{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T14:16:27Z","timestamp":1791728187626,"version":"4.3.4"},"reference-count":72,"publisher":"Springer Science and Business Media LLC","issue":"1","license":[{"start":{"date-parts":[[2024,9,14]],"date-time":"2024-09-14T00:00:00Z","timestamp":1726272000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0"},{"start":{"date-parts":[[2024,9,14]],"date-time":"2024-09-14T00:00:00Z","timestamp":1726272000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22178369, 22172182 and 22108310"],"award-info":[{"award-number":["22178369, 22172182 and 22108310"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Nat Commun"],"DOI":"10.1038\/s41467-024-52482-4","type":"journal-article","created":{"date-parts":[[2024,9,14]],"date-time":"2024-09-14T14:02:29Z","timestamp":1726322549000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["Dual-engine-driven realizing high-yield synthesis of Para-Xylene directly from CO2-containing syngas"],"prefix":"10.1038","volume":"15","author":[{"given":"Xuemei","family":"Wu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengwei","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shengying","family":"Zhao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2245-9595","authenticated-orcid":false,"given":"Yang","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Yao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weizhe","family":"Gao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Baizhang","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Taiki","family":"Arakawa","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8799-1991","authenticated-orcid":false,"given":"Yingluo","family":"He","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fei","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minghui","family":"Tan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9799-0984","authenticated-orcid":false,"given":"Guohui","family":"Yang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6786-5058","authenticated-orcid":false,"given":"Noritatsu","family":"Tsubaki","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2024,9,14]]},"reference":[{"key":"52482_CR1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119648","volume":"283","author":"J Wei","year":"2021","unstructured":"Wei, J. et al. Precisely regulating Br\u00f8nsted acid sites to promote the synthesis of light aromatics via CO2 hydrogenation. Appl. Catal. B: Environ. 283, 119648 (2021).","journal-title":"Appl. Catal. B: Environ."},{"key":"52482_CR2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.119929","volume":"286","author":"T Wang","year":"2021","unstructured":"Wang, T. et al. ZnZrOx integrated with chain-like nanocrystal HZSM-5 as efficient catalysts for aromatics synthesis from CO2 hydrogenation. Appl. Catal. B: Environ. 286, 119929 (2021).","journal-title":"Appl. Catal. B: Environ."},{"key":"52482_CR3","doi-asserted-by":"publisher","first-page":"7786","DOI":"10.1039\/D1SC01859K","volume":"12","author":"Y Wang","year":"2021","unstructured":"Wang, Y. et al. Boosting the synthesis of value-added aromatics directly from syngas via a Cr2O3 and Ga doped zeolite capsule catalyst. Chem. Sci. 12, 7786\u20137792 (2021).","journal-title":"Chem. Sci."},{"key":"52482_CR4","doi-asserted-by":"publisher","first-page":"174","DOI":"10.1016\/j.jechem.2020.05.063","volume":"54","author":"Y Ni","year":"2021","unstructured":"Ni, Y., Zhu, W. & Liu, Z. Formaldehyde intermediate participating in the conversion of methanol to aromatics over zinc modified H-ZSM-5. J. Energy Chem. 54, 174\u2013178 (2021).","journal-title":"J. Energy Chem."