{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T00:19:28Z","timestamp":1790381968879,"version":"4.1.0"},"reference-count":146,"publisher":"Springer Science and Business Media LLC","issue":"1","license":[{"start":{"date-parts":[[2026,2,17]],"date-time":"2026-02-17T00:00:00Z","timestamp":1771286400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0"},{"start":{"date-parts":[[2026,3,26]],"date-time":"2026-03-26T00:00:00Z","timestamp":1774483200000},"content-version":"vor","delay-in-days":37,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0"}],"funder":[{"DOI":"10.13039\/501100000038","name":"Gouvernement du Canada | Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","award":["Discovery RGPIN\/6762-2024"],"award-info":[{"award-number":["Discovery RGPIN\/6762-2024"]}],"id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000038","name":"Gouvernement du Canada | Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","award":["PGS-D"],"award-info":[{"award-number":["PGS-D"]}],"id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Nat Commun"],"DOI":"10.1038\/s41467-026-69445-6","type":"journal-article","created":{"date-parts":[[2026,2,16]],"date-time":"2026-02-16T23:36:07Z","timestamp":1771284967000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Strategies to control the geometry and symmetry around lanthanide centres for tailored luminescence and magnetism"],"prefix":"10.1038","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7307-3222","authenticated-orcid":false,"given":"Thomas E.","family":"Karpiuk","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3426-2848","authenticated-orcid":false,"given":"Daniel B.","family":"Leznoff","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2026,2,17]]},"reference":[{"key":"69445_CR1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-024-62074-3","volume":"14","author":"S Li","year":"2024","unstructured":"Li, S., Jansone-Popova, S. & Jiang, D. Insights into coordination and ligand trends of lanthanide complexes from the Cambridge Structural Database. Sci. Rep. 14, 11301 (2024).","journal-title":"Sci. Rep."},{"key":"69445_CR2","doi-asserted-by":"publisher","first-page":"350","DOI":"10.1016\/j.ccr.2017.10.030","volume":"378","author":"Z Zhu","year":"2019","unstructured":"Zhu, Z., Guo, M., Li, X.-L. & Tang, J. Molecular magnetism of lanthanide: advances and perspectives. Coord. Chem. Rev. 378, 350\u2013364 (2019).","journal-title":"Coord. Chem. Rev."},{"key":"69445_CR3","doi-asserted-by":"publisher","first-page":"5058","DOI":"10.1002\/ejic.201701201","volume":"2017","author":"J-CG B\u00fcnzli","year":"2017","unstructured":"B\u00fcnzli, J.-C. G. Rising stars in science and technology: luminescent lanthanide materials. Eur. J. Inorg. Chem. 2017, 5058\u20135063 (2017).","journal-title":"Eur. J. Inorg. Chem."},{"key":"69445_CR4","doi-asserted-by":"publisher","first-page":"5110","DOI":"10.1021\/cr400018q","volume":"113","author":"DN Woodruff","year":"2013","unstructured":"Woodruff, D. N., Winpenny, R. E. P. & Layfield, R. A. Lanthanide single-molecule magnets. Chem. Rev. 113, 5110\u20135148 (2013).","journal-title":"Chem. Rev."},{"key":"69445_CR5","doi-asserted-by":"publisher","first-page":"3914","DOI":"10.1039\/D4CC00468J","volume":"60","author":"TE Karpiuk","year":"2024","unstructured":"Karpiuk, T. E., Mahato, S., Storr, T. & Leznoff, D. B. Unusually short unsupported Au(III)\u22efAu(III) aurophilic contacts in emissive lanthanide tetracyanoaurate(III) complexes. Chem. Commun. 60, 3914\u20133917 (2024).","journal-title":"Chem. Commun."},{"key":"69445_CR6","doi-asserted-by":"publisher","first-page":"10079","DOI":"10.1039\/D4DT00157E","volume":"53","author":"SS Mortensen","year":"2024","unstructured":"Mortensen, S. S., Nielsen, V. R. M. & S\u00f8rensen, T. J. Contrasting impact of coordination polyhedra and site symmetry on the electronic energy levels in nine-coordinated Eu(III) and Sm(III) crystals structures determined from single crystal luminescence spectra. Dalton Trans. 53, 10079\u201310092 (2024).","journal-title":"Dalton Trans."},{"key":"69445_CR7","doi-asserted-by":"publisher","first-page":"213153","DOI":"10.1016\/j.ccr.2019.213153","volume":"406","author":"PP Ferreira da Rosa","year":"2020","unstructured":"Ferreira da Rosa, P. P., Kitagawa, Y. & Hasegawa, Y. Luminescent lanthanide complex with seven-coordination geometry. Coord. Chem. Rev. 406, 213153 (2020).","journal-title":"Coord. Chem. Rev."},{"key":"69445_CR8","doi-asserted-by":"publisher","first-page":"9166","DOI":"10.1021\/acs.inorgchem.5b01580","volume":"54","author":"NM Shavaleev","year":"2015","unstructured":"Shavaleev, N. M., Eliseeva, S. V., Scopelliti, R. & B\u00fcnzli, J.-C. G. Influence of symmetry on the luminescence and radiative lifetime of nine-coordinate europium complexes. Inorg. Chem. 54, 9166\u20139173 (2015).","journal-title":"Inorg. Chem."