{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,2,16]],"date-time":"2024-02-16T15:39:51Z","timestamp":1708097991353},"reference-count":34,"publisher":"American Chemical Society (ACS)","issue":"36","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Phys. Chem. B"],"published-print":{"date-parts":[[2003,9,1]]},"DOI":"10.1021\/jp0223206","type":"journal-article","created":{"date-parts":[[2003,9,4]],"date-time":"2003-09-04T05:32:24Z","timestamp":1062653544000},"page":"9837-9846","source":"Crossref","is-referenced-by-count":23,"title":["The \u201cHidden\u201d Phase Diagram of Water + 3-Methylpyridine at Large Absolute Negative Pressures"],"prefix":"10.1021","volume":"107","author":[{"given":"Zoran P.","family":"Visak","sequence":"first","affiliation":[{"name":"Instituto de Tecnologia Quimica e Biologica, ITQB 2, Universidade Nova de Lisboa, Av. da Republica, Apartado 127, 2780-901 Oeiras, Portugal"}]},{"given":"Lu\u00eds P. N.","family":"Rebelo","sequence":"additional","affiliation":[{"name":"Instituto de Tecnologia Quimica e Biologica, ITQB 2, Universidade Nova de Lisboa, Av. da Republica, Apartado 127, 2780-901 Oeiras, Portugal"}]},{"given":"Jerzy","family":"Szydlowski","sequence":"additional","affiliation":[{"name":"Instituto de Tecnologia Quimica e Biologica, ITQB 2, Universidade Nova de Lisboa, Av. da Republica, Apartado 127, 2780-901 Oeiras, Portugal"}]}],"member":"316","published-online":{"date-parts":[[2003,8,15]]},"reference":[{"key":"jp0223206b00001\/jp0223206b00001_1","doi-asserted-by":"crossref","first-page":"4606","DOI":"10.1039\/jr9520004606","author":"Cox J. D.","year":"1952","journal-title":"J. Chem. Soc."},{"key":"jp0223206b00002\/jp0223206b00002_1","volume-title":"Liquids and Liquid Mixtures","author":"Rowlinson J. S.","year":"1982","edition":"3"},{"key":"jp0223206b00003\/jp0223206b00003_1","doi-asserted-by":"crossref","first-page":"325","DOI":"10.1002\/bbpc.19720760521","volume":"76","author":"Schneider G. M.","year":"1972","journal-title":"Ber. Bunsen-Ges. Phys. Chem."},{"key":"jp0223206b00004\/jp0223206b00004_1","doi-asserted-by":"crossref","first-page":"195","DOI":"10.1039\/DF9531500195","volume":"15","author":"Timmermans J.","year":"1953","journal-title":"Discuss. Faraday Soc."},{"key":"jp0223206b00005\/jp0223206b00005_1","doi-asserted-by":"crossref","first-page":"333","DOI":"10.1524\/zpch.1963.37.5_6.333","volume":"37","author":"Schneider G.","year":"1963","journal-title":"Z. Phys. Chem. Neue Folge"},{"key":"jp0223206b00006\/jp0223206b00006_1","doi-asserted-by":"crossref","first-page":"135","DOI":"10.1016\/0370-1573(94)90015-9","volume":"249","author":"Narayanan T.","year":"1994","journal-title":"Phys. Rep."},{"key":"jp0223206b00007\/jp0223206b00007_1","doi-asserted-by":"crossref","first-page":"276","DOI":"10.1016\/0375-9601(91)90482-N","volume":"155","author":"Narayanan T.","year":"1991","journal-title":"Phys. Lett. A"},{"key":"jp0223206b00008\/jp0223206b00008_1","doi-asserted-by":"crossref","first-page":"489","DOI":"10.1016\/S0009-2614(88)85023-1","volume":"151","author":"Sidebottom D. L.","year":"1988","journal-title":"Chem. Phys. Lett."