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Whereas white phosphorus is a metastable modification that can be stored under certain conditions, storage of the extremely (light- and air-)sensitive form of arsenic, yellow arsenic, is a challenge rarely tackled so far. Herein, we report on the facile storage and release of these tetrahedral E<jats:sub>4<\/jats:sub> molecules (E\u2009=\u2009P, As) using activated carbon as a porous storage material. These loaded materials are air- and light-stable and have been comprehensively characterized by solid-state <jats:sup>31<\/jats:sup>P{<jats:sup>1<\/jats:sup>H} MAS NMR spectroscopy, powder X-ray diffraction analysis, nitrogen adsorption measurements, and thermogravimetric analysis. Additionally, we show that these materials can be used as a suitable E<jats:sub>4<\/jats:sub> source for releasing intact white phosphorus or yellow arsenic, enabling subsequent reactions in solution. Because the uptake and release of E<jats:sub>4<\/jats:sub> are reversible, these materials are excellent carriers of these highly reactive modifications.<\/jats:p>","DOI":"10.1038\/s41467-017-02735-2","type":"journal-article","created":{"date-parts":[[2018,1,18]],"date-time":"2018-01-18T19:52:39Z","timestamp":1516305159000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":51,"title":["Facile storage and release of white phosphorus and yellow arsenic"],"prefix":"10.1038","volume":"9","author":[{"given":"Andreas E.","family":"Seitz","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Felix","family":"Hippauf","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Werner","family":"Kremer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Stefan","family":"Kaskel","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2182-5020","authenticated-orcid":false,"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"297","published-online":{"date-parts":[[2018,1,24]]},"reference":[{"key":"2735_CR1","doi-asserted-by":"publisher","first-page":"660","DOI":"10.1002\/anie.196906601","volume":"8","author":"F Krafft","year":"1969","unstructured":"Krafft, F. 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The remaining\u00a0author declares no competing financial interests.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}],"article-number":"361"}}