},{"key":"69445_CR9","doi-asserted-by":"publisher","first-page":"5911","DOI":"10.1002\/ejic.201301102","volume":"2013","author":"Y Hasegawa","year":"2013","unstructured":"Hasegawa, Y. et al. Effect of ligand polarization on asymmetric structural formation for strongly luminescent lanthanide complexes. Eur. J. Inorg. Chem. 2013, 5911\u20135918 (2013).","journal-title":"Eur. J. Inorg. Chem."},{"key":"69445_CR10","doi-asserted-by":"publisher","DOI":"10.1038\/srep02395","volume":"3","author":"NBD Lima","year":"2013","unstructured":"Lima, N. B. D., Gon\u00e7alves, S. M. C., J\u00fanior, S. A. & Simas, A. M. A Comprehensive strategy to boost the quantum yield of luminescence of europium complexes. Sci. Rep. 3, 2395 (2013).","journal-title":"Sci. Rep."},{"key":"69445_CR11","doi-asserted-by":"publisher","first-page":"521","DOI":"10.1002\/chem.201001993","volume":"17","author":"K Miyata","year":"2011","unstructured":"Miyata, K. et al. Remarkable luminescence properties of lanthanide complexes with asymmetric dodecahedron structures. Chem. Eur. J. 17, 521\u2013528 (2011).","journal-title":"Chem. Eur. J."},{"key":"69445_CR12","doi-asserted-by":"publisher","first-page":"3029","DOI":"10.1021\/jp067672h","volume":"111","author":"K Nakamura","year":"2007","unstructured":"Nakamura, K. et al. Enhanced lasing properties of dissymmetric Eu(III) complex with bidentate phosphine ligands. J. Phys. Chem. A 111, 3029\u20133037 (2007).","journal-title":"J. Phys. Chem. A"},{"key":"69445_CR13","doi-asserted-by":"publisher","first-page":"29","DOI":"10.1016\/S0022-2313(98)00018-0","volume":"79","author":"M Iwamuro","year":"1998","unstructured":"Iwamuro, M. et al. Luminescence of Nd3+ complexes with some asymmetric ligands in organic solutions. J. Lumin. 79, 29\u201338 (1998).","journal-title":"J. Lumin."},{"key":"69445_CR14","doi-asserted-by":"publisher","first-page":"1405","DOI":"10.1364\/JOSA.66.001405","volume":"66","author":"PP Yaney","year":"1976","unstructured":"Yaney, P. P. & DeShazer, L. G. Spectroscopic studies and analysis of the laser states of Nd3+ in YVO4. J. Opt. Soc. Am. 66, 1405\u20131414 (1976).","journal-title":"J. Opt. Soc. Am."},{"key":"69445_CR15","doi-asserted-by":"publisher","first-page":"13770","DOI":"10.1039\/C9TC04521J","volume":"7","author":"D Avram","year":"2019","unstructured":"Avram, D., Colbea, C. & Tiseanu, C. Effects of local symmetry on upconversion emission mechanisms under pulsed excitation. J. Mater. Chem. C\u00a07, 13770\u201313777 (2019).","journal-title":"J. Mater. Chem. C"},{"key":"69445_CR16","doi-asserted-by":"publisher","first-page":"1523","DOI":"10.1021\/acsphotonics.6b00166","volume":"3","author":"MD Wisser","year":"2016","unstructured":"Wisser, M. D. et al. Enhancing quantum yield via local symmetry distortion in lanthanide-based upconverting nanoparticles. ACS Photonics 3, 1523\u20131530 (2016).","journal-title":"ACS Photonics"},{"key":"69445_CR17","doi-asserted-by":"publisher","first-page":"8084","DOI":"10.1039\/c3nr01916k","volume":"5","author":"C Zhao","year":"2013","unstructured":"Zhao, C. et al. Li+ ion doping: an approach for improving the crystallinity and upconversion emissions of NaYF4:Yb3+, Tm3+ nanoparticles. Nanoscale 5, 8084\u20138089 (2013).","journal-title":"Nanoscale"},{"key":"69445_CR18","doi-asserted-by":"publisher","first-page":"213984","DOI":"10.1016\/j.ccr.2021.213984","volume":"441","author":"A Zabala-Lekuona","year":"2021","unstructured":"Zabala-Lekuona, A., Seco, J. M. & Colacio, E. Single-molecule magnets: from Mn12-ac to dysprosium metallocenes, a travel in time. Coord. Chem. Rev. 441, 213984 (2021).","journal-title":"Coord. Chem. Rev."},{"key":"69445_CR19","doi-asserted-by":"publisher","first-page":"2431","DOI":"10.1039\/C7CS00266A","volume":"47","author":"J-L Liu","year":"2018","unstructured":"Liu, J.-L., Chen, Y.-C. & Tong, M.-L. Symmetry strategies for high performance lanthanide-based single-molecule magnets. Chem. Soc. Rev. 47, 2431\u20132453 (2018).","journal-title":"Chem. Soc. Rev."},{"key":"69445_CR20","doi-asserted-by":"publisher","first-page":"15377","DOI":"10.1002\/chem.201703014","volume":"23","author":"K Katoh","year":"2017","unstructured":"Katoh, K., Aizawa, Y., Morita, T., Breedlove, B. K. & Yamashita, M. Elucidation of dual magnetic relaxation processes in dinuclear dysprosium(iii) phthalocyaninato triple-decker single-molecule magnets depending on the octacoordination geometry. Chem. Eur. J. 23, 15377\u201315386 (2017).","journal-title":"Chem. Eur. J."},{"key":"69445_CR21","doi-asserted-by":"publisher","first-page":"16071","DOI":"10.1002\/anie.201609685","volume":"55","author":"Y-S Ding","year":"2016","unstructured":"Ding, Y.-S., Chilton, N. F., Winpenny, R. E. P. & Zheng, Y.