{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T02:27:49Z","timestamp":1792549669881,"version":"4.5.0"},"reference-count":58,"publisher":"Springer Science and Business Media LLC","issue":"1","license":[{"start":{"date-parts":[[2024,11,12]],"date-time":"2024-11-12T00:00:00Z","timestamp":1731369600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0"},{"start":{"date-parts":[[2024,11,12]],"date-time":"2024-11-12T00:00:00Z","timestamp":1731369600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0"}],"funder":[{"DOI":"10.13039\/501100001843","name":"DST | Science and Engineering Research Board","doi-asserted-by":"publisher","award":["CRG\/2022\/003553"],"award-info":[{"award-number":["CRG\/2022\/003553"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Nat Commun"],"DOI":"10.1038\/s41467-024-54101-8","type":"journal-article","created":{"date-parts":[[2024,11,12]],"date-time":"2024-11-12T09:18:33Z","timestamp":1731403113000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":35,"title":["Tailored pore-confined single-site iron(III) catalyst for selective CH4 oxidation to CH3OH or CH3CO2H using O2"],"prefix":"10.1038","volume":"15","author":[{"given":"Manav","family":"Chauhan","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bharti","family":"Rana","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Poorvi","family":"Gupta","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rahul","family":"Kalita","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chhaya","family":"Thadhani","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2924-0353","authenticated-orcid":false,"given":"Kuntal","family":"Manna","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2024,11,12]]},"reference":[{"key":"54101_CR1","doi-asserted-by":"publisher","first-page":"582","DOI":"10.1038\/s41560-022-01060-3","volume":"7","author":"C Kemfert","year":"2022","unstructured":"Kemfert, C., Pr\u00e4ger, F., Braunger, I., Hoffart, F. M. & Brauers, H. The expansion of natural gas infrastructure puts energy transitions at risk. Nat. Energy 7, 582\u2013587 (2022).","journal-title":"Nat. Energy"},{"key":"54101_CR2","doi-asserted-by":"publisher","first-page":"16567","DOI":"10.1021\/acs.est.2c02136","volume":"56","author":"BM Erland","year":"2022","unstructured":"Erland, B. M., Thorpe, A. K. & Gamon, J. A. Recent advances toward transparent methane emissions monitoring: a review. Environ. Sci. Technol. 56, 16567\u201316581 (2022).","journal-title":"Environ. Sci. Technol."},{"key":"54101_CR3","doi-asserted-by":"publisher","first-page":"1755","DOI":"10.1016\/j.chempr.2021.02.002","volume":"7","author":"X Li","year":"2021","unstructured":"Li, X., Pei, C. & Gong, J. Shale gas revolution: catalytic conversion of C1\u2013C3 light alkanes to value-added chemicals. Chem 7, 1755\u20131801 (2021).","journal-title":"Chem"},{"key":"54101_CR4","doi-asserted-by":"publisher","first-page":"6359","DOI":"10.1021\/acs.chemrev.2c00439","volume":"123","author":"NF Dummer","year":"2023","unstructured":"Dummer, N. F. et al. Methane oxidation to methanol. Chem. Rev. 123, 6359\u20136411 (2023).","journal-title":"Chem. Rev."