},{"key":"52482_CR5","doi-asserted-by":"publisher","first-page":"530","DOI":"10.1016\/j.gee.2021.07.003","volume":"2","author":"Y Fu","year":"2023","unstructured":"Fu, Y. et al. Insights into the size effect of ZnCr2O4 spinel oxide in composite catalysts for conversion of syngas to aromatics. Green. Energy Environ. 2, 530\u2013537 (2023).","journal-title":"Green. Energy Environ."},{"key":"52482_CR6","doi-asserted-by":"publisher","first-page":"597","DOI":"10.1016\/j.jechem.2021.03.044","volume":"66","author":"Y Fu","year":"2022","unstructured":"Fu, Y., Ni, Y., Chen, Z., Zhu, W. & Liu, Z. Achieving high conversion of syngas to aromatics. J. Energy Chem. 66, 597\u2013602 (2022).","journal-title":"J. Energy Chem."},{"key":"52482_CR7","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120098","volume":"291","author":"T Fu","year":"2021","unstructured":"Fu, T., Shao, J. & Li, Z. Catalytic synergy between the low Si\/Al ratio Zn\/ZSM-5 and high Si\/Al ratio HZSM-5 for high-performance methanol conversion to aromatics. Appl. Catal. B: Environ. 291, 120098 (2021).","journal-title":"Appl. Catal. B: Environ."},{"key":"52482_CR8","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201803390","volume":"31","author":"S Kasipandi","year":"2019","unstructured":"Kasipandi, S. & Bae, J. W. Recent advances in direct synthesis of value-added aromatic chemicals from syngas by cascade reactions over bifunctional catalysts. Adv. Mater. 31, 1803390 (2019).","journal-title":"Adv. Mater."},{"key":"52482_CR9","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2019.116851","volume":"264","author":"M Ali","year":"2020","unstructured":"Ali, M., Koo, H.-M., Kasipandi, S., Han, G. Y. & Bae, J. W. Direct synthesis of liquid fuels and aromatics from syngas over mesoporous FeZrOx catalyst mixed with Mo\/ferrierite. Fuel 264, 116851 (2020).","journal-title":"Fuel"},{"key":"52482_CR10","doi-asserted-by":"publisher","first-page":"779","DOI":"10.1016\/j.checat.2022.01.014","volume":"2","author":"H Wang","year":"2022","unstructured":"Wang, H. et al. Bifunctional catalysts with versatile zeolites enable unprecedented para-xylene productivity for syngas conversion under mild conditions. Chem. Catal. 2, 779\u2013796 (2022).","journal-title":"Chem. Catal."},{"key":"52482_CR11","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2021.111622","volume":"509","author":"M Han","year":"2021","unstructured":"Han, M. et al. Effect of Lewis\/Br\u00f8nsted acid sites in HZSM\u22125 zeolite on the selectivity of para-xylene during methylation of toluene with methanol. Mol. Catal. 509, 111622 (2021).","journal-title":"Mol. Catal."},{"key":"52482_CR12","doi-asserted-by":"publisher","first-page":"967","DOI":"10.1007\/s11144-021-01929-6","volume":"132","author":"Y Zhao","year":"2021","unstructured":"Zhao, Y., Ma, X., Ren, D. & Xia, Y. A strategy to improve the para-selectivity in toluene methylation on P2O5-ZSM-5 modified by the para-xylene placeholder method. React. Kinet., Mech. Catal. 132, 967\u2013981 (2021).","journal-title":"React. Kinet., Mech. Catal."},{"key":"52482_CR13","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-12285-4","volume":"10","author":"C Wang","year":"2019","unstructured":"Wang, C. et al. Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene. Nat. Commun. 10, 4348 (2019).","journal-title":"Nat. Commun."},{"key":"52482_CR14","doi-asserted-by":"publisher","first-page":"7941","DOI":"10.1039\/C7SC03427J","volume":"8","author":"P Zhang","year":"2017","unstructured":"Zhang, P., Tan, L., Yang, G. & Tsubaki, N. One-pass selective conversion of syngas to para-xylene. Chem. Sci. 8, 7941\u20137946 (2017).","journal-title":"Chem. Sci."