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Here we report a highly efficient, stable and multifunctional Na\u2013Fe<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub>\/HZSM-5 catalyst, which can directly convert CO<jats:sub>2<\/jats:sub> to gasoline-range (C<jats:sub>5<\/jats:sub>\u2013C<jats:sub>11<\/jats:sub>) hydrocarbons with selectivity up to 78% of all hydrocarbons while only 4% methane at a CO<jats:sub>2<\/jats:sub> conversion of 22% under industrial relevant conditions. It is achieved by a multifunctional catalyst providing three types of active sites (Fe<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub>, Fe<jats:sub>5<\/jats:sub>C<jats:sub>2<\/jats:sub> and acid sites), which cooperatively catalyse a tandem reaction. More significantly, the appropriate proximity of three types of active sites plays a crucial role in the successive and synergetic catalytic conversion of CO<jats:sub>2<\/jats:sub> to gasoline. The multifunctional catalyst, exhibiting a remarkable stability for 1,000 h on stream, definitely has the potential to be a promising industrial catalyst for CO<jats:sub>2<\/jats:sub> utilization to liquid fuels.<\/jats:p>","DOI":"10.1038\/ncomms15174","type":"journal-article","created":{"date-parts":[[2017,5,2]],"date-time":"2017-05-02T09:19:23Z","timestamp":1493716763000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":879,"title":["Directly converting CO2 into a gasoline fuel"],"prefix":"10.1038","volume":"8","author":[{"given":"Jian","family":"Wei","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingjie","family":"Ge","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruwei","family":"Yao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiyong","family":"Wen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuanyan","family":"Fang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lisheng","family":"Guo","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hengyong","family":"Xu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4191-578X","authenticated-orcid":false,"given":"Jian","family":"Sun","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2017,5,2]]},"reference":[{"key":"BFncomms15174_CR1","doi-asserted-by":"publisher","first-page":"487","DOI":"10.1021\/jo801260f","volume":"74","author":"GA Olah","year":"2008","unstructured":"Olah, G. 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The error has not been fixed in the paper.","order":6,"name":"change_details","label":"Change Details","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"The authors declare no competing financial interests.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}],"article-number":"15174"}}