{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,15]],"date-time":"2025-10-15T17:07:37Z","timestamp":1760548057569},"reference-count":17,"publisher":"American Chemical Society (ACS)","issue":"8","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Organometallics"],"published-print":{"date-parts":[[2005,4,1]]},"DOI":"10.1021\/om049057a","type":"journal-article","created":{"date-parts":[[2005,4,4]],"date-time":"2005-04-04T04:30:43Z","timestamp":1112589043000},"page":"1809-1812","source":"Crossref","is-referenced-by-count":60,"title":["X-ray, <sup>13<\/sup>C NMR, and DFT Studies on a Ruthenium(IV) Allyl Complex. Explanation for the Observed Control of Regioselectivity in Allylic Alkylation Chemistry"],"prefix":"10.1021","volume":"24","author":[{"given":"Ren\u00e9","family":"Hermatschweiler","sequence":"first","affiliation":[]},{"given":"Ignacio","family":"Fern\u00e1ndez","sequence":"additional","affiliation":[]},{"given":"Paul S.","family":"Pregosin","sequence":"additional","affiliation":[]},{"given":"Eric J.","family":"Watson","sequence":"additional","affiliation":[]},{"given":"Alberto","family":"Albinati","sequence":"additional","affiliation":[]},{"given":"Silvia","family":"Rizzato","sequence":"additional","affiliation":[]},{"given":"Luis F.","family":"Veiros","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Complexo I, Instituto Superior T\u00e9cnico, Av. Rovisco Pais 1, 1049-001 Lisbon, Portugal"}]},{"given":"Maria Jos\u00e9","family":"Calhorda","sequence":"additional","affiliation":[{"name":"ITQB, Av. da Rep\u00fablica, EAN, Apart. 127, 2781-901 Oeiras, Portugal, and Departamento de Qu\u00edmica e Bioqu\u00edmica, Faculdade de Ci\u00eancias, Universidade de Lisboa, 1749-016 Lisbon, Portugal"}]}],"member":"316","published-online":{"date-parts":[[2005,3,15]]},"reference":[{"key":"om049057ab00001\/om049057ab00001_1","doi-asserted-by":"crossref","first-page":"5837","DOI":"10.1021\/jo0491004","volume":"69","author":"Trost B. M.","year":"2004","journal-title":"J. Org. Chem."},{"key":"om049057ab00001\/om049057ab00001_2","first-page":"1470","volume":"5","author":"Trost B. M.","year":"2003","journal-title":"Org. Lett."},{"key":"om049057ab00001\/om049057ab00001_3","first-page":"1061","volume":"41","author":"Trost B. M.","year":"2003","journal-title":"Angew. Chem., Int. Ed."},{"key":"om049057ab00001\/om049057ab00001_4","doi-asserted-by":"crossref","first-page":"2546","DOI":"10.1021\/om020143p","volume":"21","author":"Trost B. M.","year":"2002","journal-title":"Organometallics"},{"key":"om049057ab00002\/om049057ab00002_1","doi-asserted-by":"crossref","first-page":"4746","DOI":"10.1021\/om990533k","volume":"18","author":"Morisaki Y.","year":"1999","journal-title":"Organometallics"},{"key":"om049057ab00003\/om049057ab00003_1","doi-asserted-by":"crossref","first-page":"904","DOI":"10.1002\/adsc.200404124","volume":"346","author":"Kundig E. P.","year":"2004","journal-title":"Adv. Synth. Catal."},{"key":"om049057ab00004\/om049057ab00004_1","doi-asserted-by":"crossref","first-page":"395","DOI":"10.1021\/cr9409804","volume":"96","author":"Trost B. M.","year":"1996","journal-title":"Chem. Rev."},{"key":"om049057ab00005\/om049057ab00005_1","first-page":"3765","volume":"23","author":"RuCp L","year":"2004","journal-title":"Organometallics"},{"key":"om049057ab00006\/om049057ab00006_1","unstructured":"(a) Crystallographic data for3:\u2009 C21H27ClF6NPRu, fw = 574.93, monoclinic, space groupP21\/c(No. 14),a= 11.8085(13) \u00c5,b= 15.1804(17) \u00c5,c= 13.4054(16) \u00c5, \u03b2 = 104.605(4)\u00b0,V= 2325.4(5) \u00c53,Z= 4,Dc= 1.642 g cm-3, Mo K\u03b1 radiation, \u03bb = 0.710\u200973 \u00c5, \u03bc = 9.14 cm-1,T= 120(2) K. A total of 20\u2009762 reflections were collected on a Bruker SMART CCD diffractometer in the range 2.98 \u2264 \u03b8 \u2264 26.01\u00b0. A total of 4556 unique reflections, after corrections forLpand absorption, were used for the solution and refinement (based onFo2) of the structure. All non-H atoms were refined anisotropically. Hydrogen atoms, in their calculated positions, were included in the refinement using a riding model. The finalRfactor is 0.0272 for 3712 observed reflections and 0.0398 for all data."},{"key":"om049057ab00007\/om049057ab00007_1","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1016\/S0022-328X(03)00207-9","volume":"674","author":"Castro A.","year":"2003","journal-title":"J. Organomet. Chem."},{"key":"om049057ab00007\/om049057ab00007_2","doi-asserted-by":"crossref","first-page":"63","DOI":"10.1016\/S0022-328X(01)01487-5","volume":"649","author":"Becker E.","year":"2002","journal-title":"J. Organomet. Chem."},{"key":"om049057ab00007\/om049057ab00007_3","first-page":"S83","volume":"1","author":"Orpen A. G.","year":"1989","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"om049057ab00007\/om049057ab00007_4","doi-asserted-by":"crossref","first-page":"5068","DOI":"10.1002\/anie.200352257","volume":"42","author":"Mbaye M. D.","year":"2003","journal-title":"Angew. Chem., Int. 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