-Z. On Approaching the limit of molecular magnetic anisotropy: a near-perfect pentagonal bipyramidal dysprosium(iii) single-molecule magnet. Angew. Chem. Int. Ed. 55, 16071\u201316074 (2016).","journal-title":"Angew. Chem. Int. Ed."},{"key":"69445_CR22","doi-asserted-by":"publisher","first-page":"2078","DOI":"10.1039\/c1sc00513h","volume":"2","author":"JD Rinehart","year":"2011","unstructured":"Rinehart, J. D. & Long, J. R. Exploiting single-ion anisotropy in the design of f-element single-molecule magnets. Chem. Sci. 2, 2078\u20132085 (2011).","journal-title":"Chem. Sci."},{"key":"69445_CR23","doi-asserted-by":"publisher","first-page":"8874","DOI":"10.1021\/ja801659m","volume":"130","author":"MA AlDamen","year":"2008","unstructured":"AlDamen, M. A., Clemente-Juan, J. M., Coronado, E., Mart\u00ed-Gastaldo, C. & Gaita-Ari\u00f1o, A. Mononuclear Lanthanide Single-Molecule Magnets Based on Polyoxometalates. J. Am. Chem. Soc. 130, 8874\u20138875 (2008).","journal-title":"J. Am. Chem. Soc."},{"key":"69445_CR24","doi-asserted-by":"publisher","first-page":"8694","DOI":"10.1021\/ja029629n","volume":"125","author":"N Ishikawa","year":"2003","unstructured":"Ishikawa, N., Sugita, M., Ishikawa, T., Koshihara, S. & Kaizu, Y. Lanthanide double-decker complexes functioning as magnets at the single-molecular level. J. Am. Chem. Soc. 125, 8694\u20138695 (2003).","journal-title":"J. Am. Chem. Soc."},{"key":"69445_CR25","doi-asserted-by":"publisher","first-page":"1520","DOI":"10.1021\/acs.accounts.0c00275","volume":"53","author":"D Parker","year":"2020","unstructured":"Parker, D., Suturina, E. A., Kuprov, I. & Chilton, N. F. How the ligand field in lanthanide coordination complexes determines magnetic susceptibility anisotropy, paramagnetic NMR shift, and relaxation behavior. Acc. Chem. Res. 53, 1520\u20131534 (2020).","journal-title":"Acc. Chem. Res."},{"key":"69445_CR26","doi-asserted-by":"publisher","first-page":"12506","DOI":"10.1021\/acs.inorgchem.9b01799","volume":"58","author":"L Dai","year":"2019","unstructured":"Dai, L. et al. Synthesis of water-soluble chiral DOTA lanthanide complexes with predominantly twisted square antiprism isomers and circularly polarized luminescence. Inorg. Chem. 58, 12506\u201312510 (2019).","journal-title":"Inorg. Chem."},{"key":"69445_CR27","doi-asserted-by":"publisher","first-page":"26662","DOI":"10.1039\/C7CP05296K","volume":"19","author":"J Blahut","year":"2017","unstructured":"Blahut, J., Hermann, P., To\u0161ner, Z. & Platas-Iglesias, C. A combined NMR and DFT study of conformational dynamics in lanthanide complexes of macrocyclic DOTA-like ligands. Phys. Chem. Chem. Phys. 19, 26662\u201326671 (2017).","journal-title":"Phys. Chem. Chem. Phys."},{"key":"69445_CR28","doi-asserted-by":"publisher","first-page":"5762","DOI":"10.1021\/ja990225d","volume":"121","author":"S Aime","year":"1999","unstructured":"Aime, S. et al. NMR, relaxometric, and structural studies of the hydration and exchange dynamics of cationic lanthanide complexes of macrocyclic tetraamide ligands. J. Am. Chem. Soc. 121, 5762\u20135771 (1999).","journal-title":"J. Am. Chem. Soc."},{"key":"69445_CR29","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202417582","volume":"64","author":"L Tacconi","year":"2025","unstructured":"Tacconi, L. et al. Exploiting high order magnetic anisotropy for advanced magnetocaloric refrigerants. Angew. Chem. Int. Ed. 64, e202417582 (2025).","journal-title":"Angew. Chem. Int. Ed."},{"key":"69445_CR30","doi-asserted-by":"publisher","first-page":"348","DOI":"10.1038\/nature16984","volume":"531","author":"M Shiddiq","year":"2016","unstructured":"Shiddiq, M. et al. Enhancing coherence in molecular spin qubits via atomic clock transitions. Nature 531, 348\u2013351 (2016).","journal-title":"Nature"},{"key":"69445_CR31","doi-asserted-by":"publisher","first-page":"893","DOI":"10.1039\/C5QI00142K","volume":"2","author":"JJ Baldov\u00ed","year":"2015","unstructured":"Baldov\u00ed, J. J. et al. Molecular spin qubits based on lanthanide ions encapsulated in cubic polyoxopalladates: design criteria to enhance quantum coherence. Inorg. Chem. Front. 2, 893\u2013897 (2015).","journal-title":"Inorg. Chem. Front."},{"key":"69445_CR32","doi-asserted-by":"publisher","first-page":"12565","DOI":"10.1021\/ic302068c","volume":"51","author":"JJ Baldov\u00ed","year":"2012","unstructured":"Baldov\u00ed, J. J. et al. Rational design of single-ion magnets and spin qubits based on mononuclear lanthanoid complexes. Inorg. Chem. 51, 12565\u201312574 (2012).","journal-title":"Inorg. Chem."},{"key":"69445_CR33","doi-asserted-by":"publisher","first-page":"12558","DOI":"10.1039\/D5SC01893E","volume":"16","author":"J Faltejsek","year":"2025","unstructured":"Faltejsek, J. et al. Extraordinary kinetic inertness of lanthanide(III) complexes of pyridine-rigidified 18-membered hexaazamacrocycles with four acetate pendant arms. Chem. Sci. 16, 12558\u201312567 (2025).","journal-title":"Chem. Sci."