},{"key":"jp0223206b00009\/jp0223206b00009_1","doi-asserted-by":"crossref","first-page":"1887","DOI":"10.1021\/ma011533a","volume":"35","author":"Rebelo L. P. N.","year":"2002","journal-title":"Macromolecules"},{"key":"jp0223206b00010\/jp0223206b00010_1","doi-asserted-by":"crossref","first-page":"4277","DOI":"10.1039\/a902825k","volume":"1","author":"Rebelo L. P. N.","year":"1999","journal-title":"Phys. Chem. Chem. Phys."},{"key":"jp0223206b00011\/jp0223206b00011_1","doi-asserted-by":"crossref","first-page":"3062","DOI":"10.1021\/j100295a084","volume":"91","author":"Henderson S. J.","year":"1987","journal-title":"J J. Phys. Chem."},{"key":"jp0223206b00012\/jp0223206b00012_1","volume-title":"NJ, 1996.","author":"Liquids Under Negative Pressure","year":"2002"},{"key":"jp0223206b00013\/jp0223206b00013_1","doi-asserted-by":"crossref","first-page":"351","DOI":"10.1515\/jnet.1998.23.4.351","volume":"23","author":"Imre A.","year":"1998","journal-title":"J. Non-Equilibrium Thermodyn."},{"key":"jp0223206b00014\/jp0223206b00014_1","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1039\/a827117z","volume":"27","author":"Imre A.","year":"1998","journal-title":"Chem. Soc. Rev."},{"key":"jp0223206b00015\/jp0223206b00015_1","doi-asserted-by":"crossref","first-page":"1046","DOI":"10.1039\/b109405j","volume":"4","author":"Rebelo L. P. N.","year":"2002","journal-title":"Phys. Chem. Chem. Phys."},{"key":"jp0223206b00016\/jp0223206b00016_1","doi-asserted-by":"crossref","first-page":"1989","DOI":"10.1103\/PhysRevE.48.1989","volume":"48","author":"Narayanan T.","year":"1993","journal-title":"Phys. Rev. E"},{"key":"jp0223206b00017\/jp0223206b00017_1","doi-asserted-by":"crossref","first-page":"1145","DOI":"10.1021\/ma60066a017","volume":"11","author":"Sanchez I. C.","year":"1978","journal-title":"Macromolecules"},{"key":"jp0223206b00018\/jp0223206b00018_1","first-page":"423","volume":"43","author":"Szydlowski J.","year":"1998","journal-title":"Nukleonika"},{"key":"jp0223206b00020\/jp0223206b00020_1","unstructured":"In some experiments, higher tensions than those corresponding to pressures of \u2212200 bar were held for long periods of time, despite the fact that the system had already entered the two-phase region. In one a pressurep= \u2212353 \u00b1 20 bar was reached. In another, one single Berthelot run revealed, first, the phase separation between the top 3-MP rich phase and the bottom H\/D water rich one and, afterwards, at higher tensions, turbidity (due to strong heterogeneity) in the top phase. This heterogeneity was certainly originated at the diffusion of more 3-MP from the bottom to the upper phase, a process which has an increasing driving force as tension raises. The system only collapsed and relaxed to total equilibrium at a dive inside the metastable 2-phase region as deep as 76 bar of tension."},{"key":"jp0223206b00021\/jp0223206b00021_1","doi-asserted-by":"crossref","first-page":"483","DOI":"10.1016\/0021-9614(78)90096-4","volume":"10","author":"Abe J.-I.","year":"1978","journal-title":"J. Chem. Thermodyn."},{"key":"jp0223206b00022\/jp0223206b00022_1","doi-asserted-by":"crossref","first-page":"1239","DOI":"10.1002\/bbpc.19720761209","volume":"76","author":"Engels P.","year":"1972","journal-title":"Ber. Bunsen-Ges. Phys. Chem."