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J.","year":"1994","journal-title":"Neuroreport"},{"key":"ref7\/cit7","doi-asserted-by":"crossref","first-page":"1108","DOI":"10.1529\/biophysj.105.073783","volume":"91","author":"Coelho Neto J.","year":"2006","journal-title":"Biophys. J."},{"key":"ref8\/cit8a","doi-asserted-by":"crossref","first-page":"398","DOI":"10.1021\/ja056370a","volume":"128","author":"Haidekkar M. A.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref8\/cit8b","doi-asserted-by":"crossref","first-page":"227","DOI":"10.1038\/nprot.2006.455","volume":"2","author":"Fischer D.","year":"2007","journal-title":"Nat. Protoc."},{"key":"ref8\/cit8c","doi-asserted-by":"crossref","first-page":"935","DOI":"10.1023\/A:1004144623480","volume":"67","author":"Bondarev S. L.","year":"2000","journal-title":"J. Appl. Spectrosc."},{"key":"ref8\/cit8d","doi-asserted-by":"crossref","first-page":"6474","DOI":"10.1002\/chem.200700106","volume":"13","author":"Rosspeintner A.","year":"2007","journal-title":"Chem.\u2014Eur. 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Photobiol."},{"key":"ref9\/cit9e","doi-asserted-by":"crossref","first-page":"3835","DOI":"10.1021\/jp013319u","volume":"106","author":"Geddes C. D.","year":"2002","journal-title":"J. Phys. Chem. B"},{"key":"ref10\/cit10a","doi-asserted-by":"crossref","first-page":"E145","DOI":"10.1038\/35078615","volume":"3","author":"Reits E. A. J.","year":"2001","journal-title":"Nat. Cell Biol."},{"key":"ref10\/cit10b","doi-asserted-by":"crossref","first-page":"1140","DOI":"10.1016\/S0006-3495(96)79316-5","volume":"71","author":"Swaminathan R.","year":"1996","journal-title":"Biophys. J."},{"key":"ref10\/cit10c","doi-asserted-by":"crossref","first-page":"265","DOI":"10.1111\/j.1751-1097.1996.tb03023.x","volume":"63","author":"Periasamy N.","year":"1996","journal-title":"Photochem. Photobiol."},{"key":"ref10\/cit10d","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1007\/BF00257504","volume":"15","author":"Vaz W. L. C.","year":"1987","journal-title":"Eur. Biophys. J."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"1669","DOI":"10.1039\/B618415D","volume":"5","author":"Haidekker M. A.","year":"2007","journal-title":"Org. Biomol. Chem."},{"key":"ref12\/cit12a","doi-asserted-by":"crossref","first-page":"3995","DOI":"10.1021\/jp0224719","volume":"107","author":"Lu J.","year":"2003","journal-title":"J. Phys. Chem. A"},{"key":"ref12\/cit12b","doi-asserted-by":"crossref","first-page":"6114","DOI":"10.1021\/bi00368a042","volume":"25","author":"Kung C. E.","year":"1986","journal-title":"Biochemistry"},{"key":"ref12\/cit12c","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1016\/0009-2614(93)85641-Z","volume":"214","author":"Lang M.","year":"1993","journal-title":"Chem. Phys. Lett."},{"key":"ref12\/cit12d","doi-asserted-by":"crossref","first-page":"329","DOI":"10.1016\/j.cplett.2006.06.027","volume":"426","author":"Gutkowski K. I.","year":"2006","journal-title":"Chem. Phys. Lett."},{"key":"ref13\/cit13a","doi-asserted-by":"crossref","first-page":"4205","DOI":"10.1021\/j100218a023","volume":"86","author":"Loutfy R. O.","year":"1982","journal-title":"J. Phys. Chem."},{"key":"ref13\/cit13b","doi-asserted-by":"crossref","first-page":"2803","DOI":"10.1021\/j100458a027","volume":"84","author":"Loutfy R. O.","year":"1980","journal-title":"J. Phys. Chem."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"3035","DOI":"10.1039\/b507165h","volume":"7","author":"Allen B. D.","year":"2005","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref15\/cit15","unstructured":"Bodipy dyes have been developed by Molecular Probes (Invitrogen) for numerous sensing applications (seehttp:\/\/probes.invitrogen.com). For reviews of other uses for bodipy dyes, see:"},{"key":"ref15\/cit15a","doi-asserted-by":"crossref","first-page":"496","DOI":"10.1039\/b617972j","volume":"31","author":"Ziessel R.","year":"2007","journal-title":"New J. Chem."},{"key":"ref15\/cit15b","doi-asserted-by":"crossref","first-page":"4891","DOI":"10.1021\/cr078381n","volume":"107","author":"Loudet A.","year":"2007","journal-title":"Chem. Rev."