{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T17:01:28Z","timestamp":1790182888137,"version":"4.1.0"},"reference-count":72,"publisher":"American Chemical Society (ACS)","issue":"37","license":[{"start":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T00:00:00Z","timestamp":1788480000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T00:00:00Z","timestamp":1788480000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T00:00:00Z","timestamp":1788480000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RS-2024-00348577"],"award-info":[{"award-number":["RS-2024-00348577"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RS-2024-00399165"],"award-info":[{"award-number":["RS-2024-00399165"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RS-2024-00399739"],"award-info":[{"award-number":["RS-2024-00399739"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RS-2024-00415940"],"award-info":[{"award-number":["RS-2024-00415940"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RS-2024-00421181"],"award-info":[{"award-number":["RS-2024-00421181"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010446","name":"Institute for Basic Science","doi-asserted-by":"publisher","award":["IBS-R006-D1"],"award-info":[{"award-number":["IBS-R006-D1"]}],"id":[{"id":"10.13039\/501100010446","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002551","name":"Seoul National University","doi-asserted-by":"publisher","award":["0458-20240094"],"award-info":[{"award-number":["0458-20240094"]}],"id":[{"id":"10.13039\/501100002551","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,23]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Control of the local reaction environment at electrified interfaces is central to electrocatalysis, yet this principle has rarely been integrated into electro-organic synthesis. Electro-organic transformations are not governed by electron transfer alone; reaction turnover is often coupled to ion transfer and, in particular, proton transfer across aqueous, mixed, and nonaqueous media. Under high-rate operation, these fluxes polarize proton activity near electrodes. Although such concentration polarization is expected to be widespread and consequential, it has been largely neglected in electrosynthesis design. Here we establish a mechanistically distinct, oxygen-driven electrosynthetic pathway for Baeyer\u2013Villiger oxidation (BVO) and use it to develop a local-pH design framework for electro-organic synthesis. Isotope labeling shows that O2 supplies the inserted oxygen atom, and radical trapping, operando EPR spectroscopy, rotating ring\u2013disk electrode analysis, and H2O2-additivity experiments support a paired mechanism in which O2-derived hydroperoxyl-radical equivalents enter acetonitrile-assisted oxygen transfer while anodic oxidation of electrogenerated H2O2 sustains radical flux. This productive pathway is intrinsically coupled to proton activity: the proton-coupled electrode reactions that generate oxygenating equivalents also impose local pH gradients that attenuate reactive oxygen species availability, divert ketone substrates through \u03b1-enolization\/tautomerization, and accelerate lactone hydrolysis under nominally neutral bulk conditions. Electrometric local pH estimations, together with molecular \u03b1-deuteration reporters and transport simulations, link these local pH swings to reaction performance. By tuning electrode spacing and convective flow, these opposing proton-activity gradients are attenuated, enabling high-yield BVO across diverse ketones at elevated substrate loading. The same local-pH control strategy is further extended to electrochemical epoxidation.