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By incorporating efficient Li<jats:sup>+<\/jats:sup> diffusion channels found in inorganic solid-state electrolytes and polar functional groups present in solid polymer electrolytes, it is conceivable to design inorganic-organic hybrid solid-state electrolytes to achieve true fusion and synergy in performance. Herein, we demonstrate that traditional metal coordination compounds can serve as exceptional Li<jats:sup>+<\/jats:sup> ion conductors at room temperature through rational structural design. Specifically, we synthesize copper maleate hydrate nanoflakes via bottom-up self-assembly featuring highly-ordered 1D channels that are interconnected by Cu<jats:sup>2+<\/jats:sup>\/Cu<jats:sup>+<\/jats:sup> nodes and maleic acid ligands, alongside rich COO<jats:sup>\u2212<\/jats:sup> groups and structural water within the channels. Benefiting from the combination of ion-hopping and coupling-dissociation mechanisms, Li<jats:sup>+<\/jats:sup> ions can preferably transport through these channels rapidly. Thus, the Li<jats:sup>+<\/jats:sup>-implanted copper maleate hydrate solid-state electrolytes shows remarkable ionic conductivity (1.17 \u00d7 10<jats:sup>\u22124<\/jats:sup>\u2009S\u2009cm<jats:sup>\u22121<\/jats:sup> at room temperature), high Li<jats:sup>+<\/jats:sup> transference number (0.77), and a 4.7 V-wide operating window. More impressively, Li<jats:sup>+<\/jats:sup>-implanted copper maleate hydrate solid-state electrolytes are demonstrated to have exceptional compatibility with both cathode and Li anode, enabling long-term stability of more than 800 cycles. This work brings new insight on exploring superior room-temperature ionic conductors based on metal coordination compounds.<\/jats:p>","DOI":"10.1038\/s41467-024-45372-2","type":"journal-article","created":{"date-parts":[[2024,2,5]],"date-time":"2024-02-05T13:03:17Z","timestamp":1707138197000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":108,"title":["Self-assembled hydrated copper coordination compounds as ionic conductors for room temperature solid-state batteries"],"prefix":"10.1038","volume":"15","author":[{"given":"Xiao","family":"Zhan","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Miao","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaolin","family":"Zhao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaning","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sha","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weiwei","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5303-5771","authenticated-orcid":false,"given":"Jiande","family":"Lin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0635-9789","authenticated-orcid":false,"given":"Zi-Ang","family":"Nan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0045-6169","authenticated-orcid":false,"given":"Jiawei","family":"Yan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhefei","family":"Sun","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8533-0882","authenticated-orcid":false,"given":"Haodong","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2057-5130","authenticated-orcid":false,"given":"Fei","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiayu","family":"Wan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2452-6966","authenticated-orcid":false,"given":"Jianjun","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3584-5201","authenticated-orcid":false,"given":"Qiaobao","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0016-2918","authenticated-orcid":false,"given":"Li","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2024,2,5]]},"reference":[{"key":"45372_CR1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-33151-w","volume":"13","author":"SQ Zhang","year":"2022","unstructured":"Zhang, S. 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