},{"key":"69445_CR34","doi-asserted-by":"publisher","first-page":"113348","DOI":"10.1016\/j.inoche.2024.113348","volume":"170","author":"C Harriswangler","year":"2024","unstructured":"Harriswangler, C. et al. Dynamics of Lanthanide(III) complexes from crystallographic data and computational studies. Inorg. Chem. Commun. 170, 113348 (2024).","journal-title":"Inorg. Chem. Commun."},{"key":"69445_CR35","doi-asserted-by":"publisher","first-page":"10429","DOI":"10.1021\/jacs.1c05339","volume":"143","author":"A Hu","year":"2021","unstructured":"Hu, A. et al. Py-macrodipa: a janus chelator capable of binding medicinally relevant rare-earth radiometals of disparate sizes. J. Am. Chem. Soc. 143, 10429\u201310440 (2021).","journal-title":"J. Am. Chem. Soc."},{"key":"69445_CR36","doi-asserted-by":"publisher","first-page":"9515","DOI":"10.1002\/chem.200700883","volume":"13","author":"A-S Chauvin","year":"2007","unstructured":"Chauvin, A.-S. et al. A polyoxyethylene-substituted bimetallic europium helicate for luminescent staining of living cells. Chem. Eur. J. 13, 9515\u20139526 (2007).","journal-title":"Chem. Eur. J."},{"key":"69445_CR37","doi-asserted-by":"publisher","first-page":"6374","DOI":"10.1021\/acs.chemrev.1c00602","volume":"122","author":"X-Z Li","year":"2022","unstructured":"Li, X.-Z., Tian, C.-B. & Sun, Q.-F. Coordination-directed self-assembly of functional polynuclear lanthanide supramolecular architectures. Chem. Rev. 122, 6374\u20136458 (2022).","journal-title":"Chem. Rev."},{"key":"69445_CR38","doi-asserted-by":"publisher","first-page":"7949","DOI":"10.1039\/D0CS00292E","volume":"49","author":"F Saraci","year":"2020","unstructured":"Saraci, F., Quezada-Novoa, V., Donnarumma, P. R. & Howarth, A. J. Rare-earth metal\u2013organic frameworks: from structure to applications. Chem. Soc. Rev. 49, 7949\u20137977 (2020).","journal-title":"Chem. Soc. Rev."},{"key":"69445_CR39","doi-asserted-by":"publisher","first-page":"2423","DOI":"10.1039\/C5CS00770D","volume":"45","author":"K Liu","year":"2016","unstructured":"Liu, K. et al. Constraining the coordination geometries of lanthanide centers and magnetic building blocks in frameworks: a new strategy for molecular nanomagnets. Chem. Soc. Rev. 45, 2423\u20132439 (2016).","journal-title":"Chem. Soc. Rev."},{"key":"69445_CR40","doi-asserted-by":"publisher","first-page":"3706","DOI":"10.1080\/00958972.2014.957201","volume":"67","author":"J-CG B\u00fcnzli","year":"2014","unstructured":"B\u00fcnzli, J.-C. G. Review: Lanthanide coordination chemistry: from old concepts to coordination polymers. J. Coord. Chem. 67, 3706\u20133733 (2014).","journal-title":"J. Coord. Chem."},{"key":"69445_CR41","doi-asserted-by":"publisher","first-page":"213146","DOI":"10.1016\/j.ccr.2019.213146","volume":"406","author":"JA Peters","year":"2020","unstructured":"Peters, J. A., Djanashvili, K., Geraldes, C. F. G. C. & Platas-Iglesias, C. The chemical consequences of the gradual decrease of the ionic radius along the Ln-series. Coord. Chem. Rev. 406, 213146 (2020).","journal-title":"Coord. Chem. Rev."},{"key":"69445_CR42","doi-asserted-by":"publisher","first-page":"11153","DOI":"10.1021\/ja072750f","volume":"129","author":"M Seitz","year":"2007","unstructured":"Seitz, M., Oliver, A. G. & Raymond, K. N. The lanthanide contraction revisited. J. Am. Chem. Soc. 129, 11153\u201311160 (2007).","journal-title":"J. Am. Chem. Soc."},{"key":"69445_CR43","doi-asserted-by":"publisher","first-page":"8537","DOI":"10.1039\/D1SC01076J","volume":"12","author":"A van der Lee","year":"2021","unstructured":"van der Lee, A. & Dumitrescu, D. G. Thermal expansion properties of organic crystals: a CSD study. Chem. Sci. 12, 8537\u20138547 (2021).","journal-title":"Chem. Sci."},{"key":"69445_CR44","doi-asserted-by":"publisher","first-page":"5476","DOI":"10.1039\/C9DT00542K","volume":"48","author":"M Bazargan","year":"2019","unstructured":"Bazargan, M., Mirzaei, M., Franconetti, A. & Frontera, A. On the preferences of five-membered chelate rings in coordination chemistry: insights from the Cambridge Structural Database and theoretical calculations. Dalton Trans. 48, 5476\u20135490 (2019).","journal-title":"Dalton Trans."},{"key":"69445_CR45","doi-asserted-by":"publisher","first-page":"9427","DOI":"10.1021\/acs.chemrev.9b00155","volume":"119","author":"R Taylor","year":"2019","unstructured":"Taylor, R. & Wood, P. A. A million crystal structures: the whole is greater than the sum of its parts. Chem. Rev. 119, 9427\u20139477 (2019).","journal-title":"Chem. Rev."