},{"key":"ref15\/cit15c","doi-asserted-by":"crossref","first-page":"1184","DOI":"10.1002\/anie.200702070","volume":"47","author":"Ulrich G.","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref16\/cit16","doi-asserted-by":"crossref","first-page":"968","DOI":"10.1021\/ja992630a","volume":"122","author":"Rurack K.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ref16\/cit16b","doi-asserted-by":"crossref","first-page":"6956","DOI":"10.1021\/ja042414o","volume":"127","author":"Yamada K.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref16\/cit16c","doi-asserted-by":"crossref","first-page":"10464","DOI":"10.1021\/ja052574f","volume":"127","author":"Coskun A.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref16\/cit16d","doi-asserted-by":"crossref","first-page":"1089","DOI":"10.1039\/b504408a","volume":"29","author":"Malval J.-P.","year":"2005","journal-title":"New J. Chem."},{"key":"ref16\/cit16e","doi-asserted-by":"crossref","first-page":"1842","DOI":"10.1021\/ja066789g","volume":"129","author":"Oleynik P.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref17\/cit17","doi-asserted-by":"crossref","first-page":"20433","DOI":"10.1021\/jp0525078","volume":"109","author":"Kee H. L.","year":"2005","journal-title":"J. Phys. Chem. B"},{"key":"ref18\/cit18","unstructured":"A small series of bodipy-based dyes have been evaluated for probing viscosity; the increase in fluorescence lifetime, however, by changing the solvent from water to a micelle environment is only ca. 30%. See:"},{"key":"ref18\/cit18a","doi-asserted-by":"crossref","first-page":"195","DOI":"10.1021\/bc025600x","volume":"14","author":"Buschmann V.","year":"2003","journal-title":"Bioconjugate Chem."},{"key":"ref19\/cit19a","doi-asserted-by":"crossref","first-page":"41","DOI":"10.1007\/s00348-003-0620-2","volume":"35","author":"Quintella C. M.","year":"2003","journal-title":"J. Expt. Fluids"},{"key":"ref19\/cit19b","doi-asserted-by":"crossref","DOI":"10.1002\/3527600248","volume-title":"Molecular Fluorescence","author":"Valeur B.","year":"2001"},{"key":"ref20\/cit20","volume-title":"Organic Solvents","author":"Riddick J. A.","year":"1986","edition":"4"},{"key":"ref21\/cit21","doi-asserted-by":"crossref","first-page":"1207","DOI":"10.1002\/cphc.200700060","volume":"8","author":"Harriman A.","year":"2007","journal-title":"ChemPhysChem"},{"key":"ref22\/cit22a","doi-asserted-by":"crossref","first-page":"1511","DOI":"10.1016\/S0006-3495(02)73921-0","volume":"83","author":"Dahim M.","year":"2002","journal-title":"Biophys. J."},{"key":"ref22\/cit22b","first-page":"253","volume":"122","author":"Ji D.","year":"2006","journal-title":"J. Lumin."},{"key":"ref22\/cit22c","doi-asserted-by":"crossref","first-page":"3191","DOI":"10.1002\/ejoc.200700190","author":"Harriman A.","year":"2007","journal-title":"Eur. J. Org. Chem."},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"7994","DOI":"10.1021\/jp054992c","volume":"110","author":"Harriman A.","year":"2006","journal-title":"J. Phys. Chem. A"},{"key":"ref24\/cit24a","doi-asserted-by":"crossref","first-page":"306","DOI":"10.1002\/recl.19770961205","volume":"96","author":"Vos de Wael E.","year":"1977","journal-title":"Recl. Trav. Chim. Pays-Bas"},{"key":"ref24\/cit24b","doi-asserted-by":"crossref","first-page":"10211","DOI":"10.1021\/jp982701c","volume":"102","author":"Kollmannsberger M.","year":"1998","journal-title":"J. Phys. Chem. A"},{"key":"ref24\/cit24c","doi-asserted-by":"crossref","first-page":"7736","DOI":"10.1021\/jp0209897","volume":"106","author":"Costela A.","year":"2002","journal-title":"J. Phys. Chem. A"},{"key":"ref24\/cit24d","doi-asserted-by":"crossref","first-page":"7371","DOI":"10.1021\/jp052626n","volume":"109","author":"Qin W.","year":"2005","journal-title":"J. Phys. Chem. A"},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"7366","DOI":"10.1002\/chem.200500373","volume":"11","author":"Ziessel R.","year":"2005","journal-title":"Chem.\u2014Eur. J."},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"814","DOI":"10.1063\/1.1733166","volume":"37","author":"Strickler S. J.","year":"1962","journal-title":"J. Chem. Phys."},{"key":"ref27\/cit27","doi-asserted-by":"crossref","first-page":"42","DOI":"10.1166\/sl.2005.003","volume":"3","author":"Haidekker M. A.","year":"2005","journal-title":"Sens. Lett."