{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T19:58:43Z","timestamp":1776369523915,"version":"3.51.2"},"reference-count":64,"publisher":"American Chemical Society (ACS)","issue":"36","license":[{"start":{"date-parts":[[2019,8,19]],"date-time":"2019-08-19T00:00:00Z","timestamp":1566172800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2019,8,19]],"date-time":"2019-08-19T00:00:00Z","timestamp":1566172800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2019,8,19]],"date-time":"2019-08-19T00:00:00Z","timestamp":1566172800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001655","name":"Deutscher Akademischer Austauschdienst","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001655","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008530","name":"European Regional Development Fund","doi-asserted-by":"publisher","award":["POCI-01-0145-FEDER-028973"],"award-info":[{"award-number":["POCI-01-0145-FEDER-028973"]}],"id":[{"id":"10.13039\/501100008530","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007215","name":"Verband der Chemischen Industrie","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100007215","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda??o para a Ci?ncia e a Tecnologia","doi-asserted-by":"publisher","award":["UID\/QUI\/0313\/2019"],"award-info":[{"award-number":["UID\/QUI\/0313\/2019"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda??o para a Ci?ncia e a Tecnologia","doi-asserted-by":"publisher","award":["SFRH\/BPD\/86021\/2012"],"award-info":[{"award-number":["SFRH\/BPD\/86021\/2012"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2019,9,11]]},"DOI":"10.1021\/jacs.9b06869","type":"journal-article","created":{"date-parts":[[2019,8,19]],"date-time":"2019-08-19T10:22:51Z","timestamp":1566210171000},"page":"14340-14348","source":"Crossref","is-referenced-by-count":66,"title":["Competitive Nitrogen versus Carbon Tunneling"],"prefix":"10.1021","volume":"141","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8511-1230","authenticated-orcid":true,"given":"Cl\u00e1udio M.","family":"Nunes","sequence":"first","affiliation":[{"name":"CQC, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal"}]},{"given":"Andr\u00e9 K.","family":"Eckhardt","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17, 35392 Giessen, Germany"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5983-7743","authenticated-orcid":true,"given":"Igor","family":"Reva","sequence":"additional","affiliation":[{"name":"CQC, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8264-6854","authenticated-orcid":true,"given":"Rui","family":"Fausto","sequence":"additional","affiliation":[{"name":"CQC, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3608-5515","authenticated-orcid":true,"given":"Peter R.","family":"Schreiner","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17, 35392 Giessen, Germany"}]}],"member":"316","published-online":{"date-parts":[[2019,8,19]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"crossref","DOI":"10.1007\/978-3-662-05900-5","volume-title":"Atom Tunneling Phenomena in Physics, Chemistry and Biology","author":"Miyazaki T.","year":"2004"},{"key":"ref2\/cit2","first-page":"415","volume-title":"Reviews of Reactive Intermediate Chemistry","author":"Sheridan R. S.","year":"2006"},{"key":"ref3\/cit3","volume-title":"The Tunnel Effect in Chemistry","author":"Bell R. P."},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2016.09.029"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/cr400400p"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1692"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1039\/c2ob07170c"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/cr1001035"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1038\/nature07010"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1021\/cr050301x"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1002\/poc.1676"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.1235"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/ja00216a049"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/ja00088a076"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1126\/science.1079294"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1021\/ja0488939"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1021\/ja404172s"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201303792"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b10495"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201704787"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201710307"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/ja00272a061"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b06035"},{"key":"ref24\/cit24","first-page":"51","volume-title":"Physics and Chemistry at Low Temperatures","author":"Fausto R.","year":"2012"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201708489"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1126\/science.1203761"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201705140"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2609"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC03720E"},{"key":"ref30\/cit30","doi-asserted-by":"crossref","DOI":"10.1002\/9781118560907","volume-title":"Nitrenes and Nitrenium Ions","author":"Falvey D. E.","year":"2013"},{"key":"ref31\/cit31","first-page":"501","volume-title":"Reactive Intermediate Chemistry","author":"Platz M. S.","year":"2004"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201804863"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/ja9635241"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b07368"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1021\/cr040055+"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1021\/jo901145h"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1021\/jo960093w"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1021\/ol5017977"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1002\/qua.1518"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/ja9944305"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1039\/B511229J"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1063\/1.4707734"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.7b12118"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1021\/ol2013457"},{"key":"ref50\/cit50","doi-asserted-by":"crossref","first-page":"618","DOI":"10.1142\/9789812812162_0016","volume-title":"Modern Methods for Multidimensional Dynamics Computations in Chemistry","author":"Allison T. C.","year":"1998"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcb.5b05758"},{"key":"ref52\/cit52","unstructured":"Lau, A. N. K.; Eason, R. G. Polymers Having Orthogonal Reactive Groups and Uses Thereof. Int. Patent WO\/2014\/059352, April 17, 2014."},{"key":"ref53\/cit53","volume-title":"Gaussian 09","author":"Frisch M. J.","year":"2013"},{"key":"ref54\/cit54","volume-title":"Exploring Chemistry with Electronic Structure Methods","author":"Foresman J. B.","year":"2015","edition":"3"},{"key":"ref55\/cit55","unstructured":"Changes\nfrom Gaussian 09 to Gaussian 16: http:\/\/gaussian.com\/relnotes\/ (last accessed April 26, 2019)."},{"key":"ref56\/cit56","unstructured":"Zhurko, G. A. ChemCraft, Version 1.8. http:\/\/www.chemcraftprog.com, 2016. (last accessed April 26, 2019)."},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1039\/b308564c"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.1063\/1.1574788"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1063\/1.476471"},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.1063\/1.470099"},{"key":"ref61\/cit61","volume-title":"Gaussian 16","author":"Frisch M. J.","year":"2016"},{"key":"ref62\/cit62","doi-asserted-by":"publisher","DOI":"10.1002\/qua.560360824"},{"key":"ref63\/cit63","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.81"},{"key":"ref64\/cit64","doi-asserted-by":"publisher","DOI":"10.1021\/ja982661q"},{"key":"ref65\/cit65","doi-asserted-by":"publisher","DOI":"10.1007\/BF01451751"},{"key":"ref66\/cit66","doi-asserted-by":"publisher","DOI":"10.1007\/BF01397171"},{"key":"ref67\/cit67","first-page":"24","volume":"183","author":"Brillouin L.","year":"1926","journal-title":"C. R. Acad. Sci."},{"key":"ref68\/cit68","doi-asserted-by":"publisher","DOI":"10.1063\/1.443130"},{"key":"ref69\/cit69","doi-asserted-by":"publisher","DOI":"10.1021\/j100485a023"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.9b06869","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,22]],"date-time":"2023-04-22T23:43:30Z","timestamp":1682207010000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.9b06869"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,8,19]]},"references-count":64,"journal-issue":{"issue":"36","published-print":{"date-parts":[[2019,9,11]]}},"alternative-id":["10.1021\/jacs.9b06869"],"URL":"https:\/\/doi.org\/10.1021\/jacs.9b06869","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,8,19]]}}}