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Soc."},{"key":"ref3\/cit3b","doi-asserted-by":"crossref","first-page":"7775","DOI":"10.1002\/anie.200701408","volume":"46","author":"Mueller J.","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref3\/cit3c","doi-asserted-by":"crossref","first-page":"776","DOI":"10.1021\/ja068312a","volume":"129","author":"Anstey M. R.","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref3\/cit3d","doi-asserted-by":"crossref","first-page":"3766","DOI":"10.1021\/ja801004d","volume":"130","author":"Draghici C.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref4\/cit4","doi-asserted-by":"crossref","first-page":"2663","DOI":"10.1002\/anie.200604472","volume":"46","author":"Niwa T.","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref5\/cit5","doi-asserted-by":"crossref","DOI":"10.1002\/0471433489","volume-title":"Hydrocarbon Chemistry","author":"Olah G. A.","year":"2003"},{"key":"ref6\/cit6a","doi-asserted-by":"crossref","first-page":"292","DOI":"10.1021\/ar9501885","volume":"29","author":"Gaillard E. R.","year":"1996","journal-title":"Acc. Chem. Res."},{"key":"ref6\/cit6b","doi-asserted-by":"crossref","first-page":"175","DOI":"10.1021\/ja00261a029","volume":"108","author":"Lee L. Y. C.","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"ref7\/cit7a","doi-asserted-by":"crossref","first-page":"6466","DOI":"10.1021\/ja043481l","volume":"127","author":"Hammerum S.","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref7\/cit7b","doi-asserted-by":"crossref","DOI":"10.1007\/978-1-4020-2575-4","volume-title":"Organic Spectoscopy","author":"Yadav L. D. S.","year":"2005"},{"key":"ref8\/cit8","doi-asserted-by":"crossref","DOI":"10.1093\/oso\/9780195122589.001.0001","volume-title":"Enzymatic Reaction Mechanisms","author":"Frey P. A.","year":"2007"},{"key":"ref9\/cit9a","doi-asserted-by":"crossref","first-page":"2922","DOI":"10.1021\/ic702373b","volume":"47","author":"Jaremko \u0141.","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref9\/cit9b","doi-asserted-by":"crossref","first-page":"2686","DOI":"10.1002\/ejic.200601152","author":"Kirillov A. M.","year":"2007","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref9\/cit9c","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1039\/B712360D","author":"Smole\u0144ski P.","year":"2008","journal-title":"Dalton Trans."},{"key":"ref10\/cit10a","unstructured":"For a comprehensive review, see:"},{"key":"ref10\/cit10b","doi-asserted-by":"crossref","first-page":"955","DOI":"10.1016\/j.ccr.2004.03.010","volume":"248","author":"Phillips A. D.","year":"2004","journal-title":"Coord. Chem. Rev."},{"key":"ref11\/cit11","unstructured":"For recent examples, see:"},{"key":"ref11\/cit11a","doi-asserted-by":"crossref","first-page":"1355","DOI":"10.1021\/om800025a","volume":"27","author":"Dutta B.","year":"2008","journal-title":"Organometallics"},{"key":"ref11\/cit11b","doi-asserted-by":"crossref","first-page":"5641","DOI":"10.1021\/ic7021903","volume":"47","author":"Miranda S.","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref11\/cit11c","doi-asserted-by":"crossref","first-page":"2670","DOI":"10.1002\/ejic.200800114","author":"Marchi A.","year":"2008","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref11\/cit11d","doi-asserted-by":"crossref","first-page":"620","DOI":"10.1002\/ejic.200700792","author":"Erlandsson M.","year":"2008","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref11\/cit11e","doi-asserted-by":"crossref","first-page":"429","DOI":"10.1021\/om060892x","volume":"26","author":"Mebi C. A.","year":"2007","journal-title":"Organometallics"},{"key":"ref11\/cit11f","doi-asserted-by":"crossref","first-page":"10962","DOI":"10.1021\/ic701864g","volume":"46","author":"Huang R.","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref11\/cit11g","doi-asserted-by":"crossref","first-page":"3969","DOI":"10.1021\/om700364s","volume":"26","author":"Gossens C.","year":"2007","journal-title":"Organometallics"},{"key":"ref11\/cit11h","doi-asserted-by":"crossref","first-page":"3289","DOI":"10.1021\/om061023a","volume":"26","author":"Rossin A.","year":"2007","journal-title":"Organometallics"},{"key":"ref12\/cit12","doi-asserted-by":"crossref","first-page":"2246","DOI":"10.1021\/ic702239w","volume":"47","author":"Mena-Cruz A.","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref13\/cit13a","doi-asserted-by":"crossref","first-page":"2568","DOI":"10.1002\/anie.200462790","volume":"44","author":"Lidrissi C.","year":"2005","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref13\/cit13b","doi-asserted-by":"crossref","first-page":"1182","DOI":"10.1002\/ejic.200501019","author":"Frost B. J.","year":"2006","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref13\/cit13c","doi-asserted-by":"crossref","first-page":"3152","DOI":"10.1002\/ejic.200600455","author":"Mohr F.","year":"2006","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref14\/cit14a","doi-asserted-by":"crossref","first-page":"1395","DOI":"10.1039\/a804053b","author":"Pruchnik F. P.","year":"1998","journal-title":"New J. Chem."