},{"key":"69445_CR46","doi-asserted-by":"publisher","first-page":"380","DOI":"10.1107\/S0108768102003890","volume":"58","author":"FH Allen","year":"2002","unstructured":"Allen, F. H. The Cambridge Structural Database: a quarter of a million crystal structures and rising. Acta Crystallogr. Sect. B 58, 380\u2013388 (2002).","journal-title":"Acta Crystallogr. Sect. B"},{"key":"69445_CR47","doi-asserted-by":"publisher","first-page":"1235","DOI":"10.1107\/S1600576724005934","volume":"57","author":"RA Sykes","year":"2024","unstructured":"Sykes, R. A. et al. What has scripting ever done for us? the CSD Python application programming interface (API). J. Appl. Crystallogr. 57, 1235\u20131250 (2024).","journal-title":"J. Appl. Crystallogr."},{"key":"69445_CR48","doi-asserted-by":"publisher","first-page":"683","DOI":"10.1107\/S2052520620007994","volume":"76","author":"D Waroquiers","year":"2020","unstructured":"Waroquiers, D. et al. ChemEnv: a fast and robust coordination environment identification tool. Acta Crystallogr. Sect. B 76, 683\u2013695 (2020).","journal-title":"Acta Crystallogr. Sect. B"},{"key":"69445_CR49","doi-asserted-by":"publisher","first-page":"011002","DOI":"10.1063\/1.4812323","volume":"1","author":"A Jain","year":"2013","unstructured":"Jain, A. et al. Commentary: The materials project: a materials genome approach to accelerating materials innovation. APL Mater. 1, 011002 (2013).","journal-title":"APL Mater."},{"key":"69445_CR50","doi-asserted-by":"publisher","first-page":"314","DOI":"10.1016\/j.commatsci.2012.10.028","volume":"68","author":"SP Ong","year":"2013","unstructured":"Ong, S. P. et al. Python Materials Genomics (pymatgen): a robust, open-source python library for materials analysis. Comput. Mater. Sci. 68, 314\u2013319 (2013).","journal-title":"Comput. Mater. Sci."},{"key":"69445_CR51","doi-asserted-by":"publisher","first-page":"772","DOI":"10.1107\/S0567739479001765","volume":"35","author":"M O\u2019Keeffe","year":"1979","unstructured":"O\u2019Keeffe, M. A proposed rigorous definition of coordination number. Acta Crystallogr. Sect. A 35, 772\u2013775 (1979).","journal-title":"Acta Crystallogr. Sect. A"},{"key":"69445_CR52","doi-asserted-by":"publisher","first-page":"2553","DOI":"10.1021\/ic50187a041","volume":"17","author":"JK Burdett","year":"1978","unstructured":"Burdett, J. K., Hoffmann, R. & Fay, R. C. Eight-coordination. Inorg. Chem. 17, 2553\u20132568 (1978).","journal-title":"Inorg. Chem."},{"key":"69445_CR53","doi-asserted-by":"publisher","first-page":"4207","DOI":"10.1021\/cr990114x","volume":"103","author":"AEV Gorden","year":"2003","unstructured":"Gorden, A. E. V., Xu, J., Raymond, K. N. & Durbin, P. Rational design of sequestering agents for plutonium and other actinides. Chem. Rev. 103, 4207\u20134282 (2003).","journal-title":"Chem. Rev."},{"key":"69445_CR54","doi-asserted-by":"publisher","first-page":"4156","DOI":"10.1021\/ic000063i","volume":"39","author":"J Xu","year":"2000","unstructured":"Xu, J., Radkov, E., Ziegler, M. & Raymond, K. N. Plutonium(IV) Sequestration: structural and thermodynamic evaluation of the extraordinarily stable cerium(IV) hydroxypyridinonate complexes1. Inorg. Chem. 39, 4156\u20134164 (2000).","journal-title":"Inorg. Chem."},{"key":"69445_CR55","doi-asserted-by":"publisher","first-page":"1748","DOI":"10.1021\/ja00813a017","volume":"96","author":"EL Muetterties","year":"1974","unstructured":"Muetterties, E. L. & Guggenberger, L. J. Idealized polytopal forms. description of real molecules referenced to idealized polygons or polyhedra in geometric reaction path form. J. Am. Chem. Soc. 96, 1748\u20131756 (1974).","journal-title":"J. Am. Chem. Soc."},{"key":"69445_CR56","doi-asserted-by":"publisher","first-page":"244","DOI":"10.1007\/BF00744495","volume":"13","author":"MA Porai-Koshits","year":"1972","unstructured":"Porai-Koshits, M. A. & Aslanov, L. A. Some aspects of the stereochemistry of eight-coordinate complexes. J. Struct. Chem. 13, 244\u2013253 (1972).","journal-title":"J. Struct. Chem."},{"key":"69445_CR57","doi-asserted-by":"publisher","first-page":"3162","DOI":"10.1002\/chem.200501516","volume":"12","author":"J Cirera","year":"2006","unstructured":"Cirera, J., Ruiz, E. & Alvarez, S. Shape and spin state in four-coordinate transition-metal complexes: the case of the d6 configuration. Chem. Eur. J. 12, 3162\u20133167 (2006).","journal-title":"Chem. Eur. J."},{"key":"69445_CR58","doi-asserted-by":"publisher","first-page":"5575","DOI":"10.1021\/ic9804925","volume":"37","author":"M Pinsky","year":"1998","unstructured":"Pinsky, M. & Avnir, D. Continuous symmetry measures. 5. the classical polyhedra. Inorg. Chem. 37, 5575\u20135582 (1998).","journal-title":"Inorg. Chem."},{"key":"69445_CR59","doi-asserted-by":"publisher","first-page":"7843","DOI":"10.1021\/ja00046a033","volume":"114","author":"H Zabrodsky","year":"1992","unstructured":"Zabrodsky, H., Peleg, S. & Avnir, D. Continuous symmetry measures. J. Am. Chem. Soc. 114, 7843\u20137851 (1992).","journal-title":"J. Am. Chem. Soc."