},{"key":"52482_CR15","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-33217-9","volume":"13","author":"G Tian","year":"2022","unstructured":"Tian, G. et al. Accelerating syngas-to-aromatic conversion via spontaneously monodispersed Fe in ZnCr2O4 spinel. Nat. Commun. 13, 5567 (2022).","journal-title":"Nat. Commun."},{"key":"52482_CR16","doi-asserted-by":"publisher","first-page":"7389","DOI":"10.1021\/acscatal.9b05200","volume":"10","author":"D Miao","year":"2020","unstructured":"Miao, D. et al. Selective synthesis of benzene, toluene, and xylenes from syngas. ACS Catal. 10, 7389\u20137397 (2020).","journal-title":"ACS Catal."},{"key":"52482_CR17","doi-asserted-by":"publisher","first-page":"334","DOI":"10.1016\/j.chempr.2017.05.007","volume":"3","author":"K Cheng","year":"2017","unstructured":"Cheng, K. et al. Bifunctional catalysts for one-step conversion of syngas into aromatics with excellent selectivity and stability. Chem 3, 334\u2013347 (2017).","journal-title":"Chem"},{"key":"52482_CR18","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120906","volume":"303","author":"W Gao","year":"2022","unstructured":"Gao, W. et al. Capsule-like zeolite catalyst fabricated by solvent-free strategy for para-Xylene formation from CO2 hydrogenation. Appl. Catal. B: Environ. 303, 120906 (2022).","journal-title":"Appl. Catal. B: Environ."},{"key":"52482_CR19","doi-asserted-by":"publisher","first-page":"6541","DOI":"10.1002\/cssc.202002305","volume":"13","author":"W Gao","year":"2020","unstructured":"Gao, W. et al. Selective conversion of CO2 into para-xylene over a ZnCr2O4-ZSM-5 catalyst. ChemSusChem 13, 6541\u20136545 (2020).","journal-title":"ChemSusChem"},{"key":"52482_CR20","doi-asserted-by":"publisher","first-page":"5149","DOI":"10.1002\/chem.201806165","volume":"25","author":"Y Wang","year":"2019","unstructured":"Wang, Y. et al. Direct and oriented conversion of CO2 into value-added aromatics. Chemistry. A Eur. J. 25, 5149\u20135153 (2019).","journal-title":"A Eur. J."},{"key":"52482_CR21","doi-asserted-by":"publisher","first-page":"895","DOI":"10.1021\/acscatal.8b01344","volume":"9","author":"Y Wang","year":"2019","unstructured":"Wang, Y. et al. Rationally designing bifunctional catalysts as an efficient strategy to boost CO2 hydrogenation producing value-added aromatics. ACS Catal. 9, 895\u2013901 (2019).","journal-title":"ACS Catal."},{"key":"52482_CR22","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120956","volume":"304","author":"C Tu","year":"2022","unstructured":"Tu, C. et al. CO2-assisted ethane aromatization over zinc and phosphorous modified ZSM-5 catalysts. Appl. Catal. B: Environ. 304, 120956 (2022).","journal-title":"Appl. Catal. B: Environ."},{"key":"52482_CR23","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120813","volume":"301","author":"MG Sibi","year":"2022","unstructured":"Sibi, M. G., Khan, M. K., Verma, D., Yoon, W. & Kim, J. High-yield synthesis of BTEX over Na-FeAlOx\/Zn-HZSM-5@SiO2 by direct CO2 conversion and identification of surface intermediates. Appl. Catal. B: Environ. 301, 120813 (2022).","journal-title":"Appl. Catal. B: Environ."},{"key":"52482_CR24","doi-asserted-by":"publisher","first-page":"302","DOI":"10.1021\/acscatal.9b04309","volume":"10","author":"C Zhou","year":"2020","unstructured":"Zhou, C. et al. Highly active ZnO-ZrO2 aerogels integrated with H-ZSM-5 for aromatics synthesis from carbon dioxide. ACS Catal. 10, 302\u2013310 (2020).","journal-title":"ACS Catal."},{"key":"52482_CR25","doi-asserted-by":"publisher","first-page":"385","DOI":"10.1016\/j.gee.2019.12.001","volume":"5","author":"X Huang","year":"2020","unstructured":"Huang, X. et al. Catalyst design strategies towards highly shape-selective HZSM-5 for para-xylene through toluene alkylation. Green. Energy Environ. 