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Here, we present a zeolite nanoreactor with joint gas-solid-liquid interfaces for boosting H<jats:sub>2<\/jats:sub> gas and substrates to involve reactions. Specifically, the Pt active sites are encapsulated within zeolite crystals, followed by modifying the external zeolite surface with organosilanes. The silane sheath with aerophilic\/hydrophobic properties can promote the diffusion of H<jats:sub>2<\/jats:sub> and the mass transfer of reactant\/product molecules. In aqueous solutions, the gaseous H<jats:sub>2<\/jats:sub> molecules can rapidly diffuse into the zeolite channels, thereby augmenting H<jats:sub>2<\/jats:sub> concentration surround Pt sites. Simultaneously, the silane sheath with lipophilicity nature promotes the enrichment of the aldehydes\/ketones on the catalyst and facilitates the hydrophilia products of alcohol rediffusion back to the aqueous phase. By modifying the wettability of the catalyst, the hydrogenation of aldehydes\/ketones can be operated in water at ambient H<jats:sub>2<\/jats:sub> pressure, resulting in a noteworthy turnover frequency up to 92.3\u2009h<jats:sup>\u22121<\/jats:sup> and a 4.3-fold increase in reaction rate compared to the unmodified catalyst.<\/jats:p>","DOI":"10.1038\/s41467-024-46505-3","type":"journal-article","created":{"date-parts":[[2024,3,7]],"date-time":"2024-03-07T14:04:13Z","timestamp":1709820253000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":54,"title":["Surface hydrophobization of zeolite enables mass transfer matching in gas-liquid-solid three-phase hydrogenation under ambient pressure"],"prefix":"10.1038","volume":"15","author":[{"given":"Shuai","family":"Wang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Riming","family":"Hu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianyu","family":"Ren","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yipin","family":"Lv","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lianghao","family":"Song","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huaiqing","family":"Zhao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuchuan","family":"Jiang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4963-3813","authenticated-orcid":false,"given":"Daowei","family":"Gao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guozhu","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2024,3,7]]},"reference":[{"key":"46505_CR1","doi-asserted-by":"publisher","first-page":"11522","DOI":"10.1021\/acs.chemrev.7b00272","volume":"117","author":"F Meemken","year":"2017","unstructured":"Meemken, F. & Baiker, A. 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