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Halide solid electrolytes are valued for their high ionic conductivity, oxidative stability, and ductility. Among them, Li\n                    <jats:sub>2<\/jats:sub>\n                    ZrCl\n                    <jats:sub>6<\/jats:sub>\n                    is cost-effective but has a relatively lower Li\u207a ionic conductivity (0.4 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 25 \u00b0C) compared to other halides, such as Li\n                    <jats:sub>3<\/jats:sub>\n                    InCl\n                    <jats:sub>6<\/jats:sub>\n                    (&gt; 1 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 25 \u00b0C). Here, we elucidate a fundamental mechanism of divalent-anion-driven framework modification that enables enhanced ionic conduction in Zr-based halides. Specifically, we demonstrate enhanced Li\n                    <jats:sup>+<\/jats:sup>\n                    conductivities for oxygen- (0.8Li\n                    <jats:sub>2<\/jats:sub>\n                    O\u2013ZrCl\n                    <jats:sub>4<\/jats:sub>\n                    : 1.78 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 25 \u00b0C) and sulfur- (0.8Li\n                    <jats:sub>2<\/jats:sub>\n                    S\u2013ZrCl\n                    <jats:sub>4<\/jats:sub>\n                    : 1.01 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 25 \u00b0C) substituted lattices. Synchrotron-based X-ray analyses identify distinct anionic sublattices and first-principles calculations reveal that divalent anions locally cluster within the lattice, inducing structural distortion and Li-site destabilization. These changes widen lithium conduction channels and alter the bonding environment, weakening and diversifying Li\u2013Cl interactions. As a result, the energy landscape for lithium migration is flattened, leading to improved ionic conduction. These findings highlight design strategies for divalent-anion-driven framework regulation in halide solid electrolytes.\n                  <\/jats:p>","DOI":"10.1038\/s41467-025-65702-2","type":"journal-article","created":{"date-parts":[[2025,11,27]],"date-time":"2025-11-27T14:20:02Z","timestamp":1764253202000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Divalent anion-driven framework regulation in Zr-based halide solid electrolytes for all-solid-state batteries"],"prefix":"10.1038","volume":"16","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3052-6444","authenticated-orcid":false,"given":"Jae-Seung","family":"Kim","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daseul","family":"Han","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinyeong","family":"Choe","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Youngkyung","family":"Kim","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hae-Yong","family":"Kim","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-6072-695X","authenticated-orcid":false,"given":"Soeul","family":"Lee","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0085-9774","authenticated-orcid":false,"given":"Jiwon","family":"Seo","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Seung-Hui","family":"Ham","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"You-Yeob","family":"Song","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chang-Dae","family":"Lee","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juho","family":"Lee","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-1624-0388","authenticated-orcid":false,"given":"Hiram","family":"Kwak","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8217-5071","authenticated-orcid":false,"given":"Jinsoo","family":"Kim","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0357-9508","authenticated-orcid":false,"given":"Yoon Seok","family":"Jung","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3708-3757","authenticated-orcid":false,"given":"Sung-Kyun","family":"Jung","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6278-6369","authenticated-orcid":false,"given":"Kyung-Wan","family":"Nam","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7200-7186","authenticated-orcid":false,"given":"Dong-Hwa","family":"Seo","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2025,11,27]]},"reference":[{"key":"65702_CR1","doi-asserted-by":"publisher","first-page":"587","DOI":"10.1021\/cm901452z","volume":"22","author":"JB Goodenough","year":"2010","unstructured":"Goodenough, J. 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