},{"key":"54101_CR5","doi-asserted-by":"publisher","first-page":"293","DOI":"10.1016\/S0920-5861(00)00263-7","volume":"58","author":"GJ Sunley","year":"2000","unstructured":"Sunley, G. J. & Watson, D. J. High productivity methanol carbonylation catalysis using iridium: the Cativa\u2122 process for the manufacture of acetic acid. Catal. Today 58, 293\u2013307 (2000).","journal-title":"Catal. Today"},{"key":"54101_CR6","doi-asserted-by":"publisher","first-page":"10096","DOI":"10.1002\/anie.201006424","volume":"50","author":"H Schwarz","year":"2011","unstructured":"Schwarz, H. Chemistry with methane: concepts rather than recipes. Angew. Chem. Int. Ed. 50, 10096\u201310115 (2011).","journal-title":"Angew. Chem. Int. Ed."},{"key":"54101_CR7","doi-asserted-by":"publisher","first-page":"1394","DOI":"10.1021\/ja047158u","volume":"127","author":"MH Groothaert","year":"2005","unstructured":"Groothaert, M. H., Smeets, P. J., Sels, B. F., Jacobs, P. A. & Schoonheydt, R. A. Selective oxidation of methane by the bis(\u03bc-oxo)dicopper core stabilized on ZSM-5 and mordenite zeolites. J. Am. Chem. Soc. 127, 1394\u20131395 (2005).","journal-title":"J. Am. Chem. Soc."},{"key":"54101_CR8","doi-asserted-by":"publisher","first-page":"11053","DOI":"10.1039\/C4CC02832E","volume":"50","author":"T Sheppard","year":"2014","unstructured":"Sheppard, T., Hamill, C. D., Goguet, A., Rooney, D. W. & Thompson, J. M. A low temperature, isothermal gas-phase system for conversion of methane to methanol over Cu\u2013ZSM-5. Chem. Commun. 50, 11053\u201311055 (2014).","journal-title":"Chem. Commun."},{"key":"54101_CR9","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms8546","volume":"6","author":"S Grundner","year":"2015","unstructured":"Grundner, S. et al. Single-site trinuclear copper oxygen clusters in mordenite for selective conversion of methane to methanol. Nat. Commun. 6, 7546 (2015).","journal-title":"Nat. Commun."},{"key":"54101_CR10","doi-asserted-by":"publisher","first-page":"5129","DOI":"10.1002\/anie.201108706","volume":"51","author":"C Hammond","year":"2012","unstructured":"Hammond, C. et al. Direct catalytic conversion of methane to methanol in an aqueous medium by using copper-promoted Fe-ZSM-5. Angew. Chem. Int. Ed. 51, 5129\u20135133 (2012).","journal-title":"Angew. Chem. Int. Ed."},{"key":"54101_CR11","doi-asserted-by":"publisher","first-page":"1835","DOI":"10.1021\/cs400288b","volume":"3","author":"C Hammond","year":"2013","unstructured":"Hammond, C. et al. Aqueous-phase methane oxidation over Fe-MFI zeolites; promotion through isomorphous framework substitution. ACS Catal. 3, 1835\u20131844 (2013).","journal-title":"ACS Catal."},{"key":"54101_CR12","doi-asserted-by":"publisher","first-page":"9292","DOI":"10.1021\/jacs.9b02902","volume":"141","author":"J Zheng","year":"2019","unstructured":"Zheng, J. et al. Selective methane oxidation to methanol on Cu-oxo dimers stabilized by zirconia nodes of an NU-1000 metal\u2013organic framework. J. Am. Chem. Soc. 141, 9292\u20139304 (2019).","journal-title":"J. Am. Chem. Soc."},{"key":"54101_CR13","doi-asserted-by":"publisher","first-page":"1557","DOI":"10.1016\/j.chempr.2021.02.026","volume":"7","author":"L Sun","year":"2021","unstructured":"Sun, L. et al. Water-involved methane-selective catalytic oxidation by dioxygen over copper zeolites. Chem 7, 1557\u20131568 (2021).","journal-title":"Chem"},{"key":"54101_CR14","doi-asserted-by":"publisher","first-page":"45","DOI":"10.1038\/s41929-021-00725-8","volume":"5","author":"G Qi","year":"2022","unstructured":"Qi, G. et al. Au-ZSM-5 catalyses the selective oxidation of CH4 to CH3OH and CH3COOH using O2. Nat. Catal. 