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The molecular features of the Co complex of3a\u00b7Lare very similar to those of3a(see Table S1 and Figures S2 and S3 ofSupporting Information)."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"9610","DOI":"10.1021\/ja0634167","volume":"128","author":"Arnold P. L.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref15\/cit15a","doi-asserted-by":"crossref","first-page":"1100","DOI":"10.1021\/ic50111a037","volume":"11","author":"Wei C. H.","year":"1972","journal-title":"Inorg. Chem."},{"key":"ref15\/cit15b","doi-asserted-by":"crossref","first-page":"636","DOI":"10.1021\/ic051433b","volume":"45","author":"Reid S. D.","year":"2006","journal-title":"Inorg. Chem."},{"key":"ref16\/cit16","unstructured":"Results from a search carried out in the Cambridge Structural Database using the program ConQuest, developed by the CCDC."},{"key":"ref17\/cit17a","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison A. 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However, the trend is maintained if the other isomers are considered: WICo\u2212P= 0.231(3a,S= 3\/2)\/0.224(3b,S= 3\/2), WICo-O= 0.040(4a,S= 1\/2)\/0.056 (4b,S= 1\/2)."},{"key":"ref29\/cit29","unstructured":"Obtained by means of a Natural Population Analysis (NPA)."},{"key":"ref30\/cit30","unstructured":"Calculated Co NPA charges: 1.23 (3aS= 1\/2), 1.23 (3bS= 1\/2), 1.30 (4aS= 1\/2), 1.30 (4bS= 1\/2), 1.47 (3aS= 3\/2), 1.49 (3bS= 3\/2), 1.57 (4aS= 3\/2), 1.58 (4bS= 3\/2)."},{"key":"ref31\/cit31","doi-asserted-by":"crossref","first-page":"1115","DOI":"10.3891\/acta.chem.scand.17-1115","volume":"17","author":"Jensen K. A.","year":"1963","journal-title":"Acta Chem. Scand."},{"key":"ref32\/cit32a","doi-asserted-by":"crossref","first-page":"944","DOI":"10.1002\/cber.19751080327","volume":"108","author":"Klein H. F.","year":"1975","journal-title":"Chem. Ber."},{"key":"ref32\/cit32b","unstructured":"bHerrman, W. 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