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However, 2D organic systems possessing promising electrical transport properties are still rare. Here a highly crystalline thin film of a copper coordination polymer, Cu-BHT (BHT=benzenehexathiol), is prepared via a liquid\u2013liquid interface reaction between BHT\/dichloromethane and copper(II) nitrate\/H\n                    <jats:sub>2<\/jats:sub>\n                    O. The morphology and structure characterization reveal that this film is piled up by nanosheets of 2D lattice of [Cu\n                    <jats:sub>3<\/jats:sub>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    S\n                    <jats:sub>6<\/jats:sub>\n                    )]\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    , which is further verified by quantum simulation. Four-probe measurements show that the room temperature conductivity of this material can reach up to 1,580\u2009S\u2009cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which is the highest value ever reported for coordination polymers. Meanwhile, it displays ambipolar charge transport behaviour and extremely high electron and hole mobilities (99\u2009cm\n                    <jats:sup>2<\/jats:sup>\n                    V\n                    <jats:sup>\u22121<\/jats:sup>\n                    s\n                    <jats:sup>\u22121<\/jats:sup>\n                    for holes and 116\u2009cm\n                    <jats:sup>2<\/jats:sup>\n                    V\n                    <jats:sup>\u22121<\/jats:sup>\n                    s\n                    <jats:sup>\u22121<\/jats:sup>\n                    for electrons) under field-effect modulation.\n                  <\/jats:p>","DOI":"10.1038\/ncomms8408","type":"journal-article","created":{"date-parts":[[2015,6,15]],"date-time":"2015-06-15T06:07:50Z","timestamp":1434348470000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":848,"title":["A two-dimensional \u03c0\u2013d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour"],"prefix":"10.1038","volume":"6","author":[{"given":"Xing","family":"Huang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Sheng","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zeyi","family":"Tu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fengjiao","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junhua","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hua","family":"Geng","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ye","family":"Zou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chong-an","family":"Di","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0052-9364","authenticated-orcid":false,"given":"Yuanping","family":"Yi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yimeng","family":"Sun","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Xu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daoben","family":"Zhu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2015,6,15]]},"reference":[{"key":"BFncomms8408_CR1","doi-asserted-by":"publisher","first-page":"666","DOI":"10.1126\/science.1102896","volume":"306","author":"KS Novoselov","year":"2004","unstructured":"Novoselov, K. 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