5, 45\u201354 (2022).","journal-title":"Nat. Catal."},{"key":"54101_CR15","doi-asserted-by":"publisher","first-page":"7199","DOI":"10.1021\/acscatal.3c01226","volume":"13","author":"J Cao","year":"2023","unstructured":"Cao, J. et al. Methane conversion to methanol using Au\/ZSM-5 is promoted by carbon. ACS Catal. 13, 7199\u20137209 (2023).","journal-title":"ACS Catal."},{"key":"54101_CR16","doi-asserted-by":"publisher","first-page":"20507","DOI":"10.1021\/jacs.9b11440","volume":"141","author":"H Song","year":"2019","unstructured":"Song, H. et al. Direct and selective photocatalytic oxidation of CH4 to oxygenates with O2 on cocatalysts\/ZnO at room temperature in water. J. Am. Chem. Soc. 141, 20507\u201320515 (2019).","journal-title":"J. Am. Chem. Soc."},{"key":"54101_CR17","doi-asserted-by":"publisher","first-page":"10796","DOI":"10.1039\/D1TA00420D","volume":"9","author":"X Cai","year":"2021","unstructured":"Cai, X., Fang, S. & Hu, Y. H. Unprecedentedly high efficiency for photocatalytic conversion of methane to methanol over Au\u2013Pd\/TiO2 \u2013 what is the role of each component in the system? J. Mater. Chem. A 9, 10796\u201310802 (2021).","journal-title":"J. Mater. Chem. A"},{"key":"54101_CR18","doi-asserted-by":"publisher","first-page":"509","DOI":"10.1038\/s41893-021-00682-x","volume":"4","author":"Y Fan","year":"2021","unstructured":"Fan, Y. et al. Selective photocatalytic oxidation of methane by quantum-sized bismuth vanadate. Nat. Sustain. 4, 509\u2013515 (2021).","journal-title":"Nat. Sustain."},{"key":"54101_CR19","doi-asserted-by":"publisher","first-page":"932","DOI":"10.1038\/s41563-022-01279-1","volume":"21","author":"B An","year":"2022","unstructured":"An, B. et al. Direct photo-oxidation of methane to methanol over a mono-iron hydroxyl site. Nat. Mater. 21, 932\u2013938 (2022).","journal-title":"Nat. Mater."},{"key":"54101_CR20","doi-asserted-by":"publisher","first-page":"1797","DOI":"10.1021\/acscatal.3c05030","volume":"14","author":"J Cao","year":"2024","unstructured":"Cao, J. et al. Partially bonded aluminum site on the external surface of post-treated Au\/ZSM-5 enhances methane oxidation to oxygenates. ACS Catal. 14, 1797\u20131807 (2024).","journal-title":"ACS Catal."},{"key":"54101_CR21","doi-asserted-by":"publisher","first-page":"122983","DOI":"10.1016\/j.apcatb.2023.122983","volume":"337","author":"J Wang","year":"2023","unstructured":"Wang, J. et al. Multi-radicals mediated one-step conversion of methane to acetic acid via photocatalysis. Appl. Catal. B Environ. 337, 122983 (2023).","journal-title":"Appl. Catal. B Environ."},{"key":"54101_CR22","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-38731-y","volume":"14","author":"W Zhang","year":"2023","unstructured":"Zhang, W. et al. Light-driven flow synthesis of acetic acid from methane with chemical looping. Nat. Commun. 14, 3047 (2023).","journal-title":"Nat. Commun."},{"key":"54101_CR23","doi-asserted-by":"publisher","first-page":"276","DOI":"10.1038\/46248","volume":"402","author":"H Li","year":"1999","unstructured":"Li, H., Eddaoudi, M., O\u2019Keeffe, M. & Yaghi, O. M. Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Nature 402, 276\u2013279 (1999).","journal-title":"Nature"},{"key":"54101_CR24","doi-asserted-by":"publisher","first-page":"469","DOI":"10.1126\/science.1067208","volume":"295","author":"M Eddaoudi","year":"2002","unstructured":"Eddaoudi, M. et al. Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage. Science 295, 469\u2013472 (2002).","journal-title":"Science"},{"key":"54101_CR25","doi-asserted-by":"publisher","first-page":"1230444","DOI":"10.1126\/science.1230444","volume":"341","author":"H Furukawa","year":"2013","unstructured":"Furukawa, H., Cordova, K. E., O\u2019Keeffe, M. & Yaghi, O. M. The chemistry and applications of metal-organic frameworks. Science 341, 1230444 (2013).","journal-title":"Science"},{"key":"54101_CR26","doi-asserted-by":"publisher","first-page":"14961","DOI":"10.1021\/jacs.7b06472","volume":"139","author":"DK Pappas","year":"2017","unstructured":"Pappas, D. K. et al. Methane to methanol: structure\u2013activity relationships for Cu-CHA. J. Am. Chem. Soc. 139, 14961\u201314975 (2017).","journal-title":"J. Am. Chem. Soc."},{"key":"54101_CR27","doi-asserted-by":"publisher","first-page":"5542","DOI":"10.1021\/acscatal.8b00505","volume":"8","author":"DY Osadchii","year":"2018","unstructured":"Osadchii, D. Y. et al. Isolated Fe sites in metal organic frameworks catalyze the direct conversion of methane to methanol. ACS Catal. 8, 5542\u20135548 (2018).","journal-title":"ACS Catal."},{"key":"54101_CR28","doi-asserted-by":"publisher","first-page":"356","DOI":"10.1038\/s41929-018-0069-6","volume":"1","author":"X Zhang","year":"2018","unstructured":"Zhang, X. et al. Catalytic chemoselective functionalization of methane in a metal\u2212organic framework. Nat. Catal. 1, 356\u2013362 (2018).","journal-title":"Nat. Catal."},{"key":"54101_CR29","doi-asserted-by":"publisher","first-page":"3576","DOI":"10.1021\/acscatal.8b05178","volume":"9","author":"AS Rosen","year":"2019","unstructured":"Rosen, A. S., Notestein, J. M. & Snurr, R. Q. Structure\u2013activity relationships that identify metal\u2013organic framework catalysts for methane activation. ACS Catal. 9, 3576\u20133587 (2019).","journal-title":"ACS Catal."},{"key":"54101_CR30","doi-asserted-by":"publisher","first-page":"11196","DOI":"10.1021\/jacs.9b04285","volume":"141","author":"X Feng","year":"2019","unstructured":"Feng, X. et al. Metal\u2013organic framework stabilizes a low-coordinate iridium complex for catalytic methane borylation. J. Am. Chem. Soc. 141, 11196\u201311203 (2019).","journal-title":"J. Am. Chem. Soc."},{"key":"54101_CR31","doi-asserted-by":"publisher","first-page":"28217","DOI":"10.1021\/acsami.0c06241","volume":"12","author":"M Barona","year":"2020","unstructured":"Barona, M. & Snurr, R. Q. Exploring the tunability of trimetallic MOF nodes for partial oxidation of methane to methanol. ACS Appl. Mater. Interfaces 12, 28217\u201328231 (2020).","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"54101_CR32","doi-asserted-by":"publisher","first-page":"5811","DOI":"10.1002\/anie.202013807","volume":"60","author":"W Zhao","year":"2021","unstructured":"Zhao, W. et al. Fe-O clusters anchored on nodes of metal\u2013organic frameworks for direct methane oxidation. Angew. Chem. Int. Ed. 60, 5811\u20135815 (2021).","journal-title":"Angew. Chem. Int. Ed."},{"key":"54101_CR33","doi-asserted-by":"publisher","first-page":"11159","DOI":"10.1021\/acscatal.2c02823","volume":"12","author":"N Antil","year":"2022","unstructured":"Antil, N. et al. Metal\u2013organic framework-encaged monomeric Cobalt(III) hydroperoxides enable chemoselective methane oxidation to methanol. ACS Catal. 