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Detecting such changes in ocean biogeochemistry will require quantification of the magnitude of the change (anthropogenic signal) and the natural variability inherent to the climate system (noise). Here we use Large Ensemble (LE) experiments from four Earth system models (ESMs) with multiple emissions scenarios to estimate Time of Emergence (ToE) and partition projection uncertainty for anthropogenic signals in five biogeochemically important upper\u2010ocean variables. We find ToEs are robust across ESMs for sea surface temperature and the invasion of anthropogenic carbon; emergence time scales are 20\u201330\u00a0yr. For the biological carbon pump, and sea surface chlorophyll and salinity, emergence time scales are longer (50+\u00a0yr), less robust across the ESMs, and more sensitive to the forcing scenario considered. We find internal variability uncertainty, and model differences in the internal variability uncertainty, can be consequential sources of uncertainty for projecting regional changes in ocean biogeochemistry over the coming decades. In combining structural, scenario, and internal variability uncertainty, this study represents the most comprehensive characterization of biogeochemical emergence time scales and uncertainty to date. Our findings delineate critical spatial and duration requirements for marine observing systems to robustly detect anthropogenic change.<\/jats:p>","DOI":"10.1029\/2019gb006453","type":"journal-article","created":{"date-parts":[[2020,7,23]],"date-time":"2020-07-23T15:13:02Z","timestamp":1595517182000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":57,"title":["Time of Emergence and Large Ensemble Intercomparison for Ocean Biogeochemical Trends"],"prefix":"10.1029","volume":"34","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6668-9088","authenticated-orcid":false,"given":"Sarah","family":"Schlunegger","sequence":"first","affiliation":[{"name":"Program in Atmospheric and Oceanic Sciences Princeton University  Princeton NJ USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6465-8923","authenticated-orcid":false,"given":"Keith B.","family":"Rodgers","sequence":"additional","affiliation":[{"name":"Program in Atmospheric and Oceanic Sciences Princeton University  Princeton NJ USA"},{"name":"Center for Climate Physics Institute for Basic Science  Busan South Korea"},{"name":"Pusan National University  Busan South Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5219-2604","authenticated-orcid":false,"given":"Jorge L.","family":"Sarmiento","sequence":"additional","affiliation":[{"name":"Program in Atmospheric and Oceanic Sciences Princeton University  Princeton NJ USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3475-4842","authenticated-orcid":false,"given":"Tatiana","family":"Ilyina","sequence":"additional","affiliation":[{"name":"Max Plank Institute for Meteorology  Hamburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8794-0489","authenticated-orcid":false,"given":"John P.","family":"Dunne","sequence":"additional","affiliation":[{"name":"NOAA Geophysical Fluid Dynamics Laboratory  Princeton NJ USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7984-8810","authenticated-orcid":false,"given":"Yohei","family":"Takano","sequence":"additional","affiliation":[{"name":"Max Plank Institute for Meteorology  Hamburg Germany"},{"name":"Los Alamos National Laboratory  Los Alamos NM USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"James R.","family":"Christian","sequence":"additional","affiliation":[{"name":"Canadian Center for Climate Modeling and Analysis  Victoria British Columbia Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1273-2957","authenticated-orcid":false,"given":"Matthew C.","family":"Long","sequence":"additional","affiliation":[{"name":"National Center for Atmospheric Research  Boulder CO USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2348-7854","authenticated-orcid":false,"given":"Thomas L.","family":"Fr\u00f6licher","sequence":"additional","affiliation":[{"name":"Climate and Environmental Physics, Physics Institute University of Bern  Bern Switzerland"},{"name":"Oeschger Centre for Climate Change Research University of Bern  Bern Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8868-1338","authenticated-orcid":false,"given":"Richard","family":"Slater","sequence":"additional","affiliation":[{"name":"Program in Atmospheric and Oceanic Sciences Princeton University  Princeton NJ USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4632-9701","authenticated-orcid":false,"given":"Flavio","family":"Lehner","sequence":"additional","affiliation":[{"name":"National Center for Atmospheric Research  Boulder CO USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"13","published-online":{"date-parts":[[2020,8,23]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1029\/2010GL046270"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1175\/JCLI-D-12-00494.1"},{"key":"e_1_2_8_4_1","first-page":"867","volume-title":"Climate change 2013: The physical science basis. 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