},{"key":"69445_CR60","doi-asserted-by":"publisher","first-page":"1755","DOI":"10.1021\/ja036479n","volume":"126","author":"D Casanova","year":"2004","unstructured":"Casanova, D. et al. Minimal distortion pathways in polyhedral rearrangements. J. Am. Chem. Soc. 126, 1755\u20131763 (2004).","journal-title":"J. Am. Chem. Soc."},{"key":"69445_CR61","doi-asserted-by":"publisher","first-page":"1479","DOI":"10.1002\/chem.200400799","volume":"11","author":"D Casanova","year":"2005","unstructured":"Casanova, D., Llunell, M., Alemany, P. & Alvarez, S. The rich stereochemistry of eight-vertex polyhedra: a continuous shape measures study. Chem. Eur. J. 11, 1479\u20131494 (2005).","journal-title":"Chem. Eur. J."},{"key":"69445_CR62","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-66054-7","volume":"16","author":"VRM Nielsen","year":"2025","unstructured":"Nielsen, V. R. M. & Just S\u00f8rensen, T. Determining molecular structure, coordination geometry, and molecular symmetry using a continuous symmetry operation measure software. Nat. Commun. 16, 11122 (2025).","journal-title":"Nat. Commun."},{"key":"69445_CR63","doi-asserted-by":"publisher","first-page":"5740","DOI":"10.1021\/acs.jpca.4c00801","volume":"128","author":"VRM Nielsen","year":"2024","unstructured":"Nielsen, V. R. M., Le Guennic, B. & S\u00f8rensen, T. J. Evaluation of point group symmetry in lanthanide(iii) complexes: a new implementation of a continuous symmetry operation measure with autonomous assignment of the principal axis. J. Phys. Chem. A 128, 5740\u20135751 (2024).","journal-title":"J. Phys. Chem. A"},{"key":"69445_CR64","doi-asserted-by":"crossref","unstructured":"Hagberg, A., Swart, P. J. & Schult, D. A. Exploring Network Structure, Dynamics, and Function Using NetworkX. In Proceedings of the 7th Python in Science Conference (SciPy2008) (eds. Varoquaax, G., Vaught, T. & Millman, J.) 11\u201315 (Pasadena, CA, 2008).","DOI":"10.25080\/TCWV9851"},{"key":"69445_CR65","doi-asserted-by":"publisher","first-page":"90","DOI":"10.1109\/MCSE.2007.55","volume":"9","author":"JD Hunter","year":"2007","unstructured":"Hunter, J. D. Matplotlib: A 2D graphics environment. Comput. Sci. Eng. 9, 90\u201395 (2007).","journal-title":"Comput. Sci. Eng."},{"key":"69445_CR66","doi-asserted-by":"crossref","unstructured":"Gansner, E. R., Koren, Y. & North, S. Graph Drawing by Stress Majorization. in Graph Drawing (ed. Pach, J.) 239\u2013250 (Springer, Berlin, Heidelberg, 2005).","DOI":"10.1007\/978-3-540-31843-9_25"},{"key":"69445_CR67","doi-asserted-by":"publisher","first-page":"996","DOI":"10.1039\/b200641n","volume":"26","author":"S Alvarez","year":"2002","unstructured":"Alvarez, S., Avnir, D., Llunell, M. & Pinsky, M. Continuous symmetry maps and shape classification. The case of six-coordinated metal compounds. New J. Chem. 26, 996\u20131009 (2002).","journal-title":"New J. Chem."},{"key":"69445_CR68","doi-asserted-by":"publisher","first-page":"8960","DOI":"10.1039\/D2DT01522F","volume":"51","author":"MS Thomsen","year":"2022","unstructured":"Thomsen, M. S., Anker, A. S., Kacenauskaite, L. & S\u00f8rensen, T. J. We are never ever getting (back to) ideal symmetry: structure and luminescence in a ten-coordinated europium(III) sulfate crystal. Dalton Trans. 51, 8960\u20138963 (2022).","journal-title":"Dalton Trans."},{"key":"69445_CR69","doi-asserted-by":"publisher","first-page":"10432","DOI":"10.1002\/chem.200900435","volume":"15","author":"P Wang","year":"2009","unstructured":"Wang, P., Ma, J.-P. & Dong, Y.-B. Guest-driven luminescence: lanthanide-based host\u2013guest systems with bimodal emissive properties based on a guest-driven approach. Chem. Eur. J. 15, 10432\u201310445 (2009).","journal-title":"Chem. Eur. J."},{"key":"69445_CR70","doi-asserted-by":"publisher","first-page":"4872","DOI":"10.1021\/ja070058e","volume":"129","author":"Y-B Dong","year":"2007","unstructured":"Dong, Y.-B. et al. Coordination-driven nanosized lanthanide \u201cmolecular lantern\u201d with tunable luminescent properties. J. Am. Chem. Soc. 129, 4872\u20134873 (2007).","journal-title":"J. Am. Chem. Soc."},{"key":"69445_CR71","doi-asserted-by":"publisher","first-page":"3287","DOI":"10.1002\/anie.200600455","volume":"45","author":"Z-X Wang","year":"2006","unstructured":"Wang, Z.-X. et al. A sodalite-like framework based on octacyanomolybdate and neodymium with guest methanol molecules and neodymium octahydrate ions. Angew. Chem. Int. Ed. 45, 3287\u20133291 (2006).","journal-title":"Angew. Chem. Int. Ed."},{"key":"69445_CR72","doi-asserted-by":"publisher","first-page":"P10008","DOI":"10.1088\/1742-5468\/2008\/10\/P10008","volume":"2008","author":"VD Blondel","year":"2008","unstructured":"Blondel, V. D., Guillaume, J.