5, 385\u2013393 (2020).","journal-title":"Green. Energy Environ."},{"key":"52482_CR26","doi-asserted-by":"publisher","first-page":"28940","DOI":"10.1039\/C7RA04111J","volume":"7","author":"Q Hu","year":"2017","unstructured":"Hu, Q. et al. High yield production of C2-C3 olefins and para-xylene from methanol using a SiO2-coated FeOx\/ZSM-5 catalyst. RSC Adv. 7, 28940\u201328944 (2017).","journal-title":"RSC Adv."},{"key":"52482_CR27","doi-asserted-by":"publisher","first-page":"74797","DOI":"10.1039\/C6RA19073A","volume":"6","author":"Y Ma","year":"2016","unstructured":"Ma, Y. et al. The influence of straight pore blockage on the selectivity of methanol to aromatics in nanosized Zn\/ZSM-5: An atomic Cs-corrected STEM analysis study. RSC Adv. 6, 74797\u201374801 (2016).","journal-title":"RSC Adv."},{"key":"52482_CR28","doi-asserted-by":"publisher","first-page":"2982","DOI":"10.1021\/acscatal.5b00192","volume":"5","author":"J Zhang","year":"2015","unstructured":"Zhang, J., Qian, W., Kong, C. & Wei, F. Increasing para-xylene selectivity in making aromatics from methanol with a surface-modified Zn\/P\/ZSM-5 catalyst. ACS Catal. 5, 2982\u20132988 (2015).","journal-title":"ACS Catal."},{"key":"52482_CR29","doi-asserted-by":"publisher","first-page":"191","DOI":"10.1016\/j.apcatb.2017.08.056","volume":"220","author":"S Kim","year":"2018","unstructured":"Kim, S. et al. Gd\/HZSM-5 catalyst for conversion of methanol to hydrocarbons: effects of amounts of the Gd loading and catalyst preparation method. Appl. Catal. B: Environ. 220, 191\u2013201 (2018).","journal-title":"Appl. Catal. B: Environ."},{"key":"52482_CR30","doi-asserted-by":"publisher","first-page":"721","DOI":"10.1016\/j.apcatb.2018.11.023","volume":"243","author":"N Wang","year":"2019","unstructured":"Wang, N. et al. Modulation of b-axis thickness within MFI zeolite: Correlation with variation of product diffusion and coke distribution in the methanol-to-hydrocarbons conversion. Appl. Catal. B: Environ. 243, 721\u2013733 (2019).","journal-title":"Appl. Catal. B: Environ."},{"key":"52482_CR31","doi-asserted-by":"publisher","first-page":"15453","DOI":"10.1021\/acs.iecr.9b03357","volume":"58","author":"J Zhang","year":"2019","unstructured":"Zhang, J. et al. Solvent-free synthesis of core-shell Zn\/ZSM-5@silicalite\u22121 catalyst for selective conversion of methanol to BTX aromatics. Ind. Eng. Chem. Res. 58, 15453\u201315458 (2019).","journal-title":"Ind. Eng. Chem. Res."},{"key":"52482_CR32","doi-asserted-by":"publisher","first-page":"18","DOI":"10.1016\/j.micromeso.2014.04.050","volume":"196","author":"W Tan","year":"2014","unstructured":"Tan, W. et al. Para-selective methylation of toluene with methanol over nano-sized ZSM-5 catalysts: Synergistic effects of surface modifications with SiO2, P2O5 and MgO. Microporous Mesoporous Mater. 196, 18\u201330 (2014).","journal-title":"Microporous Mesoporous Mater."},{"key":"52482_CR33","doi-asserted-by":"publisher","first-page":"120241","DOI":"10.1016\/j.apcatb.2021.120241","volume":"293","author":"G Xu","year":"2021","unstructured":"Xu, G. & Zhu, X. A core-shell structured Zn\/SiO2@ZSM-5 catalyst: Preparation and enhanced catalytic properties in methane co-aromatization with propane. Appl. Catal. B: Environ. 293, 120241 (2021).","journal-title":"Appl. Catal. B: Environ."},{"key":"52482_CR34","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2019.118112","volume":"259","author":"I Hita","year":"2019","unstructured":"Hita, I. et al. Enhanced production of phenolics and aromatics from raw bio-oil using HZSM-5 zeolite additives for PtPd\/C and NiW\/C catalysts. Appl. Catal. B: Environ. 