{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,13]],"date-time":"2026-07-13T06:13:06Z","timestamp":1783923186910,"version":"3.55.0"},"reference-count":34,"publisher":"Springer Science and Business Media LLC","issue":"6","license":[{"start":{"date-parts":[[2006,5,14]],"date-time":"2006-05-14T00:00:00Z","timestamp":1147564800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"},{"start":{"date-parts":[[2006,5,14]],"date-time":"2006-05-14T00:00:00Z","timestamp":1147564800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Nature Mater"],"published-print":{"date-parts":[[2006,6,1]]},"DOI":"10.1038\/nmat1649","type":"journal-article","created":{"date-parts":[[2006,5,14]],"date-time":"2006-05-14T17:33:14Z","timestamp":1147627994000},"page":"467-470","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":177,"title":["Photocontrolled living polymerizations"],"prefix":"10.1038","volume":"5","author":[{"given":"Makoto","family":"Tanabe","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guido W. M.","family":"Vandermeulen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wing Yan","family":"Chan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paul W.","family":"Cyr","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lawrence","family":"Vanderark","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David A.","family":"Rider","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ian","family":"Manners","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2006,5,14]]},"reference":[{"key":"BFnmat1649_CR1","volume-title":"Principles of Polymerization","author":"GG Odian","year":"1981","unstructured":"Odian, G. G. Principles of Polymerization (Wiley, New York, 1981)."},{"key":"BFnmat1649_CR2","doi-asserted-by":"publisher","first-page":"1168","DOI":"10.1038\/1781168a0","volume":"178,","author":"M Szwarc","year":"1956","unstructured":"Szwarc, M. \u2018Living\u2019 polymers. Nature 178, 1168\u20131169 (1956).","journal-title":"Nature"},{"key":"BFnmat1649_CR3","doi-asserted-by":"publisher","first-page":"866","DOI":"10.1126\/science.272.5263.866","volume":"272,","author":"TE Patten","year":"1996","unstructured":"Patten, T. E., Xia, J., Abernathy, T. & Matyjaszewski, K. Polymers with very low polydispersities from atom transfer radical polymerization. Science 272, 866\u2013868 (1996).","journal-title":"Science"},{"key":"BFnmat1649_CR4","doi-asserted-by":"publisher","first-page":"2987","DOI":"10.1021\/ma00063a054","volume":"26,","author":"MK Georges","year":"1993","unstructured":"Georges, M. K., Veregin, R. P. N., Kazmaier, P. M. & Hamer, G. K. Narrow molecular weight resins by a free-radical polymerization process. Macromolecules 26, 2987\u20132988 (1993).","journal-title":"Macromolecules"},{"key":"BFnmat1649_CR5","doi-asserted-by":"publisher","first-page":"1721","DOI":"10.1021\/ma00109a056","volume":"28,","author":"M Kato","year":"1995","unstructured":"Kato, M., Kamigaito, M., Sawamoto, M. & Higashimura, T. Polymerization of methyl methacrylate with the carbon tetrachloride\/dichlorotris-(triphenylphosphine)ruthenium(II)\/methylaluminum bis(2,6-di-tert-butylphenoxide) initiating system: possibility of living radical polymerization. Macromolecules 28, 1721\u20131723 (1995).","journal-title":"Macromolecules"},{"key":"BFnmat1649_CR6","doi-asserted-by":"publisher","first-page":"2820","DOI":"10.1021\/ma00088a024","volume":"27,","author":"M Akatsuka","year":"1994","unstructured":"Akatsuka, M., Aida, T. & Inoue, S. High-speed \u201cimmortal\u201d polymerization of epoxides initiated with aluminum porphyrin. Acceleration of propagation and chain-transfer reactions by a Lewis acid. Macromolecules 27, 2820\u20132825 (1994).","journal-title":"Macromolecules"},{"key":"BFnmat1649_CR7","doi-asserted-by":"crossref","unstructured":"Manners, I. Poly(ferrocenylsilanes): novel organometallic plastics. Chem. Commun. 