877 (s), 792 (s), 766 (vs), 896 (m), 655 (w), 506 (m) and 461 (m) (other bands). The X-ray quality crystals of [FeL2]Cl2\u00b710H2O (1\u2032) were grown by slow evaporation, in air at ca. 20 \u00b0C, of a MeOH\/H2O (v\/v = 9\/1) solution of1."},{"key":"ref12\/cit12","unstructured":"Crystal data:1\u2032: C42H50Cl2FeN6O10, M = 925.63, triclinic,a= 10.1851(10),b= 12.2125(13),c= 19.5622(19) \u00c5,\u03b1= 76.602(6),\u03b2= 87.890(7),\u03b3= 67.321(6)\u00b0,U= 2180.3(4) \u00c53,T= 150(2) K, space groupP1\u0305,Z= 2,\u03bc(Mo-K\u03b1) = 0.532 mm\u22121, 32310 reflections measured, 8363 unique (Rint= 0.0719) which were used in all calculations,R1= 0.0469,wR2= 0.0952,R1 = 0.0943,wR2 = 0.1121 (all data)."},{"key":"ref13\/cit13a","doi-asserted-by":"crossref","first-page":"230","DOI":"10.1039\/B500989H","volume":"7","author":"McMurtrie J.","year":"2005","journal-title":"CrystEngComm"},{"key":"ref13\/cit13b","doi-asserted-by":"crossref","first-page":"7953","DOI":"10.1021\/ma0300802","volume":"36","author":"Nakayama Y.","year":"2003","journal-title":"Macromolecules"},{"key":"ref13\/cit13c","doi-asserted-by":"crossref","first-page":"791","DOI":"10.1021\/cg0340392","volume":"3","author":"Kabir M. K.","year":"2003","journal-title":"Cryst. Growth Des."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"1808","DOI":"10.1002\/1521-3773(20010518)40:10<1808::AID-ANIE1808>3.0.CO;2-1","volume":"40","author":"Ludwig R.","year":"2001","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref15\/cit15","unstructured":"The searching algorithm in the ConQuest Version 1.9 (CSD version 5.28, May 2007) was constrained to the presence of (i) at least one tetranuclear [(H2O)3(Cl)]\u2013ring (i.e., minimal cyclic fragment in our water-chloride network) withd(O\u00b7\u00b7\u00b7O) = 2.2\u20133.2 \u00c5 andd(O\u00b7\u00b7\u00b7Cl) = 2.6\u20133.6 \u00c5, and (ii) at least one crystallization water molecule and one chloride counter ion. All symmetry-related contacts were taken into consideration."},{"key":"ref16\/cit16","unstructured":"For 2D networks with the [(H2O)3(Cl)]\u2013core, see the CSD refcodes: AGETAH, AMIJAH, BEXVIJ, EXOWIX, FANJUA, GAFGIE, HIQCIT, LUNHUX, LUQCEF, PAYBEW, TESDEB, TXCDNA, WAQREL, WIXVUU, ZUHCOW. For 3D network, see the CSD refcode: LUKZEW."},{"key":"ref17\/cit17","unstructured":"This analysis was run on1since we were unable to get1\u2032 in a sufficient amount due to the varying content of crystallization water in the samples obtained upon recrystallization of1."},{"key":"ref18\/cit18a","doi-asserted-by":"crossref","first-page":"187","DOI":"10.1021\/cg050263a","volume":"6","author":"Das S.","year":"2006","journal-title":"Cryst. Growth. Des."},{"key":"ref18\/cit18b","doi-asserted-by":"crossref","first-page":"357","DOI":"10.1021\/cg050388f","volume":"6","author":"Wang J.","year":"2006","journal-title":"Cryst. Growth. Des."},{"key":"ref18\/cit18c","doi-asserted-by":"crossref","first-page":"3856","DOI":"10.1021\/ic050102w","volume":"44","author":"Ghosh S. K.","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref19\/cit19","unstructured":"A temperature below 305 \u00b0C has been used to avoid the eventual decomposition of the compound upon rather prolonged heating."}],"container-title":["Crystal Growth &amp; Design"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/cg7010315","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,10,4]],"date-time":"2021-10-04T10:56:15Z","timestamp":1633344975000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/cg7010315"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2008,2,8]]},"references-count":51,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2008,3,1]]}},"alternative-id":["10.1021\/cg7010315"],"URL":"https:\/\/doi.org\/10.1021\/cg7010315","relation":{},"ISSN":["1528-7483","1528-7505"],"issn-type":[{"value":"1528-7483","type":"print"},{"value":"1528-7505","type":"electronic"}],"subject":[],"published":{"date-parts":[[2008,2,8]]}}}