-L., Lambiotte, R. & Lefebvre, E. Fast unfolding of communities in large networks. J. Stat. Mech. 2008, P10008 (2008).","journal-title":"J. Stat. Mech."},{"key":"69445_CR73","doi-asserted-by":"publisher","first-page":"12476","DOI":"10.1002\/chem.201101838","volume":"17","author":"Y Bi","year":"2011","unstructured":"Bi, Y. et al. Capping ligand perturbed slow magnetic relaxation in dysprosium single-ion magnets. Chem. Eur. J. 17, 12476\u201312481 (2011).","journal-title":"Chem. Eur. J."},{"key":"69445_CR74","doi-asserted-by":"publisher","first-page":"5417","DOI":"10.1021\/ic1021164","volume":"50","author":"C Freund","year":"2011","unstructured":"Freund, C. et al. Thiophene based europium \u03b2-diketonate complexes: effect of the ligand structure on the emission quantum yield. Inorg. Chem. 50, 5417\u20135429 (2011).","journal-title":"Inorg. Chem."},{"key":"69445_CR75","doi-asserted-by":"publisher","first-page":"1818","DOI":"10.1021\/ic048951r","volume":"44","author":"A Bellusci","year":"2005","unstructured":"Bellusci, A. et al. Synthesis and luminescent properties of novel lanthanide(iii) \u03b2-diketone complexes with nitrogen p,p\u2018-disubstituted aromatic ligands. Inorg. Chem. 44, 1818\u20131825 (2005).","journal-title":"Inorg. Chem."},{"key":"69445_CR76","doi-asserted-by":"publisher","first-page":"5117","DOI":"10.1021\/ja01077a015","volume":"86","author":"LR Melby","year":"1964","unstructured":"Melby, L. R., Rose, N. J., Abramson, E. & Caris, J. C. Synthesis and fluorescence of some trivalent lanthanide complexes. J. Am. Chem. Soc. 86, 5117\u20135125 (1964).","journal-title":"J. Am. Chem. Soc."},{"key":"69445_CR77","doi-asserted-by":"publisher","first-page":"1187","DOI":"10.1021\/acscentsci.9b00288","volume":"5","author":"D Errulat","year":"2019","unstructured":"Errulat, D. et al. A luminescent thermometer exhibiting slow relaxation of the magnetization: toward self-monitored building blocks for next-generation optomagnetic devices. ACS Cent. Sci. 5, 1187\u20131198 (2019).","journal-title":"ACS Cent. Sci."},{"key":"69445_CR78","doi-asserted-by":"publisher","first-page":"14625","DOI":"10.1002\/chem.201902837","volume":"25","author":"DA G\u00e1lico","year":"2019","unstructured":"G\u00e1lico, D. A. et al. Triplet-state position and crystal-field tuning in opto-magnetic lanthanide complexes: two sides of the same coin. Chem. Eur. J. 25, 14625\u201314637 (2019).","journal-title":"Chem. Eur. J."},{"key":"69445_CR79","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-63226-3","volume":"16","author":"J Zheng","year":"2025","unstructured":"Zheng, J. et al. Lanthanide cerium(III) complex with deep-red emission beyond 700 nm. Nat. Commun. 16, 7801 (2025).","journal-title":"Nat. Commun."},{"key":"69445_CR80","doi-asserted-by":"publisher","first-page":"2141","DOI":"10.1039\/D3SC05146C","volume":"15","author":"W Yang","year":"2024","unstructured":"Yang, W. et al. Covalency versus magnetic axiality in Nd molecular magnets: Nd-photoluminescence, strong ligand-field, and unprecedented nephelauxetic effect in fullerenes NdM2N@C80 (M = Sc, Lu, Y). Chem. Sci. 15, 2141\u20132157 (2024).","journal-title":"Chem. Sci."},{"key":"69445_CR81","doi-asserted-by":"publisher","first-page":"3041","DOI":"10.1039\/C6DT04519G","volume":"46","author":"VA Ilichev","year":"2017","unstructured":"Ilichev, V. A. et al. LMCT facilitated room temperature phosphorescence and energy transfer in substituted thiophenolates of Gd and Yb. Dalton Trans. 46, 3041\u20133050 (2017).","journal-title":"Dalton Trans."},{"key":"69445_CR82","doi-asserted-by":"publisher","first-page":"19","DOI":"10.1016\/j.ccr.2014.10.013","volume":"293\u2013294","author":"J-CG B\u00fcnzli","year":"2015","unstructured":"B\u00fcnzli, J.-C. G. On the design of highly luminescent lanthanide complexes. Coord. Chem. Rev. 293\u2013294, 19\u201347 (2015).","journal-title":"Coord. Chem. Rev."},{"key":"69445_CR83","doi-asserted-by":"publisher","first-page":"69","DOI":"10.1016\/S0022-2313(99)00015-0","volume":"82","author":"S Petoud","year":"1999","unstructured":"Petoud, S. et al. Influence of charge-transfer states on the Eu(III) luminescence in mononuclear triple helical complexes with tridentate aromatic ligands. J. Lumin. 82, 69\u201379 (1999).","journal-title":"J. Lumin."},{"key":"69445_CR84","doi-asserted-by":"publisher","first-page":"751","DOI":"10.1107\/S0567739476001551","volume":"32","author":"RD Shannon","year":"1976","unstructured":"Shannon, R. D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr. Sect. A 32, 751\u2013767 (1976).","journal-title":"Acta Crystallogr. Sect. A"},{"key":"69445_CR85","doi-asserted-by":"publisher","first-page":"1461","DOI":"10.1039\/B201846M","volume":"26","author":"E Huskowska","year":"2002","unstructured":"Huskowska, E., Turowska-Tyrk, I., Legendziewicz, J. & Riehl, J. P. The structure and spectroscopy of lanthanide(III) complexes with 2,2\u2032-bipyridine-1,1\u2032-dioxide in solution and in the solid state: effects of ionic size and solvent on photophysics, ligand structure and coordination. New J. Chem. 26, 1461\u20131467 (2002).","journal-title":"New J. Chem."