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In this context, the combination of Li\n                    <jats:sub>10<\/jats:sub>\n                    GeP\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>12<\/jats:sub>\n                    solid electrolyte and LiNi\n                    <jats:sub>1-x-y<\/jats:sub>\n                    Co\n                    <jats:sub>x<\/jats:sub>\n                    Mn\n                    <jats:sub>y<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    positive electrode active materials is considered promising despite the yet unsatisfactory battery performance induced by the thermodynamically unstable electrode|electrolyte interface. Here, we report electrochemical and spectrometric studies to monitor the interface evolution during cycling and understand the reactivity and degradation kinetics. We found that the Wagner-type model for diffusion-controlled reactions describes the degradation kinetics very well, suggesting that electronic transport limits the growth of the degradation layer formed at the electrode|electrolyte interface. Furthermore, we demonstrate that the rate of interfacial degradation increases with the state of charge and the presence of two oxidation mechanisms at medium (3.7\u2009V\n                    <jats:italic>vs<\/jats:italic>\n                    . Li\n                    <jats:sup>+<\/jats:sup>\n                    \/Li &lt;\n                    <jats:italic>E<\/jats:italic>\n                    \u2009&lt;\u20094.2\u2009V\n                    <jats:italic>vs<\/jats:italic>\n                    . Li\n                    <jats:sup>+<\/jats:sup>\n                    \/Li) and high (\n                    <jats:italic>E<\/jats:italic>\n                    \u2009\u2265\u20094.2\u2009V\n                    <jats:italic>vs<\/jats:italic>\n                    . Li\n                    <jats:sup>+<\/jats:sup>\n                    \/Li) potentials. A high state of charge (&gt;80%) triggers the structural instability and oxygen release at the positive electrode and leads to more severe degradation.\n                  <\/jats:p>","DOI":"10.1038\/s41467-021-26895-4","type":"journal-article","created":{"date-parts":[[2021,11,18]],"date-time":"2021-11-18T06:06:20Z","timestamp":1637215580000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":187,"title":["A mechanistic investigation of the Li10GeP2S12|LiNi1-x-yCoxMnyO2 interface stability in all-solid-state lithium batteries"],"prefix":"10.1038","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3594-7029","authenticated-orcid":false,"given":"Tong-Tong","family":"Zuo","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Raffael","family":"Rue\u00df","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruijun","family":"Pan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Felix","family":"Walther","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8867-950X","authenticated-orcid":false,"given":"Marcus","family":"Rohnke","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Satoshi","family":"Hori","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ryoji","family":"Kanno","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2198-0218","authenticated-orcid":false,"given":"Daniel","family":"Schr\u00f6der","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9221-4756","authenticated-orcid":false,"given":"J\u00fcrgen","family":"Janek","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2021,11,18]]},"reference":[{"key":"26895_CR1","doi-asserted-by":"publisher","first-page":"16141","DOI":"10.1038\/nenergy.2016.141","volume":"1","author":"J Janek","year":"2016","unstructured":"Janek, J. & Zeier, W. 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