259, 118112 (2019).","journal-title":"Appl. Catal. B: Environ."},{"key":"52482_CR35","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119467","volume":"281","author":"S He","year":"2021","unstructured":"He, S. et al. Catalytic conversion of pure glycerol over an un-modified H-ZSM-5 zeolite to bio-based aromatics. Appl. Catal. B: Environ. 281, 119467 (2021).","journal-title":"Appl. Catal. B: Environ."},{"key":"52482_CR36","doi-asserted-by":"publisher","first-page":"2477","DOI":"10.1021\/acscatal.9b03417","volume":"10","author":"MT Arslan","year":"2020","unstructured":"Arslan, M. T. et al. Selective conversion of syngas into tetramethylbenzene via an aldol-aromatic mechanism. ACS Catal. 10, 2477\u20132488 (2020).","journal-title":"ACS Catal."},{"key":"52482_CR37","doi-asserted-by":"publisher","first-page":"4476","DOI":"10.1021\/acscatal.0c05658","volume":"11","author":"Y Xu","year":"2021","unstructured":"Xu, Y. et al. Yolk@ shell FeMn@ hollow HZSM-5 nanoreactor for directly converting syngas to aromatics. ACS Catal. 11, 4476\u20134485 (2021).","journal-title":"ACS Catal."},{"key":"52482_CR38","doi-asserted-by":"publisher","first-page":"3553","DOI":"10.1021\/acscatal.1c00169","volume":"11","author":"T Wang","year":"2021","unstructured":"Wang, T. et al. Sodium-mediated bimetallic Fe-Ni catalyst boosts stable and selective production of light aromatics over HZSM-5 zeolite. ACS Catal. 11, 3553\u20133574 (2021).","journal-title":"ACS Catal."},{"key":"52482_CR39","doi-asserted-by":"publisher","first-page":"1966","DOI":"10.1002\/cctc.202100024","volume":"13","author":"MA Nawaz","year":"2021","unstructured":"Nawaz, M. A. et al. Harnessing the synergistic interplay of Fischer-Tropsch synthesis (Fe-Co) bimetallic oxides in Na-FeMnCo\/HZSM-5 composite catalyst for syngas conversion to aromatic hydrocarbons. ChemCatChem 13, 1966\u20131980 (2021).","journal-title":"ChemCatChem"},{"key":"52482_CR40","doi-asserted-by":"publisher","first-page":"3797","DOI":"10.1021\/acscatal.9b05449","volume":"10","author":"X Yang","year":"2020","unstructured":"Yang, X. et al. Exploring the reaction paths in the consecutive Fe-based FT catalyst-zeolite process for syngas conversion. ACS Catal. 10, 3797\u20133806 (2020).","journal-title":"ACS Catal."},{"key":"52482_CR41","doi-asserted-by":"publisher","first-page":"4419","DOI":"10.1021\/acs.iecr.0c00237","volume":"59","author":"T Sun","year":"2020","unstructured":"Sun, T. et al. Syngas conversion to aromatics over the Co2C-based catalyst and HZSM-5 via a tandem system. Ind. Eng. Chem. Res. 59, 4419\u20134427 (2020).","journal-title":"Ind. Eng. Chem. Res."},{"key":"52482_CR42","doi-asserted-by":"publisher","first-page":"5147","DOI":"10.1021\/acscatal.9b01045","volume":"9","author":"Y Xu","year":"2019","unstructured":"Xu, Y. et al. Selective conversion of syngas to aromatics over Fe3O4@ MnO2 and hollow HZSM-5 bifunctional catalysts. ACS Catal. 9, 5147\u20135156 (2019).","journal-title":"ACS Catal."},{"key":"52482_CR43","doi-asserted-by":"publisher","first-page":"323","DOI":"10.1016\/j.chempr.2017.06.017","volume":"3","author":"B Zhao","year":"2017","unstructured":"Zhao, B. et al. Direct transformation of syngas to aromatics over Na-Zn-Fe5C2 and hierarchical HZSM-5 tandem catalysts. Chem 3, 323\u2013333 (2017).","journal-title":"Chem"},{"key":"52482_CR44","doi-asserted-by":"publisher","first-page":"15227","DOI":"10.1021\/acscatal.0c03658","volume":"10","author":"C Liu","year":"2020","unstructured":"Liu, C. et al. Insights into the key factor of zeolite morphology on the selective conversion of syngas to light aromatics over a Cr2O3\/ZSM-5 catalyst. ACS Catal. 