12, 11159\u201311168 (2022).","journal-title":"ACS Catal."},{"key":"54101_CR34","doi-asserted-by":"publisher","first-page":"6156","DOI":"10.1021\/jacs.2c12042","volume":"145","author":"N Antil","year":"2023","unstructured":"Antil, N., Chauhan, M., Akhtar, N., Kalita, R. & Manna, K. Selective methane oxidation to acetic acid using molecular oxygen over a mono-copper hydroxyl catalyst. J. Am. Chem. Soc. 145, 6156\u20136165 (2023).","journal-title":"J. Am. Chem. Soc."},{"key":"54101_CR35","doi-asserted-by":"publisher","first-page":"10427","DOI":"10.1021\/acscatal.4c02883","volume":"14","author":"W Begum","year":"2024","unstructured":"Begum, W. et al. Synergetic Ni\u2013Ce active sites in mixed Cerium\/Zirconium metal\u2013organic framework nodes for selective methane oxidation into ethanol. ACS Catal. 14, 10427\u201310436 (2024).","journal-title":"ACS Catal."},{"key":"54101_CR36","doi-asserted-by":"publisher","first-page":"6504","DOI":"10.1039\/D4CC01568A","volume":"60","author":"R Kalita","year":"2024","unstructured":"Kalita, R. et al. Selective monoborylation of methane by metal\u2013organic framework confined mononuclear pyridylimine-iridium(i) hydride. Chem. Commun. 60, 6504\u20136507 (2024).","journal-title":"Chem. Commun."},{"key":"54101_CR37","doi-asserted-by":"publisher","first-page":"1450","DOI":"10.1039\/b807080f","volume":"38","author":"J Lee","year":"2009","unstructured":"Lee, J. et al. Metal\u2013organic framework materials as catalysts. Chem. Soc. Rev. 38, 1450\u20131459 (2009).","journal-title":"Chem. Soc. Rev."},{"key":"54101_CR38","doi-asserted-by":"publisher","first-page":"970","DOI":"10.1021\/cr200179u","volume":"112","author":"SM Cohen","year":"2012","unstructured":"Cohen, S. M. Postsynthetic methods for the functionalization of metal\u2013organic frameworks. Chem. Rev. 112, 970\u20131000 (2012).","journal-title":"Chem. Rev."},{"key":"54101_CR39","doi-asserted-by":"publisher","first-page":"2573","DOI":"10.1021\/acs.chemmater.5b04575","volume":"28","author":"C Kutzscher","year":"2016","unstructured":"Kutzscher, C. et al. Proline functionalized UiO-67 and UiO-68 Type metal\u2013organic frameworks showing reversed diastereoselectivity in aldol addition reactions. Chem. Mater. 28, 2573\u20132580 (2016).","journal-title":"Chem. Mater."},{"key":"54101_CR40","doi-asserted-by":"publisher","first-page":"2327","DOI":"10.1039\/C5CS00837A","volume":"45","author":"Y Bai","year":"2016","unstructured":"Bai, Y. et al. Zr-based metal\u2013organic frameworks: design, synthesis, structure, and applications. Chem. Soc. Rev. 45, 2327\u20132367 (2016).","journal-title":"Chem. Soc. Rev."},{"key":"54101_CR41","doi-asserted-by":"publisher","first-page":"1046","DOI":"10.1021\/acscentsci.0c00690","volume":"6","author":"M Kalaj","year":"2020","unstructured":"Kalaj, M. & Cohen, S. M. Postsynthetic modification: an enabling technology for the advancement of metal\u2013organic frameworks. ACS Cent. Sci. 6, 1046\u20131057 (2020).","journal-title":"ACS Cent. Sci."},{"key":"54101_CR42","doi-asserted-by":"publisher","first-page":"30320","DOI":"10.1021\/acsami.3c05397","volume":"15","author":"D Bai","year":"2023","unstructured":"Bai, D. et al. Mesoporous mixed-metal\u2013organic framework incorporating a [Ru(Phen)3]2+ photosensitizer for highly efficient aerobic photocatalytic oxidative coupling of amines. ACS Appl. Mater. Interfaces 15, 30320\u201330331 (2023).","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"54101_CR43","doi-asserted-by":"publisher","first-page":"6491","DOI":"10.1021\/ja00359a023","volume":"105","author":"PL Watson","year":"1983","unstructured":"Watson, P. L. Methane exchange reactions of lanthanide and early-transition-metal methyl complexes. J. Am. Chem. Soc. 105, 6491\u20136493 (1983).","journal-title":"J. Am. Chem. Soc."