857\u2013865 (1999).","DOI":"10.1039\/a810043h"},{"key":"BFnmat1649_CR8","doi-asserted-by":"publisher","first-page":"11434","DOI":"10.1021\/ja046657s","volume":"126,","author":"M Tanabe","year":"2004","unstructured":"Tanabe, M. & Manners, I. Photolytic living anionic ring-opening polymerization (ROP) of silicon-bridged [1]ferrocenophanes via an iron-cyclopentadienyl bond cleavage mechanism. J. Am. Chem. Soc. 126, 11434\u201311435 (2004).","journal-title":"J. Am. Chem. Soc."},{"key":"BFnmat1649_CR9","doi-asserted-by":"publisher","first-page":"2068","DOI":"10.1021\/ja029297m","volume":"125,","author":"T Mizuta","year":"2003","unstructured":"Mizuta, T., Imamura, Y. & Miyoshi, K. Ring-opening reaction of phosphorus-bridged [1]ferrocenophane via ring slippage from\u03b75- to\u03b71-Cp. J. Am. Chem. Soc. 125, 2068\u20132069 (2003).","journal-title":"J. Am. Chem. Soc."},{"key":"BFnmat1649_CR10","doi-asserted-by":"publisher","first-page":"5765","DOI":"10.1021\/ja000311+","volume":"122,","author":"A Berenbaum","year":"2000","unstructured":"Berenbaum, A. et al. Synthesis, electronic structure, and novel reactivity of strained, boron-bridged [1]ferrocenophanes. J. Am. Chem. Soc. 122, 5765\u20135774 (2000).","journal-title":"J. Am. Chem. Soc."},{"key":"BFnmat1649_CR11","doi-asserted-by":"publisher","first-page":"4861","DOI":"10.1021\/ic990173t","volume":"38,","author":"Y Yamaguchi","year":"1999","unstructured":"Yamaguchi, Y. & Kutal, C. Efficient photodissociation of anions from benzoyl-functionalized ferrocene complexes. Inorg. Chem. 38, 4861\u20134867 (1999).","journal-title":"Inorg. Chem."},{"key":"BFnmat1649_CR12","doi-asserted-by":"publisher","first-page":"1532","DOI":"10.1021\/ic020639z","volume":"42,","author":"W Ding","year":"2003","unstructured":"Ding, W. et al. Characterization of the low-energy electronic excited states of benzoyl-substituted ferrocenes. Inorg. Chem. 42, 1532\u20131537 (2003).","journal-title":"Inorg. Chem."},{"key":"BFnmat1649_CR13","doi-asserted-by":"publisher","first-page":"10976","DOI":"10.1021\/ja972043u","volume":"119,","author":"R Rulkens","year":"1997","unstructured":"Rulkens, R. et al. Highly strained, ring-tilted [1]ferrocenophanes containing group 16 elements in the bridge: synthesis, structures, and ring-opening oligomerization and polymerization of [1]thia- and [1]selenaferrocenophanes. J. Am. Chem. Soc. 119, 10976\u201310986 (1997).","journal-title":"J. Am. Chem. Soc."},{"key":"BFnmat1649_CR14","doi-asserted-by":"publisher","first-page":"2113","DOI":"10.1021\/om980087l","volume":"17,","author":"S Barlow","year":"1998","unstructured":"Barlow, S. et al. Electronic structure of strained silicon- and sulfur-bridged [1]ferrocenophanes and an analogous dicarbon-bridged [2]ferrocenophane: an investigation by photoelectron spectroscopy and density-functional theory. Organometallics 17, 2113\u20132120 (1998).","journal-title":"Organometallics"},{"key":"BFnmat1649_CR15","doi-asserted-by":"publisher","first-page":"79","DOI":"10.1016\/S0022-328X(00)87889-4","volume":"81,","author":"RW Harrigan","year":"1974","unstructured":"Harrigan, R. W., Hammond, G. S. & Gray, H. B. Photochemistry of titanocene(IV) derivatives. J. Organomet. Chem. 81, 79\u201385 (1974).","journal-title":"J. Organomet. Chem."},{"key":"BFnmat1649_CR16","doi-asserted-by":"publisher","first-page":"77","DOI":"10.1002\/marc.1991.030120202","volume":"12,","author":"S Penczek","year":"1991","unstructured":"Penczek, S., Kubisa, P. & Szymanski, R. On the diagnostic criteria of the livingness of polymerizations. Makromol. Chem. Rapid Commun. 12, 77\u201380 (1991).","journal-title":"Makromol. Chem. Rapid Commun."