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However, the inherent challenge of direct electrocatalytic reduction of inert CO<jats:sub>2<\/jats:sub> often results in the formation of Li<jats:sub>2<\/jats:sub>CO<jats:sub>3<\/jats:sub>, causing a dip in output voltage and energy efficiency. Our innovative approach involves solid redox mediators, affixed to the cathode via a Cu(II) coordination compound of benzene-1,3,5-tricarboxylic acid. This technique effectively circumvents the shuttle effect and sluggish kinetics associated with soluble redox mediators. Results show that the electrochemically reduced Cu(I) solid redox mediator efficiently captures CO<jats:sub>2<\/jats:sub>, facilitating Li<jats:sub>2<\/jats:sub>C<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub> formation through a dimerization reaction involving a dimeric oxalate intermediate. The Li-CO<jats:sub>2<\/jats:sub> battery employing the Cu(II) solid redox mediator boasts a higher discharge voltage of 2.8\u2009V, a lower charge potential of 3.7\u2009V, and superior cycling performance over 400 cycles. 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