},{"key":"54101_CR44","doi-asserted-by":"publisher","first-page":"3356","DOI":"10.1039\/c2sc20530k","volume":"3","author":"VN Cavaliere","year":"2012","unstructured":"Cavaliere, V. N. & Mindiola, D. J. Methane: a new frontier in organometallic chemistry. Chem. Sci. 3, 3356\u20133365 (2012).","journal-title":"Chem. Sci."},{"key":"54101_CR45","doi-asserted-by":"publisher","first-page":"93","DOI":"10.1016\/j.micromeso.2009.02.020","volume":"122","author":"I Senkovska","year":"2009","unstructured":"Senkovska, I. et al. New highly porous aluminium based metal-organic frameworks: Al(OH)(ndc) (ndc=2,6-naphthalene dicarboxylate) and Al(OH)(bpdc) (bpdc=4,4\u2032-biphenyl dicarboxylate). Microporous Mesoporous Mater. 122, 93\u201398 (2009).","journal-title":"Microporous Mesoporous Mater."},{"key":"54101_CR46","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms12610","volume":"7","author":"K Manna","year":"2016","unstructured":"Manna, K. et al. Chemoselective single-site Earth-abundant metal catalysts at metal\u2013organic framework nodes. Nat. Commun. 7, 12610 (2016).","journal-title":"Nat. Commun."},{"key":"54101_CR47","doi-asserted-by":"publisher","first-page":"889","DOI":"10.1038\/s41929-018-0170-x","volume":"1","author":"J Xie","year":"2018","unstructured":"Xie, J. et al. Highly selective oxidation of methane to methanol at ambient conditions by titanium dioxide-supported iron species. Nat. Catal. 1, 889\u2013896 (2018).","journal-title":"Nat. Catal."},{"key":"54101_CR48","doi-asserted-by":"crossref","unstructured":"Hagen, W. R. EPR spectroscopy as a probe of metal centres in biological systems. Dalton Trans. 4415\u20134434 (2006).","DOI":"10.1039\/b608163k"},{"key":"54101_CR49","doi-asserted-by":"publisher","first-page":"2581","DOI":"10.1002\/er.5948","volume":"45","author":"L Zhang","year":"2021","unstructured":"Zhang, L. et al. Direct conversion of methane to oxygenates catalyzed by iron(III) chloride in water at near ambient temperature. Int. J. Energy Res. 45, 2581\u20132592 (2021).","journal-title":"Int. J. Energy Res."},{"key":"54101_CR50","doi-asserted-by":"publisher","first-page":"3420","DOI":"10.1021\/ja00743a020","volume":"93","author":"GA Hamilton","year":"1971","unstructured":"Hamilton, G. A. & Adolf, P. K. Oxidation by molecular oxygen. VI. Iron(III)-catalyzed oxidation of acetoin by oxygen and hydrogen peroxide. Model for some enzymic redox reactions. J. Am. Chem. Soc. 93, 3420\u20133427 (1971).","journal-title":"J. Am. Chem. Soc."},{"key":"54101_CR51","doi-asserted-by":"crossref","unstructured":"Annaraj, J. et al. Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation. Chem. Commun. 