{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,14]],"date-time":"2026-02-14T09:42:44Z","timestamp":1771062164646,"version":"3.50.1"},"reference-count":43,"publisher":"American Geophysical Union (AGU)","issue":"D10","license":[{"start":{"date-parts":[[2007,2,10]],"date-time":"2007-02-10T00:00:00Z","timestamp":1171065600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Geophys. Res."],"published-print":{"date-parts":[[2007,5,27]]},"abstract":"<jats:p>A chemical ionization mass spectrometer (CIMS) utilizing protonated acetone dimer ion chemistry to measure gas\u2010phase ammonia (NH<jats:sub>3<\/jats:sub>) from the NOAA WP\u20103D aircraft is described. The average sensitivity determined from in\u2010flight standard addition calibrations ranged from 2.6 to 5 ion counts s<jats:sup>\u22121<\/jats:sup> pptv<jats:sup>\u22121<\/jats:sup>, depending on flow conditions, for 1 MHz of reagent ion signal. The instrument time response was determined to be 5 s from the 2 e\u2010folding signal decay time after removal of a standard addition calibration. The instrumental background varied from flight to flight ranging from 0.5 to 1.3 ppbv. The variability between successive background measurements ranged from 50 pptv to 100 pptv. Total uncertainty for the 5 s data was conservatively estimated to be \u00b1(30% + 125 pptv). Two NH<jats:sub>3<\/jats:sub> sources were sampled during the New England Air Quality Study\u2013Intercontinental Transport and Chemical Transformation (NEAQS\u2010ITCT) 2004 campaign, one urban and one agricultural. During the 25 July flight, enhancements in NH<jats:sub>3<\/jats:sub> mixing ratios were coincident with enhancements in CO, NOx, and SO<jats:sub>2<\/jats:sub> mixing ratios downwind of New York City. The NH<jats:sub>3<\/jats:sub> mixing ratios in the urban outflow plume ranged from 0.4 to 1 ppbv, or enhancements of 0.2 to 0.8 ppbv above local background. During the 15 August flight, NH<jats:sub>3<\/jats:sub> mixing ratios were enhanced 0.3 to 0.45 ppbv above local background directly downwind of an agricultural area northeast of Atlanta, Georgia. The NH<jats:sub>3<\/jats:sub> CIMS instrument has shown the ability to measure sub\u2010ppbv NH<jats:sub>3<\/jats:sub> levels at high time resolution from an aircraft.<\/jats:p>","DOI":"10.1029\/2006jd007589","type":"journal-article","created":{"date-parts":[[2007,2,9]],"date-time":"2007-02-09T21:00:13Z","timestamp":1171054813000},"source":"Crossref","is-referenced-by-count":111,"title":["A chemical ionization mass spectrometry technique for airborne measurements of ammonia"],"prefix":"10.1029","volume":"112","author":[{"given":"J. B.","family":"Nowak","sequence":"first","affiliation":[{"name":"Cooperative Institute for Research in Environmental Sciences University of Colorado  Boulder Colorado USA"},{"name":"Chemical Sciences Division, Earth System Research Laboratory NOAA  Boulder Colorado USA"}]},{"given":"J. A.","family":"Neuman","sequence":"additional","affiliation":[{"name":"Cooperative Institute for Research in Environmental Sciences University of Colorado  Boulder Colorado USA"},{"name":"Chemical Sciences Division, Earth System Research Laboratory NOAA  Boulder Colorado USA"}]},{"given":"K.","family":"Kozai","sequence":"additional","affiliation":[{"name":"Cooperative Institute for Research in Environmental Sciences University of Colorado  Boulder Colorado USA"},{"name":"Chemical Sciences Division, Earth System Research Laboratory NOAA  Boulder Colorado USA"}]},{"given":"L. G.","family":"Huey","sequence":"additional","affiliation":[{"name":"School of Earth and Atmospheric Sciences Georgia Institute of Technology  Atlanta Georgia USA"}]},{"given":"D. J.","family":"Tanner","sequence":"additional","affiliation":[{"name":"School of Earth and Atmospheric Sciences Georgia Institute of Technology  Atlanta Georgia USA"}]},{"given":"J. S.","family":"Holloway","sequence":"additional","affiliation":[{"name":"Cooperative Institute for Research in Environmental Sciences University of Colorado  Boulder Colorado USA"},{"name":"Chemical Sciences Division, Earth System Research Laboratory NOAA  Boulder Colorado USA"}]},{"given":"T. B.","family":"Ryerson","sequence":"additional","affiliation":[{"name":"Chemical Sciences Division, Earth System Research Laboratory NOAA  Boulder Colorado USA"}]},{"given":"G. J.","family":"Frost","sequence":"additional","affiliation":[{"name":"Cooperative Institute for Research in Environmental Sciences University of Colorado  Boulder Colorado USA"},{"name":"Chemical Sciences Division, Earth System Research Laboratory NOAA  Boulder Colorado USA"}]},{"given":"S. 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