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As expected, 4BrR123 reacts in water at high NaOH concentration yielding HO4BrR123 much faster than observed in spontaneous solvolytic addition."},{"key":"ref57\/cit57b","doi-asserted-by":"crossref","first-page":"4071","DOI":"10.1021\/j100782a004","volume":"69","author":"Nandi P. K.","year":"1965","journal-title":"J. Phys. Chem."},{"key":"ref58\/cit58","doi-asserted-by":"crossref","first-page":"321","DOI":"10.1016\/j.molstruc.2008.09.026","volume":"919","author":"Janjua N. K.","year":"2009","journal-title":"J. Mol. Struct."},{"key":"ref59\/cit59a","unstructured":"aThroughout the text kcal mol\u20131refers to thermochemical calorie. 1 cal = 4.184 J."},{"key":"ref59\/cit59b","unstructured":"bTime evolution of 4BrR123 electronic absorption spectra in water yields kinetic traces obtained from depletion of the 4BrR123 S1\u2190S0band, indicating a pseudo-first-order process with rate constantkobs= 3.2 \u00d7 10\u20135s\u20131(T= 318 K). S1\u2190S0absorbanceA(T,t,\u03bb) maximum (\u03bb= 517 nm), ratios,A0\/A, were collected at consecutive equilibrium temperatures (294 <T\/K < 336). Arrhenius\u2019 law,k=ATe\u2013EA\/RTand first-order kinetics [1](t) = [1]0e\u2013ktwere combined asfA(T,t) = ln ln(A0\/A) = lnAT\u2013EA\/RT+ lnt. Rate constants of the corresponding nucleophilic addition,k, yield the activation energyEA= 18 kcal mol\u20131."},{"key":"ref59\/cit59c","unstructured":"cS\u00e1nchez-Coronilla, A.; Ferreira, J. A. B.; Costa, S. M. 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