4529\u20134531 (2005).","DOI":"10.1039\/b505562h"},{"key":"54101_CR52","doi-asserted-by":"publisher","first-page":"502","DOI":"10.1038\/nature10535","volume":"478","author":"J Cho","year":"2011","unstructured":"Cho, J. et al. Structure and reactivity of a mononuclear non-haem iron(III)\u2013peroxo complex. Nature 478, 502\u2013505 (2011).","journal-title":"Nature"},{"key":"54101_CR53","doi-asserted-by":"publisher","first-page":"18121","DOI":"10.1021\/jacs.1c06911","volume":"143","author":"KA Jesse","year":"2021","unstructured":"Jesse, K. A. et al. Direct aerobic generation of a ferric hydroperoxo intermediate via a preorganized secondary coordination sphere. J. Am. Chem. Soc. 143, 18121\u201318130 (2021).","journal-title":"J. Am. Chem. Soc."},{"key":"54101_CR54","doi-asserted-by":"publisher","first-page":"3384","DOI":"10.1021\/acscatal.0c05492","volume":"11","author":"C Tu","year":"2021","unstructured":"Tu, C. et al. Insight into acetic acid synthesis from the reaction of CH4 and CO2. ACS Catal. 11, 3384\u20133401 (2021).","journal-title":"ACS Catal."},{"key":"54101_CR55","doi-asserted-by":"publisher","first-page":"52979","DOI":"10.1021\/acsami.2c16323","volume":"14","author":"K Yang","year":"2022","unstructured":"Yang, K. & Jiang, J. Rational design of metal-alkoxide-functionalized metal\u2013organic frameworks for synergistic dual activation of CH4 and CO2 toward acetic acid synthesis. ACS Appl. Mater. Interfaces 14, 52979\u201352992 (2022).","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"54101_CR56","doi-asserted-by":"publisher","first-page":"150690","DOI":"10.1016\/j.cej.2024.150690","volume":"487","author":"N Liu","year":"2024","unstructured":"Liu, N. et al. Photocatalytic conversion of CH4 and CO2 to acetic acid over Cu\/ZnO catalysts under mild conditions. Chem. Eng. J. 487, 150690 (2024).","journal-title":"Chem. Eng. J."},{"key":"54101_CR57","doi-asserted-by":"publisher","first-page":"649","DOI":"10.1021\/ol9025414","volume":"12","author":"C He","year":"2010","unstructured":"He, C. et al. A mild hydrothermal route to fix carbon dioxide to simple carboxylic acids. Org. Lett. 12, 649\u2013651 (2010).","journal-title":"Org. Lett."},{"key":"54101_CR58","doi-asserted-by":"publisher","first-page":"6613","DOI":"10.1039\/C9CY01803D","volume":"9","author":"S Wang","year":"2019","unstructured":"Wang, S. et al. Direct synthesis of acetic acid from carbon dioxide and methane over Cu-modulated BEA, MFI, MOR and TON zeolites: a density functional theory study. Catal. Sci. Technol. 9, 6613\u20136626 (2019).","journal-title":"Catal. Sci. Technol."}],"container-title":["Nature Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/s41467-024-54101-8.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41467-024-54101-8","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41467-024-54101-8.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,11,12]],"date-time":"2024-11-12T11:01:58Z","timestamp":1731409318000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/s41467-024-54101-8"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,12]]},"references-count":58,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2024,12]]}},"alternative-id":["54101"],"URL":"https:\/\/doi.org\/10.1038\/s41467-024-54101-8","relation":{},"ISSN":["2041-1723"],"issn-type":[{"value":"2041-1723","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,11,12]]},"assertion":[{"value":"7 July 2024","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"30 October 2024","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"12 November 2024","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"The authors declare no competing interests.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}],"article-number":"9798"}}