<\/jats:p>","DOI":"10.1021\/jacs.6c12994","type":"journal-article","created":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T17:02:27Z","timestamp":1788541347000},"page":"40243-40254","source":"Crossref","is-referenced-by-count":0,"title":["Local pH Control Promotes\nOxygen-Atom Transfer Electrosynthesis"],"prefix":"10.1021","volume":"148","author":[{"given":"Seonghyeon","family":"Min","sequence":"first","affiliation":[{"name":"Seoul National University (SNU) , , ,","place":["Seoul, Republic of Korea, 08826"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junghoon","family":"Lee","sequence":"additional","affiliation":[{"name":"Seoul National University (SNU) , , ,","place":["Seoul, Republic of Korea, 08826"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanju","family":"Kim","sequence":"additional","affiliation":[{"name":"Seoul National University (SNU) , , ,","place":["Seoul, Republic of Korea, 08826"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-7301-4220","authenticated-orcid":true,"given":"Jaeyune","family":"Ryu","sequence":"additional","affiliation":[{"name":"Seoul National University (SNU) , , ,","place":["Seoul, Republic of Korea, 08826"]},{"name":"Center for Nanocrystal Research, Institute for Basic Science (IBS) , ,","place":["Seoul, Republic of Korea, 08826"]},{"name":"Seoul National University (SNU) , , ,","place":["Seoul, Republic of Korea, 08826"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,4]]},"reference":[{"key":"2026092311080221600_cit1","doi-asserted-by":"publisher","first-page":"2265","DOI":"10.1021\/cr0680843","article-title":"Modern Strategies in\nElectroorganic Synthesis","volume":"108","author":"Yoshida","year":"2008","journal-title":"Chem. Rev."},{"key":"2026092311080221600_cit2","doi-asserted-by":"publisher","first-page":"12386","DOI":"10.1039\/D0SC01848A","article-title":"Electro-organic\nsynthesis \u2013 a 21st century technique","volume":"11","author":"Pollok","year":"2020","journal-title":"Chem. Sci."},{"key":"2026092311080221600_cit3","doi-asserted-by":"publisher","first-page":"415","DOI":"10.1021\/acscentsci.0c01532","article-title":"Organic Electrochemistry:\nMolecular Syntheses with Potential","volume":"7","author":"Zhu","year":"2021","journal-title":"ACS Cent.\nSci."},{"key":"2026092311080221600_cit4","doi-asserted-by":"publisher","first-page":"11269","DOI":"10.1021\/acs.chemrev.3c00158","article-title":"Electrochemical Late-Stage Functionalization","volume":"123","author":"Wang","year":"2023","journal-title":"Chem. Rev."},{"key":"2026092311080221600_cit5","doi-asserted-by":"publisher","first-page":"7941","DOI":"10.1039\/D1CS00223F","article-title":"Electrocatalysis as an enabling technology\nfor organic synthesis","volume":"50","author":"Novaes","year":"2021","journal-title":"Chem. Soc. Rev."},{"key":"2026092311080221600_cit6","doi-asserted-by":"publisher","first-page":"13230","DOI":"10.1021\/acs.chemrev.7b00397","article-title":"Synthetic\nOrganic Electrochemical\nMethods Since 2000: On the Verge of a Renaissance","volume":"117","author":"Yan","year":"2017","journal-title":"Chem. Rev."},{"key":"2026092311080221600_cit7","doi-asserted-by":"publisher","first-page":"2492","DOI":"10.1039\/c3cs60464k","article-title":"Redox catalysis in organic electrosynthesis:\nbasic\nprinciples and recent developments","volume":"43","author":"Francke","year":"2014","journal-title":"Chem. Soc.\nRev."},{"key":"2026092311080221600_cit8","doi-asserted-by":"publisher","first-page":"3180","DOI":"10.1021\/acs.chemrev.1c00614","article-title":"Advances on the\nMerger of Electrochemistry and Transition Metal Catalysis for Organic\nSynthesis","volume":"122","author":"Malapit","year":"2022","journal-title":"Chem. Rev."},{"key":"2026092311080221600_cit9","doi-asserted-by":"publisher","first-page":"7559","DOI":"10.1021\/ja101578m","article-title":"Inner-Sphere\nHeterogeneous Electrode Reactions. Electrocatalysis and Photocatalysis:\nThe Challenge","volume":"132","author":"Bard","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"2026092311080221600_cit10","doi-asserted-by":"publisher","first-page":"57","DOI":"10.1038\/nmat4738","article-title":"Energy and fuels\nfrom electrochemical interfaces","volume":"16","author":"Stamenkovic","year":"2017","journal-title":"Nat. Mater."