10, 15227\u201315237 (2020).","journal-title":"ACS Catal."},{"key":"52482_CR45","doi-asserted-by":"publisher","first-page":"4519","DOI":"10.1002\/cctc.201800911","volume":"10","author":"Z Huang","year":"2018","unstructured":"Huang, Z. et al. Ceria-zirconia\/zeolite bifunctional catalyst for highly selective conversion of syngas into aromatics. ChemCatChem 10, 4519\u20134524 (2018).","journal-title":"ChemCatChem"},{"key":"52482_CR46","doi-asserted-by":"publisher","first-page":"119815","DOI":"10.1016\/j.apcatb.2020.119815","volume":"285","author":"Z Yang","year":"2021","unstructured":"Yang, Z. et al. Tuning direct CO hydrogenation reaction over Fe-Mn bimetallic catalysts toward light olefins: Effects of Mn promotion. Appl. Catal. B: Environ. 285, 119815 (2021).","journal-title":"Appl. Catal. B: Environ."},{"key":"52482_CR47","doi-asserted-by":"publisher","first-page":"7610","DOI":"10.1021\/acscatal.7b01822","volume":"7","author":"H Song","year":"2017","unstructured":"Song, H. et al. Spinel-structured ZnCr2O4 with excess Zn is the active ZnO\/Cr2O3 catalyst for high-temperature methanol synthesis. ACS Catal. 7, 7610\u20137622 (2017).","journal-title":"ACS Catal."},{"key":"52482_CR48","doi-asserted-by":"publisher","first-page":"65","DOI":"10.1007\/BF00765056","volume":"3","author":"E Errani","year":"1989","unstructured":"Errani, E., Trifiro, F., Vaccari, A., Richter, M. & Del Piero, G. Structure and reactivity of Zn-Cr mixed oxides. Role of non-stoichiometry in the catalytic synthesis of methanol. Catal. Lett. 3, 65\u201372 (1989).","journal-title":"Catal. Lett."},{"key":"52482_CR49","doi-asserted-by":"publisher","first-page":"8793","DOI":"10.1021\/acscatal.2c02125","volume":"12","author":"Y Li","year":"2022","unstructured":"Li, Y. et al. Distance for communication between metal and acid sites for syngas conversion. ACS Catal. 12, 8793\u20138801 (2022).","journal-title":"ACS Catal."},{"key":"52482_CR50","doi-asserted-by":"publisher","first-page":"11268","DOI":"10.1021\/acscatal.0c02722","volume":"10","author":"G Song","year":"2020","unstructured":"Song, G., Li, M., Yan, P., Nawaz, M. A. & Liu, D. High conversion to aromatics via CO2-FT over a CO-reduced Cu-Fe2O3 catalyst integrated with HZSM-5. ACS Catal. 10, 11268\u201311279 (2020).","journal-title":"ACS Catal."},{"key":"52482_CR51","doi-asserted-by":"publisher","first-page":"68","DOI":"10.1038\/nature20782","volume":"541","author":"W Karim","year":"2017","unstructured":"Karim, W. et al. Catalyst support effects on hydrogen spillover. Nature 541, 68\u201371 (2017).","journal-title":"Nature"},{"key":"52482_CR52","doi-asserted-by":"publisher","first-page":"10","DOI":"10.1016\/j.apcata.2018.01.019","volume":"554","author":"D Pe\u00f1a","year":"2018","unstructured":"Pe\u00f1a, D. et al. Identification of carbon species on iron-based catalysts during Fischer-Tropsch synthesis. Appl. Catal. A: Gen. 554, 10\u201323 (2018).","journal-title":"Appl. Catal. A: Gen."},{"key":"52482_CR53","doi-asserted-by":"publisher","DOI":"10.1038\/srep26184","volume":"6","author":"XW Liu","year":"2016","unstructured":"Liu, X. W. et al. M\u00f6ssbauer spectroscopy of iron carbides: From prediction to experimental confirmation. Sci. Rep. 6, 26184 (2016).","journal-title":"Sci. Rep."},{"key":"52482_CR54","doi-asserted-by":"publisher","first-page":"108","DOI":"10.1016\/j.jcat.2019.08.027","volume":"381","author":"VP Santos","year":"2020","unstructured":"Santos, V. P. et al. Direct conversion of syngas to light olefins (C2-C3) over a tandem catalyst CrZn-SAPO-34: Tailoring activity and stability by varying the Cr\/Zn ratio and calcination temperature. J. Catal. 381, 108\u2013120 (2020).","journal-title":"J. Catal."