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Herein, an aryldiphosphine ligand (\n                    <jats:bold>L11<\/jats:bold>\n                    ) bearing the [Ph\n                    <jats:sub>2<\/jats:sub>\n                    P(ortho-C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    )]\n                    <jats:sub>2<\/jats:sub>\n                    CH\n                    <jats:sub>2<\/jats:sub>\n                    skeleton is reported for palladium-catalyzed regioselective carbonylation of alkenes. Compared with the industrially successful Pd\/1,2-bis(di-tert-butylphosphinomethyl)benzene catalyst, catalytic efficiency catalyzed by Pd\/\n                    <jats:bold>L11<\/jats:bold>\n                    on methoxycarbonylation of ethylene is obtained, exhibiting better catalytic performance (TON: &gt;2,390,000; TOF: 100,000\u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ; selectivity: &gt;99%) and stronger oxygen-resistance stability. Moreover, a substrate compatibility (122 examples) including chiral and bioactive alkenes or alcohols is achieved with up to 99% yield and 99% regioselectivity. Experimental and computational investigations show that the appropriate bite angle of aryldiphosphine ligand and the favorable interaction of 1,4-dioxane with Pd\/\n                    <jats:bold>L11<\/jats:bold>\n                    synergistically contribute to high activity and selectivity while the electron deficient phosphines originated from electron delocalization endow\n                    <jats:bold>L11<\/jats:bold>\n                    with excellent oxygen-resistance stability.\n                  <\/jats:p>","DOI":"10.1038\/s41467-024-46286-9","type":"journal-article","created":{"date-parts":[[2024,3,5]],"date-time":"2024-03-05T14:02:33Z","timestamp":1709647353000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["Identification of a potent palladium-aryldiphosphine catalytic system for high-performance carbonylation of alkenes"],"prefix":"10.1038","volume":"15","author":[{"given":"Kang","family":"Zhao","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8746-3977","authenticated-orcid":false,"given":"Hongli","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Teng","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shujuan","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4614-1568","authenticated-orcid":false,"given":"Enrico","family":"Benassi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yao","family":"Yao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaojun","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3656-1139","authenticated-orcid":false,"given":"Xinjiang","family":"Cui","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5665-4933","authenticated-orcid":false,"given":"Feng","family":"Shi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2024,3,5]]},"reference":[{"key":"46286_CR1","doi-asserted-by":"publisher","first-page":"1159","DOI":"10.1038\/nchem.2586","volume":"8","author":"H Li","year":"2016","unstructured":"Li, H. et al. 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