},{"key":"2026092311080221600_cit11","doi-asserted-by":"publisher","first-page":"1900","DOI":"10.1021\/acs.accounts.2c00080","article-title":"Electrolyte Effects\non CO2 Electrochemical Reduction to CO","volume":"55","author":"Marcandalli","year":"2022","journal-title":"Acc. Chem. Res."},{"key":"2026092311080221600_cit12","doi-asserted-by":"publisher","first-page":"1074","DOI":"10.1126\/science.abg6582","article-title":"CO2 Electrolysis to Multicarbon\nProducts in Strong Acid","volume":"372","author":"Huang","year":"2021","journal-title":"Science"},{"key":"2026092311080221600_cit13","doi-asserted-by":"publisher","first-page":"2022","DOI":"10.1039\/D3CS00669G","article-title":"Local reaction environment\nin electrocatalysis","volume":"53","author":"Chen","year":"2024","journal-title":"Chem. Soc. Rev."},{"key":"2026092311080221600_cit14","doi-asserted-by":"publisher","first-page":"198","DOI":"10.1038\/s41929-019-0235-5","article-title":"Rational catalyst\nand electrolyte design for CO2 electroreduction towards\nmulticarbon products","volume":"2","author":"Gao","year":"2019","journal-title":"Nat. Catal."},{"key":"2026092311080221600_cit15","doi-asserted-by":"publisher","first-page":"3001","DOI":"10.1039\/C9EE01341E","article-title":"Understanding\ncation effects in electrochemical\nCO2 reduction","volume":"12","author":"Ringe","year":"2019","journal-title":"Energy Environ. Sci."},{"key":"2026092311080221600_cit16","doi-asserted-by":"publisher","DOI":"10.1002\/ntls.20210036","article-title":"The interface is\na tunable dimension in electricity-driven\norganic synthesis","volume":"1","author":"Wuttig","year":"2021","journal-title":"Nat. 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Electrochem."},{"key":"2026092311080221600_cit20","doi-asserted-by":"publisher","first-page":"4296","DOI":"10.1021\/jacs.4c14420","article-title":"Molecular\nProcesses That Control Organic Electrosynthesis\nin Near-Electrode Microenvironments","volume":"147","author":"Mathison","year":"2025","journal-title":"J. Am.\nChem. Soc."},{"key":"2026092311080221600_cit21","doi-asserted-by":"publisher","first-page":"5004","DOI":"10.1021\/cr0500030","article-title":"Proton-Coupled Electron Transfer","volume":"107","author":"Huynh","year":"2007","journal-title":"Chem. Rev."},{"key":"2026092311080221600_cit22","doi-asserted-by":"publisher","first-page":"5870","DOI":"10.1021\/ja067950q","article-title":"Concerted Proton\u2013Electron\nTransfer Reactions in Water. Are the Driving Force and Rate Constant\nDepending on pH When Water Acts as Proton Donor or Acceptor?","volume":"129","author":"Costentin","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"2026092311080221600_cit23","doi-asserted-by":"publisher","first-page":"2017","DOI":"10.1021\/acs.chemrev.1c00374","article-title":"Photochemical and Electrochemical\nApplications of Proton-Coupled Electron Transfer in Organic Synthesis","volume":"122","author":"Murray","year":"2022","journal-title":"Chem. Rev."},{"key":"2026092311080221600_cit24","doi-asserted-by":"publisher","first-page":"7050","DOI":"10.1021\/jacs.2c10212","article-title":"Bonds over\nElectrons: Proton-Coupled Electron Transfer at Solid\u2013Solution\nInterfaces","volume":"145","author":"Mayer","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"2026092311080221600_cit25","volume-title":"Electrochemical Methods:\nFundamentals and Applications","author":"Bard","year":"2022","edition":"3"},{"key":"2026092311080221600_cit26","doi-asserted-by":"publisher","first-page":"14834","DOI":"10.1021\/jacs.5b08259","article-title":"Mesostructure-Induced\nSelectivity in CO2 Reduction Catalysis","volume":"137","author":"Hall","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"2026092311080221600_cit27","doi-asserted-by":"publisher","DOI":"10.1016\/j.coelec.2020.100649","article-title":"Measuring local pH in electrochemistry","volume":"25","author":"Monteiro","year":"2021","journal-title":"Curr. Opin. Electrochem."