},{"key":"jp0223206b00023\/jp0223206b00023_1","first-page":"375","volume":"46","author":"Marczak W.","year":"1998","journal-title":"Bull. Pol. Acad. Sci. Chem."},{"key":"jp0223206b00024\/jp0223206b00024_1","doi-asserted-by":"crossref","first-page":"241","DOI":"10.1006\/jcht.1997.0295","volume":"30","author":"Marczak W.","year":"1998","journal-title":"J. Chem. Thermodyn."},{"key":"jp0223206b00025\/jp0223206b00025_1","doi-asserted-by":"crossref","first-page":"1701","DOI":"10.1039\/b201723g","volume":"4","author":"Najdanovic-Visak V.","year":"2002","journal-title":"Phys. Chem. Chem. Phys."},{"key":"jp0223206b00026\/jp0223206b00026_1","doi-asserted-by":"crossref","first-page":"632","DOI":"10.1002\/(SICI)1099-0488(20000215)38:4<632::AID-POLB15>3.0.CO;2-Q","volume":"38","author":"de Sousa H. C.","year":"2000","journal-title":"Polym. Phys."},{"key":"jp0223206b00027\/jp0223206b00027_1","doi-asserted-by":"crossref","first-page":"497","DOI":"10.1002\/bbpc.19660700502","volume":"70","author":"Schneider G.","year":"1966","journal-title":"Ber. Bunsen-Ges. Phys. Chem."},{"key":"jp0223206b00029\/jp0223206b00029_1","volume-title":"Thermodynamics of PolymerSolutions","author":"Kamide K.","year":"1990"},{"key":"jp0223206b00030\/jp0223206b00030_1","volume-title":"basic","author":"The"},{"key":"jp0223206b00032\/jp0223206b00032_1","unstructured":"Prigogine I.; Defay, R.Chemical Thermodynamics; Everett, D. H., translator; Longmans Green & Co.\u2009 London, 1954; pp 271\u2212290."},{"key":"jp0223206b00033\/jp0223206b00033_1","doi-asserted-by":"crossref","first-page":"2251","DOI":"10.1039\/b200292b","volume":"4","author":"Rebelo L. P. N.","year":"2002","journal-title":"Phys. Chem. Chem. Phys."},{"key":"jp0223206b00034\/jp0223206b00034_1","doi-asserted-by":"crossref","first-page":"7756","DOI":"10.1063\/1.473776","volume":"106","author":"Brovchenko I. V.","year":"1997","journal-title":"J. Chem. Phys."},{"key":"jp0223206b00035\/jp0223206b00035_1","doi-asserted-by":"crossref","first-page":"2132","DOI":"10.1021\/jp994094e","volume":"104","author":"Papai I.","year":"2000","journal-title":"J. Phys. Chem. A"},{"key":"jp0223206b00036\/jp0223206b00036_1","doi-asserted-by":"crossref","first-page":"89","DOI":"10.1016\/S0167-7322(02)00084-3","volume":"101","author":"Alm\u00e1sy L.","year":"2002","journal-title":"J. Mol. Liq."},{"key":"jp0223206b00037\/jp0223206b00037_1","doi-asserted-by":"crossref","first-page":"12","DOI":"10.1002\/bbpc.19910950103","volume":"95","author":"Narayanan T.","year":"1991","journal-title":"Ber. Bunsen-Ges. Phys. Chem."}],"container-title":["The Journal of Physical Chemistry B"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jp0223206","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,1,10]],"date-time":"2024-01-10T17:04:17Z","timestamp":1704906257000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jp0223206"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2003,8,15]]},"references-count":34,"journal-issue":{"issue":"36","published-print":{"date-parts":[[2003,9,1]]}},"alternative-id":["10.1021\/jp0223206"],"URL":"https:\/\/doi.org\/10.1021\/jp0223206","relation":{},"ISSN":["1520-6106","1520-5207"],"issn-type":[{"value":"1520-6106","type":"print"},{"value":"1520-5207","type":"electronic"}],"subject":[],"published":{"date-parts":[[2003,8,15]]}}}