},{"key":"52482_CR55","doi-asserted-by":"publisher","first-page":"25019","DOI":"10.1021\/jp404984y","volume":"117","author":"S Chen","year":"2013","unstructured":"Chen, S. et al. Cation distribution in ZnCr2O4 nanocrystals investigated by X-ray absorption fine structure spectroscopy. J. Phys. Chem. C. 117, 25019\u201325025 (2013).","journal-title":"J. Phys. Chem. C."},{"key":"52482_CR56","doi-asserted-by":"publisher","first-page":"17876","DOI":"10.1002\/ange.202107264","volume":"133","author":"Y Wang","year":"2021","unstructured":"Wang, Y. et al. Visualizing element migration over bifunctional metal-zeolite catalysts and its impact on catalysis. Angew. Chem. 133, 17876\u201317884 (2021).","journal-title":"Angew. Chem."},{"key":"52482_CR57","doi-asserted-by":"publisher","first-page":"2203","DOI":"10.1021\/acscatal.8b04548","volume":"9","author":"MT Arslan","year":"2019","unstructured":"Arslan, M. T. et al. Single-step conversion of H2-deficient syngas into high yield of tetramethylbenzene. ACS Catal. 9, 2203\u20132212 (2019).","journal-title":"ACS Catal."},{"key":"52482_CR58","doi-asserted-by":"publisher","first-page":"141","DOI":"10.1016\/j.jcat.2015.12.024","volume":"335","author":"JW Harris","year":"2016","unstructured":"Harris, J. W. et al. Titration and quantification of open and closed Lewis acid sites in Sn-Beta zeolites that catalyze glucose isomerization. J. Catal. 335, 141\u2013154 (2016).","journal-title":"J. Catal."},{"key":"52482_CR59","doi-asserted-by":"publisher","first-page":"209","DOI":"10.1016\/j.jcat.2019.08.037","volume":"378","author":"Z Ma","year":"2019","unstructured":"Ma, Z. et al. Co-precipitated Fe-Zr catalysts for the Fischer-Tropsch synthesis of lower olefins (C2O\u223cC4O): Synergistic effects of Fe and Zr. J. Catal. 378, 209\u2013219 (2019).","journal-title":"J. Catal."},{"key":"52482_CR60","doi-asserted-by":"publisher","first-page":"8","DOI":"10.1006\/jcat.2000.3024","volume":"196","author":"Y Jin","year":"2000","unstructured":"Jin, Y. & Datye, A. K. Phase transformations in iron Fischer-Tropsch catalysts during temperature-programmed reduction. J. Catal. 196, 8\u201317 (2000).","journal-title":"J. Catal."},{"key":"52482_CR61","doi-asserted-by":"publisher","first-page":"1352","DOI":"10.1021\/acscatal.7b03457","volume":"8","author":"W Dai","year":"2018","unstructured":"Dai, W. et al. Effect of n-butanol cofeeding on the methanol to aromatics conversion over Ga-modified nano H-ZSM-5 and its mechanistic interpretation. ACS Catal. 8, 1352\u20131362 (2018).","journal-title":"ACS Catal."},{"key":"52482_CR62","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aba5433","volume":"6","author":"J Zuo","year":"2020","unstructured":"Zuo, J. et al. Selective methylation of toluene using CO2 and H2 to para-xylene. Sci. Adv. 6, eaba5433 (2020).","journal-title":"Sci. Adv."},{"key":"52482_CR63","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2022.126874","volume":"337","author":"Q Zhou","year":"2023","unstructured":"Zhou, Q. et al. Development and catalytic mechanism of a highly efficient Pt\/K\u03b2 catalyst for n-heptane aromatization. Fuel 337, 126874 (2023).","journal-title":"Fuel"},{"key":"52482_CR64","doi-asserted-by":"publisher","first-page":"769","DOI":"10.1021\/j100835a017","volume":"64","author":"DW Bassett","year":"1960","unstructured":"Bassett, D. W. & Habgood, H. W. A gas chromatographic study of the catalytic isomerization of cyclopropane1. J. Phys. Chem. 64, 769\u2013773 (1960).","journal-title":"J. Phys. Chem."