},{"key":"2026092311080221600_cit28","doi-asserted-by":"publisher","first-page":"1055","DOI":"10.1021\/acselectrochem.5c00489","article-title":"The Role of\nLocal pH in Electrocatalysis: Measurement, Impact, and Control Strategies","volume":"2","author":"Rodriguez-Acosta","year":"2026","journal-title":"ACS Electrochem."},{"key":"2026092311080221600_cit29","doi-asserted-by":"publisher","DOI":"10.1016\/j.coelec.2025.101728","article-title":"Local pH\nengineering to impact electrocatalysis","volume":"53","author":"Decker","year":"2025","journal-title":"Curr.\nOpin. Electrochem."},{"key":"2026092311080221600_cit30","doi-asserted-by":"publisher","first-page":"13384","DOI":"10.1021\/jacs.0c01123","article-title":"Polarization-Induced Local pH Swing Promotes Pd-Catalyzed\nCO2 Hydrogenation","volume":"142","author":"Ryu","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"2026092311080221600_cit31","doi-asserted-by":"publisher","first-page":"28925","DOI":"10.1021\/jacs.4c09521","article-title":"A Straightforward\nModel for Quantifying Local pH Gradients\nGoverning the Oxygen Evolution Reaction","volume":"146","author":"Veroneau","year":"2024","journal-title":"J.\nAm. Chem. Soc."},{"key":"2026092311080221600_cit32","doi-asserted-by":"publisher","first-page":"81","DOI":"10.1126\/science.adf4762","article-title":"Overcoming the limitations\nof Kolbe coupling with waveform-controlled electrosynthesis","volume":"380","author":"Hioki","year":"2023","journal-title":"Science"},{"key":"2026092311080221600_cit33","doi-asserted-by":"publisher","first-page":"277","DOI":"10.1038\/s41570-024-00589-z","article-title":"Electrochemical\nhydrogenation and oxidation of organic species involving water","volume":"8","author":"Liu","year":"2024","journal-title":"Nat. Rev. Chem."},{"key":"2026092311080221600_cit34","doi-asserted-by":"publisher","first-page":"8967","DOI":"10.1039\/D1SC01272J","article-title":"Directing\ntransition\nmetal-based oxygen-functionalization catalysis","volume":"12","author":"Tomboc","year":"2021","journal-title":"Chem. Sci."},{"key":"2026092311080221600_cit35","doi-asserted-by":"publisher","first-page":"6413","DOI":"10.1021\/jacs.9b02345","article-title":"Epoxidation\nof Cyclooctene Using Water as the Oxygen\nAtom Source at Manganese Oxide Electrocatalysts","volume":"141","author":"Jin","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"2026092311080221600_cit36","doi-asserted-by":"publisher","first-page":"13438","DOI":"10.1021\/jacs.4c02601","article-title":"Highly selective electrochemical Baeyer\u2013Villiger oxidation\nthrough oxygen atom transfer from water","volume":"146","author":"Mu","year":"2024","journal-title":"J.\nAm. Chem. Soc."},{"key":"2026092311080221600_cit37","doi-asserted-by":"publisher","first-page":"4149","DOI":"10.1021\/acscatal.1c06013","article-title":"Electrochemical Formation and Activation\nof Hydrogen Peroxide from Water on Fluorinated Tin Oxide for Baeyer\u2013Villiger\nOxidation Reactions","volume":"12","author":"Herman","year":"2022","journal-title":"ACS Catal."