},{"key":"BFnmat1649_CR17","doi-asserted-by":"publisher","first-page":"1664","DOI":"10.1126\/science.1066321","volume":"294,","author":"I Manners","year":"2001","unstructured":"Manners, I. Putting metals into polymers. Science 294, 1664\u20131666 (2001).","journal-title":"Science"},{"key":"BFnmat1649_CR18","doi-asserted-by":"publisher","first-page":"8526","DOI":"10.1021\/ja0261269","volume":"124,","author":"JL Bender","year":"2002","unstructured":"Bender, J. L. et al. Site-isolated luminescent europium complexes with polyester macroligands: metal-centered heteroarm stars and nanoscale assemblies with labile block junctions. J. Am. Chem. Soc. 124, 8526\u20138527 (2002).","journal-title":"J. Am. Chem. Soc."},{"key":"BFnmat1649_CR19","doi-asserted-by":"publisher","first-page":"7446","DOI":"10.1021\/ja048570c","volume":"126,","author":"HB Eitouni","year":"2004","unstructured":"Eitouni, H. B. & Balsara, N. P. Effect of chemical oxidation on the self-assembly of organometallic block copolymers. J. Am. Chem. Soc. 126, 7446\u20137447 (2004).","journal-title":"J. Am. Chem. Soc."},{"key":"BFnmat1649_CR20","doi-asserted-by":"publisher","first-page":"297","DOI":"10.1002\/adma.200390071","volume":"15,","author":"K Temple","year":"2003","unstructured":"Temple, K. et al. Spontaneous vertical ordering and pyrolytic formation of nanoscopic ceramic patterns from poly(styrene-b-ferrocenylsilane) (PS-PFS). Adv. Mater. 15, 297\u2013300 (2003).","journal-title":"Adv. Mater."},{"key":"BFnmat1649_CR21","doi-asserted-by":"publisher","first-page":"1791","DOI":"10.1039\/b403831b","volume":"14,","author":"S Lastella","year":"2004","unstructured":"Lastella, S. et al. Density control of single-walled carbon nanotubes using patterned iron nanoparticle catalysts derived from phase-separated thin films of a polyferrocene block copolymer. J. Mater. Chem. 14, 1791\u20131794 (2004).","journal-title":"J. Mater. Chem."},{"key":"BFnmat1649_CR22","doi-asserted-by":"publisher","first-page":"876","DOI":"10.1002\/adma.200306447","volume":"16,","author":"C Hinderling","year":"2004","unstructured":"Hinderling, C. et al. Organometallic block copolymers as catalyst precursors for templated carbon nanotube growth. Adv. Mater. 16, 876\u2013879 (2004).","journal-title":"Adv. Mater."},{"key":"BFnmat1649_CR23","doi-asserted-by":"publisher","first-page":"1720","DOI":"10.1021\/ma034909o","volume":"37,","author":"C Kloninger","year":"2004","unstructured":"Kloninger, C. & Rehahn, M. 1,1-dimethylsilacyclobutane-mediated living anionic block copolymerization of [1]dimethylsilaferrocenophane and methyl methacrylate. Macromolecules 37, 1720\u20131727 (2004).","journal-title":"Macromolecules"},{"key":"BFnmat1649_CR24","doi-asserted-by":"publisher","first-page":"3825","DOI":"10.1002\/1521-3773(20021018)41:20<3825::AID-ANIE3825>3.0.CO;2-6","volume":"41,","author":"BGG Lohmeijer","year":"2002","unstructured":"Lohmeijer, B. G. G. & Schubert, U. S. Supramolecular engineering with macromolecules: an alternative concept for block copolymers. Angew. Chem. Int. Edn 41, 3825\u20133829 (2002).","journal-title":"Angew. Chem. Int. Edn"},{"key":"BFnmat1649_CR25","doi-asserted-by":"publisher","first-page":"2485","DOI":"10.1021\/la020773w","volume":"19,","author":"S Hou","year":"2003","unstructured":"Hou, S., Man, K. Y. K. & Chan, W. K. Nanosized micelles formed by the self-assembly of amphiphilic block copolymers with luminescent rhenium complexes. Langmuir 19, 2485\u20132490 (2003).","journal-title":"Langmuir"},{"key":"BFnmat1649_CR26","doi-asserted-by":"publisher","first-page":"3147","DOI":"10.1021\/ja003174p","volume":"123,","author":"JA Massey","year":"2001","unstructured":"Massey, J. A. et al. Fabrication of oriented nanoscopic ceramic lines from cylindrical micelles of an organometallic polyferrocene block copolymer. J. Am. Chem. Soc. 123, 3147\u20133148 (2001).","journal-title":"J. Am. Chem. Soc."