},{"key":"ref14\/cit14b","doi-asserted-by":"crossref","first-page":"3318","DOI":"10.1021\/ic034044v","volume":"42","author":"Smole\u0144ski P.","year":"2003","journal-title":"Inorg. Chem."},{"key":"ref15\/cit15","unstructured":"For examples, see:"},{"key":"ref15\/cit15a","doi-asserted-by":"crossref","first-page":"2803","DOI":"10.1002\/ejic.200601177","author":"Romerosa A.","year":"2007","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref15\/cit15b","doi-asserted-by":"crossref","first-page":"368","DOI":"10.1002\/zaac.200600312","volume":"633","author":"Mebi C. A.","year":"2007","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref15\/cit15c","doi-asserted-by":"crossref","first-page":"1289","DOI":"10.1021\/ic051053q","volume":"45","author":"Romerosa A.","year":"2006","journal-title":"Inorg. Chem."},{"key":"ref15\/cit15d","doi-asserted-by":"crossref","first-page":"2114","DOI":"10.1021\/om049022a","volume":"24","author":"Dorcier A.","year":"2005","journal-title":"Organometallics"},{"key":"ref15\/cit15e","doi-asserted-by":"crossref","first-page":"2336","DOI":"10.1039\/B405878J","author":"Kovacs J.","year":"2004","journal-title":"Dalton Trans."},{"key":"ref16\/cit16a","unstructured":"For examples, see the Cambridge Structural Database (CSD);"},{"key":"ref16\/cit16b","doi-asserted-by":"crossref","first-page":"380","DOI":"10.1107\/S0108768102003890","volume":"58","author":"Allen F. H.","year":"2002","journal-title":"Acta Crystallogr."},{"key":"ref17\/cit17a","doi-asserted-by":"crossref","DOI":"10.1093\/oso\/9780198500179.001.0001","volume-title":"Nitrogen, Oxygen and Sulfur Ylide Chemistry","author":"Clark J. S.","year":"2002"},{"key":"ref17\/cit17b","doi-asserted-by":"crossref","first-page":"2735","DOI":"10.1039\/a805308a","author":"Gaebert C.","year":"1998","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"ref18\/cit18a","first-page":"197","volume":"8","author":"Angyal S. J.","year":"1954","journal-title":"Org. React."},{"key":"ref18\/cit18b","volume-title":"Name Reactions of Functional Group Transformations","author":"Li J. J.","year":"2007"},{"key":"ref19\/cit19a","doi-asserted-by":"crossref","first-page":"1043","DOI":"10.1016\/j.tet.2005.09.123","volume":"62","author":"Vanecko J. A.","year":"2006","journal-title":"Tetrahedron"},{"key":"ref19\/cit19b","volume-title":"Comprehensive Organic Synthesis","author":"Mark\u00f3 I. E.","year":"1991"},{"key":"ref20\/cit20","doi-asserted-by":"crossref","first-page":"248","DOI":"10.1021\/ja00027a032","volume":"114","author":"Wang F.","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"ref21\/cit21a","volume-title":"Spectroscopy of Organic Compounds","author":"Kalsi P. S.","year":"2004","edition":"6"},{"key":"ref21\/cit21b","volume-title":"Structure Determination of Organic Compounds: Tables and Spectral Data","author":"Affolter C.","year":"2000"},{"key":"ref22\/cit22a","doi-asserted-by":"crossref","first-page":"407","DOI":"10.1002\/jhet.5570110326","volume":"11","author":"Daigle D. J.","year":"1974","journal-title":"J. Heterocycl. Chem."},{"key":"ref22\/cit22b","doi-asserted-by":"crossref","first-page":"40","DOI":"10.1002\/9780470132630.ch6","volume":"32","author":"Daigle D. J.","year":"1998","journal-title":"Inorg. Synth."},{"key":"ref23\/cit23","doi-asserted-by":"crossref","first-page":"829","DOI":"10.1002\/(SICI)1099-0739(199911)13:11<829::AID-AOC915>3.0.CO;2-S","volume":"13","author":"Pruchnik F. P.","year":"1999","journal-title":"Appl. Organomet. Chem."},{"key":"ref24\/cit24","doi-asserted-by":"crossref","unstructured":"Otwinowski, Z.; Minor, W.Methods in Enzymology, Vol. 276, Macromolecular Crystallography;Carter, C. W., Jr.; Sweet, R. M., Eds.Academic Press:New York; 1997; Part A, pp307\u2212326","DOI":"10.1016\/S0076-6879(97)76066-X"},{"key":"ref25\/cit25","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick G. M.","year":"2008","journal-title":"Acta Crystallogr."},{"key":"ref26\/cit26","doi-asserted-by":"crossref","first-page":"837","DOI":"10.1107\/S0021889899006020","volume":"32","author":"Farrugia L. J.","year":"1999","journal-title":"J. Appl. 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