},{"key":"52482_CR65","doi-asserted-by":"publisher","first-page":"11169","DOI":"10.1103\/PhysRevB.54.11169","volume":"54","author":"G Kresse","year":"1996","unstructured":"Kresse, G. & Furthm\u00fcller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54, 11169 (1996).","journal-title":"Phys. Rev. B"},{"key":"52482_CR66","doi-asserted-by":"publisher","first-page":"15","DOI":"10.1016\/0927-0256(96)00008-0","volume":"6","author":"G Kresse","year":"1996","unstructured":"Kresse, G. & Furthm\u00fcller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 6, 15\u201350 (1996).","journal-title":"Comput. Mater. Sci."},{"key":"52482_CR67","doi-asserted-by":"publisher","first-page":"1758","DOI":"10.1103\/PhysRevB.59.1758","volume":"59","author":"G Kresse","year":"1999","unstructured":"Kresse, G. & Joubert, D. From ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B. Condens. Matter 59, 1758 (1999).","journal-title":"Phys. Rev. B. Condens. Matter"},{"key":"52482_CR68","doi-asserted-by":"publisher","first-page":"3865","DOI":"10.1103\/PhysRevLett.77.3865","volume":"77","author":"JP Perdew","year":"1996","unstructured":"Perdew, J. P., Burke, K. & Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 77, 3865 (1996).","journal-title":"Phys. Rev. Lett."},{"key":"52482_CR69","doi-asserted-by":"publisher","DOI":"10.1063\/1.3382344","volume":"132","author":"S Grimme","year":"2010","unstructured":"Grimme, S., Antony, J., Ehrlich, S. & Krieg, H. A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu. J. Chem. Phys. 132, 154104 (2010).","journal-title":"J. Chem. Phys."},{"key":"52482_CR70","doi-asserted-by":"publisher","first-page":"5288","DOI":"10.1021\/acscatal.9b05552","volume":"10","author":"H Wang","year":"2020","unstructured":"Wang, H. et al. Insight into the effects of water on the ethene to aromatics reaction with HZSM-5. ACS Catal. 10, 5288\u20135298 (2020).","journal-title":"ACS Catal."},{"key":"52482_CR71","doi-asserted-by":"publisher","first-page":"9978","DOI":"10.1063\/1.1323224","volume":"113","author":"G Henkelman","year":"2000","unstructured":"Henkelman, G. & J\u00f3nsson, H. Improved tangent estimate in the nudged elastic band method for finding minimum energy paths and saddle points. J. Chem. Phys. 113, 9978\u20139985 (2000).","journal-title":"J. Chem. Phys."},{"key":"52482_CR72","doi-asserted-by":"publisher","first-page":"7010","DOI":"10.1063\/1.480097","volume":"111","author":"G Henkelman","year":"1999","unstructured":"Henkelman, G. & J\u00f3nsson, H. A dimer method for finding saddle points on high dimensional potential surfaces using only first derivatives. J. Chem. Phys. 111, 7010\u20137022 (1999).","journal-title":"J. Chem. Phys."}],"container-title":["Nature Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/s41467-024-52482-4.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41467-024-52482-4","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41467-024-52482-4.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,9,14]],"date-time":"2024-09-14T14:03:52Z","timestamp":1726322632000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/s41467-024-52482-4"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,9,14]]},"references-count":72,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2024,12]]}},"alternative-id":["52482"],"URL":"https:\/\/doi.org\/10.1038\/s41467-024-52482-4","relation":{},"ISSN":["2041-1723"],"issn-type":[{"value":"2041-1723","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,9,14]]},"assertion":[{"value":"4 November 2022","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"9 September 2024","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"14 September 2024","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"The authors declare no competing interest.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}],"article-number":"8064"}}