},{"key":"BFnmat1649_CR27","doi-asserted-by":"publisher","first-page":"8967","DOI":"10.1021\/ma0490092","volume":"37,","author":"LA M\u00eeinea","year":"2004","unstructured":"M\u00eeinea, L. A., Sessions, L. B., Ericson, K. D., Glueck, D. S. & Grubbs, R. B. Phenylethynylstyrene-cobalt carbonyl block copolymer composites. Macromolecules 37, 8967\u20138972 (2004).","journal-title":"Macromolecules"},{"key":"BFnmat1649_CR28","doi-asserted-by":"publisher","first-page":"1837","DOI":"10.1002\/anie.199518371","volume":"34,","author":"M Herberhold","year":"1995","unstructured":"Herberhold, M. Distorted sandwich compounds: [1]ferrocenophanes and [2]ruthenocenophanes. Angew. Chem. Int. Edn 34, 1837\u20131839 (1995).","journal-title":"Angew. Chem. Int. Edn"},{"key":"BFnmat1649_CR29","doi-asserted-by":"publisher","first-page":"1968","DOI":"10.1021\/om049872q","volume":"23,","author":"H Braunschweig","year":"2004","unstructured":"Braunschweig, H. et al. Synthesis and structure of [Cr{(\u03b76-C6H5)2B{NtBu(SiMe3)}} ] and [Cr{(\u03b76-C6H5)2(BNMe2)2} ], the first boron-bridged metalloarenophanes. Organometallics 23, 1968\u20131970 (2004).","journal-title":"Organometallics"},{"key":"BFnmat1649_CR30","doi-asserted-by":"crossref","unstructured":"Berenbaum, A. & Manners, I. Transition metal-catalyzed ring-opening polymerization (ROP) of strained, silicon-bridged bis(benzene)chromium complexes. Dalton Trans. 2057\u20132058 (2004).","DOI":"10.1039\/b406873d"},{"key":"BFnmat1649_CR31","doi-asserted-by":"publisher","first-page":"3321","DOI":"10.1002\/anie.200454022","volume":"43,","author":"U Vogel","year":"2004","unstructured":"Vogel, U., Lough, A. J. & Manners, I. Isolation of [1]ruthenocenophanes: synthesis of polyruthenocenylstannanes by ring-opening polymerization. Angew. Chem. Int. Edn 43, 3321\u20133325 (2004).","journal-title":"Angew. Chem. Int. Edn"},{"key":"BFnmat1649_CR32","doi-asserted-by":"publisher","first-page":"5530","DOI":"10.1002\/anie.200460538","volume":"43,","author":"M Tamm","year":"2004","unstructured":"Tamm, M. et al. Ansa-cycloheptatrienyl-cyclopentadienyl complexes. Angew. Chem. Int. Edn 43, 5530\u20135534 (2004).","journal-title":"Angew. Chem. Int. Edn"},{"key":"BFnmat1649_CR33","doi-asserted-by":"publisher","first-page":"785","DOI":"10.1021\/om049004t","volume":"24,","author":"JA Schachner","year":"2005","unstructured":"Schachner, J. A., Lund, C. L., Quail, J. W. & M\u00fcller, J. Synthesis and characterization of the first aluminum-bridged [1]ferrocenophane. Organometallics 24, 785\u2013787 (2005).","journal-title":"Organometallics"},{"key":"BFnmat1649_CR34","doi-asserted-by":"publisher","first-page":"1599","DOI":"10.1002\/zaac.200400247","volume":"630,","author":"C Elschenbroich","year":"2004","unstructured":"Elschenbroich, C., Paganelli, F., Nowotny, M., Neum\u00fcller, B. & Burghaus, O. Trovacene chemistry. 10. the [cyclic] [1]- and [2]silatrovacenophanes (\u03b77-C7H6)V(\u03b75-C5H4SiR2) and (\u03b77-C7H6)V(\u03b75-C5H4SiR2SiR2) (R=Me, Ph): synthesis, structure, and ring opening. Z. Anorg. Allg. Chem. 630, 1599\u20131606 (2004).","journal-title":"Z. Anorg. Allg. Chem."}],"container-title":["Nature Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/nmat1649.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/nmat1649","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/nmat1649.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,7,6]],"date-time":"2022-07-06T18:12:14Z","timestamp":1657131134000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/nmat1649"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2006,5,14]]},"references-count":34,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2006,6,1]]}},"alternative-id":["BFnmat1649"],"URL":"https:\/\/doi.org\/10.1038\/nmat1649","relation":{},"ISSN":["1476-1122","1476-4660"],"issn-type":[{"value":"1476-1122","type":"print"},{"value":"1476-4660","type":"electronic"}],"subject":[],"published":{"date-parts":[[2006,5,14]]},"assertion":[{"value":"12 December 2005","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"3 April 2006","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"14 May 2006","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"The authors declare no competing financial interests.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}]}}