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Catal."},{"key":"ref10\/cit10a","doi-asserted-by":"crossref","first-page":"4450","DOI":"10.1021\/jo000187c","volume":"65","author":"Ueda M.","year":"2000","journal-title":"Org. Chem."},{"key":"ref10\/cit10b","doi-asserted-by":"crossref","first-page":"773","DOI":"10.1039\/b518311a","volume":"4","author":"Jagt R. B. C.","year":"2006","journal-title":"Org. Biomol. Chem."},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"565","DOI":"10.1107\/S0021889897003117","volume":"30","author":"Farrugia L.","year":"1997","journal-title":"J. Appl. Crystallogr."},{"key":"ref12\/cit12","unstructured":"Deposited as CCDC deposit nos. 639254 and 644438 and published in ref5."},{"key":"ref13\/cit13","unstructured":"Crystallographic data for complex30: C49H64N2O8Rh2, FW = 1014.84, monoclinic, space groupP21\/n,a= 16.992(6) \u00c5,b= 16.649(4) \u00c5,c= 18.948(5) \u00c5, \u03b1 = 116.300(8)\u00b0,V= 4806(2) \u00c53,Z= 4,T=150 K, \u03c1calc= 1.403 mg\u00b7m-3, \u03bc = 0.739 mm-1,F(000) = 2104. Data were collected on a Bruker AXS-KAPPA APEX II diffractometer using graphite-monochromated Mo K\u03b1 radiation \u03bb = 0.71069 \u00c5, purple crystals (0.13 \u00d7 0.08 \u00d7 0.06 mm). Of 35575 reflections, 12008 were independent (Rint= 0.2299); 564 variables refined to finalRindices R1 (I> 2\u03c3(I)) = 0.0853, wR2(I> 2\u03c3(I) = 0.1521, R1(all data) = 0.2208, wR2(all data) = 0.2013, GoF = 0.870. Structure was solved by direct methods (SIR97). Non-hydrogen atoms were refined anisotropically, and hydrogen atoms were inserted in calculated positions, riding in the parent carbon atom (WINGX). CCDC deposit number 654664. Crystallographic data for complex31: C35H50N2O8Rh2, FW = 832.59, orthorhombic, space groupP212121,a= 12.659(4) \u00c5,b= 15.502(2) \u00c5,c= 18.822(3) \u00c5,V= 3693.6(14) \u00c53,Z= 4,T= 150 K, \u03c1calc= 1.497 mg\u00b7m-3, \u03bc = 0.944 mm-1,F(000) = 1712. Data were collected on a Bruker AXS-KAPPA APEX II diffractometer using graphite-monochromated Mo K\u03b1 radiation \u03bb = 0.71069 \u00c5, purple crystals (0.14 \u00d7 0.09 \u00d7 0.05 mm). Of 16605 reflections, 7325 were independent (Rint= 0.0588); 436 variables refined to finalRindices R1(I > 2\u00f3(I))=0.0422, wR2(I> 2\u03c3(I)) = 0.0730, R1(all data) = 0.0591, wR2(all data) = 0.0779, GoF = 0.955. Structure was solved by direct methods (SIR97). Non-hydrogen atoms were refined anisotropically and hydrogen atoms were inserted in calculated positions, riding in the parent carbon atom. (WINGX) CCDC deposit nno. 654665."},{"key":"ref14\/cit14","doi-asserted-by":"crossref","first-page":"11318","DOI":"10.1021\/ja016928o","volume":"123","author":"Snyder J. P.","year":"2001","journal-title":"Am. Chem. Soc."},{"key":"ref15\/cit15a","doi-asserted-by":"crossref","first-page":"5052","DOI":"10.1021\/ja012711i","volume":"124","author":"Hayashi T.","year":"2002","journal-title":"Am. Chem. Soc."},{"key":"ref15\/cit15b","doi-asserted-by":"crossref","first-page":"3904","DOI":"10.1021\/ja060225v","volume":"128","author":"Kina A.","year":"2006","journal-title":"Am. Chem. Soc."},{"key":"ref15\/cit15c","doi-asserted-by":"crossref","first-page":"707","DOI":"10.1002\/asia.200600184","volume":"1","author":"Kina A.","year":"2006","journal-title":"Chem. Asian J."},{"key":"#cr-split#-ref16\/cit16.1","unstructured":"Crystallographic data for complex CCDC 673880: C39H56N2O9Rh2, FW = 902.68, monoclinic, space groupP21\/c,a= 17.537(8) \u00c5,b= 12.284(7) \u00c5,c= 19.233(7) \u00c5, \u03b1 = 105.540(2)\u00b0,V= 3992(3) \u00c53,Z= 4,T= 150 K, \u03c1calc= 1.502 mg\u00b7m\u22123, \u03bc = 0.881 mm-1,F(000) = 1864. Data were collected on a Bruker AXS-KAPPA APEX II diffractometer using graphite-monochromated Mo K\u03b1 radiation \u03bb = 0.71069 \u00c5, purple crystals (0.10 \u00d7 0.06 \u00d7 0.02 mm). Of 37555 reflections, 7247 were independent (Rint= 0.2259)"},{"key":"#cr-split#-ref16\/cit16.2","unstructured":"481 variables refined to finalRindices R1(I> 2\u03c3(I)) = 0.0647, wR2(I> 2\u03c3(I)) = 0.0963, R1(all data) = 0.1715, wR2(all data) = 0.1186, GoF = 0.887. Structure was solved by direct methods (SIR 2004). Non-hydrogen atoms were refined anisotropically, and hydrogen atoms were inserted in calculated positions, riding in the parent carbon atom. (WINGX) CCDC deposit no. CCDC 673880."},{"volume-title":"Density Functional Theory of Atoms and Molecules","year":"1989","author":"Parr R. G.","key":"ref17\/cit17"},{"key":"ref18\/cit18a","doi-asserted-by":"crossref","first-page":"1083","DOI":"10.1016\/0040-4020(68)88057-3","volume":"24","author":"Wiberg K. B.","year":"1968","journal-title":"Tetrahedron"},{"key":"ref18\/cit18b","unstructured":"bWiberg indices are electronic parameters related to the electron density between atoms. They can be obtained from a Natural Population Analysis and provide an indication of the bond strength."},{"key":"ref19\/cit19","doi-asserted-by":"crossref","first-page":"799","DOI":"10.1071\/CH07103","volume":"60","author":"Kaiser P. F.","year":"2007","journal-title":"Aust. J. 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