},{"key":"2026092311080221600_cit38","doi-asserted-by":"publisher","first-page":"49","DOI":"10.1126\/science.adh4355","article-title":"Direct propylene\nepoxidation via water activation over\nPd-Pt electrocatalysts","volume":"383","author":"Chung","year":"2024","journal-title":"Science"},{"key":"2026092311080221600_cit39","doi-asserted-by":"publisher","first-page":"22734","DOI":"10.1021\/jacs.2c10764","article-title":"Controlling the Hydrophilicity of\nthe Electrochemical\nInterface to Modulate the Oxygen-Atom Transfer in Electrocatalytic\nEpoxidation Reactions","volume":"144","author":"Dorchies","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026092311080221600_cit40","doi-asserted-by":"publisher","first-page":"1482","DOI":"10.1021\/jacs.4c08948","article-title":"Alkene Epoxidation and Oxygen Evolution\nReactions Compete\nfor Reactive Surface Oxygen Atoms on Gold Anodes","volume":"147","author":"Ghosh","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026092311080221600_cit41","doi-asserted-by":"publisher","first-page":"3629","DOI":"10.1021\/jacsau.4c00585","article-title":"Interfacial Anion-Induced Dispersion of Active Species for Efficient\nElectrochemical Baeyer\u2013Villiger Oxidation","volume":"4","author":"Cha","year":"2024","journal-title":"JACS Au"},{"key":"2026092311080221600_cit42","doi-asserted-by":"publisher","first-page":"5750","DOI":"10.1021\/acscatal.0c00931","article-title":"Kinetic analysis\nof electrochemical lactonization of ketones using water as the oxygen\natom source","volume":"10","author":"Maalouf","year":"2020","journal-title":"ACS Catal."},{"key":"2026092311080221600_cit43","doi-asserted-by":"publisher","first-page":"3029","DOI":"10.1021\/acs.chemrev.5b00407","article-title":"Superoxide\nIon: Generation and Chemical\nImplications","volume":"116","author":"Hayyan","year":"2016","journal-title":"Chem. Rev."},{"key":"2026092311080221600_cit44","doi-asserted-by":"publisher","first-page":"173","DOI":"10.1126\/science.adk5097","article-title":"Synthetic\ndioxygenase reactivity\nby pairing electrochemical oxygen reduction and water oxidation","volume":"383","author":"Hoque","year":"2024","journal-title":"Science"},{"key":"2026092311080221600_cit45","doi-asserted-by":"publisher","first-page":"716","DOI":"10.1038\/s41929-022-00826-y","article-title":"Linear paired electrochemical valorization\nof glycerol enabled by the electro-Fenton process using a stable NiSe2 cathode","volume":"5","author":"Sheng","year":"2022","journal-title":"Nat. Catal."},{"key":"2026092311080221600_cit46","doi-asserted-by":"publisher","first-page":"22687","DOI":"10.1021\/jacs.6c02719","article-title":"Unlocking\nMulti-Product Selectivity in Olefin Electro-oxidation through Cooperative\nCation\/Oxygen Species Modulation","volume":"148","author":"Cha","year":"2026","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026092311080221600_cit47","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202500546","article-title":"Interfacial\nLithium Cations Catalyze Biomimetic Aerobic Oxygenation via Short-Range\nElectrostatic Interaction","volume":"64","author":"Cha","year":"2025","journal-title":"Angew. Chem., Int.\nEd."},{"key":"2026092311080221600_cit48","doi-asserted-by":"publisher","first-page":"4791","DOI":"10.1039\/D6CC00041J","article-title":"Cathodic Oxygen-Reduction-Reaction-Mediated\nActive Peroxide for Oxidizing Cyclohexanone to \u03b5-Caprolactone","volume":"62","author":"Chen","year":"2026","journal-title":"Chem. Commun."},{"key":"2026092311080221600_cit49","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-28346-0","article-title":"Manipulating the oxygen\nreduction reaction pathway on Pt-coordinated\nmotifs","volume":"13","author":"Zhao","year":"2022","journal-title":"Nat. Commun."},{"key":"2026092311080221600_cit50","doi-asserted-by":"publisher","first-page":"3594","DOI":"10.1021\/acs.chemrev.5b00462","article-title":"Recent advances\nin\nelectrocatalysts for oxygen reduction reaction","volume":"116","author":"Shao","year":"2016","journal-title":"Chem. Rev."},{"key":"2026092311080221600_cit51","doi-asserted-by":"publisher","first-page":"4994","DOI":"10.1021\/ja00535a029","article-title":"Spin trapping. Kinetics of the reaction\nof superoxide and hydroxyl radicals with nitrones","volume":"102","author":"Finkelstein","year":"1980","journal-title":"J. Am. Chem. Soc."