},{"key":"ref28\/cit28","doi-asserted-by":"crossref","first-page":"7500","DOI":"10.1016\/S0021-9258(17)40995-1","volume":"252","author":"Dale R. E.","year":"1977","journal-title":"J. Biol. Chem."},{"key":"ref29\/cit29","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1080\/01442358709353399","volume":"6","author":"Baggi B.","year":"1987","journal-title":"Int. Rev. Phys. Chem."},{"key":"ref30\/cit30","doi-asserted-by":"crossref","first-page":"234509","DOI":"10.1063\/1.1940050","volume":"122","author":"Petravic J.","year":"2005","journal-title":"J. Chem. Phys."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"977","DOI":"10.1063\/1.1702361","volume":"23","author":"Gutmann F.","year":"1952","journal-title":"J. Appl. Phys."},{"key":"ref32\/cit32","doi-asserted-by":"crossref","first-page":"74511","DOI":"10.1063\/1.1851510","volume":"122","author":"Schmelzer J. W. P.","year":"2005","journal-title":"J. Chem. Phys."},{"key":"ref33\/cit33","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1098\/rspa.1972.0170","volume":"331","author":"Paul G. R.","year":"1972","journal-title":"Proc. R. Soc. London, Ser. A"},{"key":"ref34\/cit34","doi-asserted-by":"crossref","first-page":"204503","DOI":"10.1063\/1.2110068","volume":"123","author":"Grocholski B.","year":"2005","journal-title":"J. Chem. Phys."},{"key":"ref35\/cit35","doi-asserted-by":"crossref","first-page":"57","DOI":"10.2307\/20026138","volume":"61","author":"Bridgman P. W.","year":"1926","journal-title":"Proc. Am. Acad. Arts Sci."},{"key":"ref36\/cit36","doi-asserted-by":"crossref","first-page":"66105","DOI":"10.1063\/1.2043253","volume":"98","author":"Kapoor K.","year":"2005","journal-title":"J. Appl. Phys."},{"key":"ref37\/cit37","doi-asserted-by":"crossref","first-page":"562","DOI":"10.1016\/j.cplett.2005.12.098","volume":"420","author":"Qin W.","year":"2006","journal-title":"Chem. Phys. Lett."},{"key":"ref38\/cit38","doi-asserted-by":"crossref","first-page":"11914","DOI":"10.1103\/PhysRevB.39.11914","volume":"39","author":"Narger U.","year":"1989","journal-title":"Phys. Rev. B"},{"key":"ref39\/cit39","doi-asserted-by":"crossref","first-page":"125204","DOI":"10.1103\/PhysRevB.67.125204","volume":"67","author":"Guha S.","year":"2003","journal-title":"Phys. Rev. B"},{"key":"ref40\/cit40","doi-asserted-by":"crossref","first-page":"9729","DOI":"10.1021\/ic060921w","volume":"45","author":"Harriman A.","year":"2006","journal-title":"Inorg. Chem."},{"key":"ref41\/cit41","doi-asserted-by":"crossref","first-page":"145","DOI":"10.1080\/00268977000100171","volume":"18","author":"Englman R.","year":"1970","journal-title":"Mol. Phys."},{"key":"ref42\/cit42","doi-asserted-by":"crossref","first-page":"7532","DOI":"10.1063\/1.1676122","volume":"120","author":"Matyushov D. V.","year":"2004","journal-title":"J. Chem. Phys."},{"key":"ref43\/cit43","doi-asserted-by":"crossref","first-page":"204503","DOI":"10.1063\/1.2110068","volume":"123","author":"Grocholski B.","year":"2005","journal-title":"J. Chem. Phys."},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"74511","DOI":"10.1063\/1.1851510","volume":"122","author":"Schmelzer J. W. P.","year":"2005","journal-title":"J. Chem. Phys."},{"key":"ref45\/cit45","doi-asserted-by":"crossref","first-page":"313","DOI":"10.1039\/b300873h","volume":"128","author":"Mann T. L.","year":"2003","journal-title":"The Analyst"},{"key":"ref46\/cit46","doi-asserted-by":"crossref","first-page":"4856","DOI":"10.1063\/1.452656","volume":"86","author":"Ben-Amotz D.","year":"1987","journal-title":"J. Chem. Phys."},{"key":"ref47\/cit47","doi-asserted-by":"crossref","first-page":"1581","DOI":"10.1021\/ja01589a021","volume":"78","author":"Oster G.","year":"1956","journal-title":"J. Am. Chem. Soc."},{"key":"ref48\/cit48","doi-asserted-by":"crossref","first-page":"63","DOI":"10.1524\/zpch.1971.75.1_2.063","volume":"75","author":"F\u00f6rster T.","year":"1971","journal-title":"Z. Phys. Chem N.F."},{"key":"ref49\/cit49","doi-asserted-by":"crossref","first-page":"7375","DOI":"10.1063\/1.444729","volume":"78","author":"Bagchi B.","year":"1983","journal-title":"J. Chem. Phys."},{"key":"ref50\/cit50","doi-asserted-by":"crossref","first-page":"389","DOI":"10.1016\/0301-0104(79)85222-2","volume":"44","author":"McCaskill J. S.","year":"1979","journal-title":"Chem. 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