},{"key":"2026092311080221600_cit52","doi-asserted-by":"publisher","first-page":"11302","DOI":"10.1021\/acs.chemrev.7b00161","article-title":"Generation and detection of reactive oxygen species\nin photocatalysis","volume":"117","author":"Nosaka","year":"2017","journal-title":"Chem. Rev."},{"key":"2026092311080221600_cit53","doi-asserted-by":"publisher","first-page":"513","DOI":"10.1063\/1.555805","article-title":"Critical Review\nof Rate Constants for Reactions of Hydrated Electrons, Hydrogen Atoms\nand Hydroxyl Radicals (\u00b7OH\/\u00b7O\u2013) in Aqueous\nSolution","volume":"17","author":"Buxton","year":"1988","journal-title":"J. Phys. Chem. Ref. Data"},{"key":"2026092311080221600_cit54","doi-asserted-by":"publisher","first-page":"255","DOI":"10.1021\/ar020230d","article-title":"Bond Dissociation\nEnergies of Organic Molecules","volume":"36","author":"Blanksby","year":"2003","journal-title":"Acc. Chem. Res."},{"key":"2026092311080221600_cit55","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-018-29075-5","article-title":"Generation of hydroxyl\nradicals from reactions between a dimethoxyhydroquinone and iron oxide\nnanoparticles","volume":"8","author":"Lyngsie","year":"2018","journal-title":"Sci. Rep."},{"key":"2026092311080221600_cit56","doi-asserted-by":"publisher","first-page":"659","DOI":"10.1021\/jo01062a004","article-title":"Reactions of hydrogen\nperoxide. VII.\nAlkali-catalyzed epoxidation and oxidation using a nitrile as co-reactant","volume":"26","author":"Payne","year":"1961","journal-title":"J. Org. Chem."},{"key":"2026092311080221600_cit57","doi-asserted-by":"publisher","first-page":"1088","DOI":"10.1021\/acs.analchem.5b04346","article-title":"Rotating Ring-Disk Electrode Method\nfor the Detection of Solution Phase Superoxide as a Reaction Intermediate\nof Oxygen Reduction in Neutral Aqueous Solutions","volume":"88","author":"Feng","year":"2016","journal-title":"Anal. Chem."},{"key":"2026092311080221600_cit58","doi-asserted-by":"publisher","first-page":"234","DOI":"10.1038\/s41929-023-00924-5","article-title":"Supramolecular tuning of supported metal phthalocyanine\ncatalysts for hydrogen peroxide electrosynthesis","volume":"6","author":"Lee","year":"2023","journal-title":"Nat. Catal."},{"key":"2026092311080221600_cit59","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-14272-1","article-title":"Atomically\ndispersed Pt\u2013N4 sites\nas efficient and selective electrocatalysts for the chlorine evolution\nreaction","volume":"11","author":"Lim","year":"2020","journal-title":"Nat. Commun."},{"key":"2026092311080221600_cit60","volume-title":"Organic Chemistry","author":"Bruice","year":"2016","edition":"8"},{"key":"2026092311080221600_cit61","doi-asserted-by":"publisher","first-page":"756","DOI":"10.1021\/ja00980a005","article-title":"A Nuclear\nMagnetic Resonance Study of the Reversible\nHydration of Aliphatic Aldehydes and Ketones. II. The Acid-Catalyzed\nOxygen Exchange of Acetaldehyde","volume":"89","author":"Greenzaid","year":"1967","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026092311080221600_cit62","doi-asserted-by":"publisher","first-page":"1146","DOI":"10.1021\/ja01033a019","article-title":"Mechanism of acid-catalyzed enolization of ketones","volume":"91","author":"Lienhard","year":"1969","journal-title":"J. Am. Chem. Soc."},{"key":"2026092311080221600_cit63","doi-asserted-by":"publisher","first-page":"413","DOI":"10.1063\/1.555854","article-title":"Rate Constants for Reactions of Peroxyl\nRadicals in Fluid Solutions","volume":"19","author":"Neta","year":"1990","journal-title":"J. Phys. Chem.\nRef. Data"},{"key":"2026092311080221600_cit64","doi-asserted-by":"publisher","first-page":"1041","DOI":"10.1063\/1.555739","article-title":"Reactivity of HO2\/O2\u2013 Radicals in Aqueous Solution","volume":"14","author":"Bielski","year":"1985","journal-title":"J. Phys. Chem. Ref. 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