},{"key":"69445_CR86","doi-asserted-by":"publisher","first-page":"3702","DOI":"10.1021\/ic50190a076","volume":"17","author":"AR Al-Karaghouli","year":"1978","unstructured":"Al-Karaghouli, A. R., Day, R. O. & Wood, J. S. Crystal structure of tetrakis(2,2\u2019-bipyridine dioxide)lanthanum perchlorate: an example of cubic eight-coordination. Inorg. Chem. 17, 3702\u20133706 (1978).","journal-title":"Inorg. Chem."},{"key":"69445_CR87","doi-asserted-by":"publisher","first-page":"1128","DOI":"10.1002\/anie.201208218","volume":"52","author":"D Tu","year":"2013","unstructured":"Tu, D. et al. Breakdown of crystallographic site symmetry in lanthanide-doped NaYF4 crystals. Angew. Chem. Int. Ed. 52, 1128\u20131133 (2013).","journal-title":"Angew. Chem. Int. Ed."},{"key":"69445_CR88","doi-asserted-by":"publisher","first-page":"11942","DOI":"10.1039\/D0DT02439B","volume":"49","author":"G Handzlik","year":"2020","unstructured":"Handzlik, G. et al. Identical anomalous Raman relaxation exponent in a family of single ion magnets: towards reliable Raman relaxation determination? Dalton Trans. 49, 11942\u201311949 (2020).","journal-title":"Dalton Trans."},{"key":"69445_CR89","doi-asserted-by":"publisher","first-page":"1508","DOI":"10.1021\/acs.jpclett.9b03275","volume":"11","author":"G Handzlik","year":"2020","unstructured":"Handzlik, G. et al. Magnetization dynamics and coherent spin manipulation of a propeller gd(iii) complex with the smallest helicene ligand. J. Phys. Chem. Lett. 11, 1508\u20131515 (2020).","journal-title":"J. Phys. Chem. Lett."},{"key":"69445_CR90","doi-asserted-by":"publisher","first-page":"10974","DOI":"10.1021\/ic2015258","volume":"50","author":"H Svendsen","year":"2011","unstructured":"Svendsen, H. et al. Analysis of the photomagnetic properties of cyano-bridged heterobimetallic complexes by x-ray diffraction. Inorg. Chem. 50, 10974\u201310984 (2011).","journal-title":"Inorg. Chem."},{"key":"69445_CR91","doi-asserted-by":"publisher","first-page":"16","DOI":"10.2174\/1874846501104010016","volume":"4","author":"Y Kimoto","year":"2011","unstructured":"Kimoto, Y., Matsui, T. & Akitsu, T. Isotope effect and lanthanide contraction for 3d-4f cyanide-bridged complexes exhibiting negative thermal expansion. Open Crystallogr. J. 4, 16\u201320 (2011).","journal-title":"Open Crystallogr. J."},{"key":"69445_CR92","doi-asserted-by":"publisher","first-page":"855","DOI":"10.1080\/00958970410001721439","volume":"57","author":"G Li","year":"2004","unstructured":"Li, G., Akitsu, T., Sato, O. & Einaga, Y. Three-dimensional 3d\u20134f hetero-bimetallic coordination polymers through hydrogen bonds: synthesis, structures and m\u00f6ssbauer spectrum analysis. J. Coord. Chem. 57, 855\u2013864 (2004).","journal-title":"J. Coord. Chem."},{"key":"69445_CR93","doi-asserted-by":"publisher","first-page":"175","DOI":"10.1016\/S0022-2860(99)00399-3","volume":"523","author":"JA Kautz","year":"2000","unstructured":"Kautz, J. A., Mullica, D. F., Cunningham, B. P., Combs, R. A. & Farmer, J. M. Synthesis, characterization, and structural analyses of two cyanide-bridged bimetallic complexes. J. Mol. Struct. 523, 175\u2013182 (2000).","journal-title":"J. Mol. Struct."},{"key":"69445_CR94","doi-asserted-by":"publisher","first-page":"6512","DOI":"10.1039\/D4CC01232A","volume":"60","author":"Y Iwai","year":"2024","unstructured":"Iwai, Y. et al. Giant anisotropic thermal expansion of copper-cyanido flat layers with flexible copper nodes. Chem. Commun. 60, 6512\u20136515 (2024).","journal-title":"Chem. Commun."},{"key":"69445_CR95","doi-asserted-by":"publisher","first-page":"8935","DOI":"10.1021\/acs.inorgchem.6b01442","volume":"55","author":"K Yamashita","year":"2016","unstructured":"Yamashita, K., Sakata, N. & Ogawa, T. Systematic structural elucidation for the protonated form of rare earth bis(porphyrinato) double-decker complexes: direct structural evidence of the location of the attached proton. Inorg. Chem. 55, 8935\u20138942 (2016).","journal-title":"Inorg. Chem."},{"key":"69445_CR96","doi-asserted-by":"publisher","first-page":"7796","DOI":"10.1039\/c2cc00086e","volume":"48","author":"D Tanaka","year":"2012","unstructured":"Tanaka, D. et al. Proton-induced switching of the single molecule magnetic properties of a porphyrin based TbIII double-decker complex. Chem. Commun. 48, 7796\u20137798 (2012).","journal-title":"Chem. Commun."},{"key":"69445_CR97","doi-asserted-by":"publisher","first-page":"213","DOI":"10.1038\/s41557-019-0387-6","volume":"12","author":"C Gao","year":"2020","unstructured":"Gao, C. et al. Observation of the asphericity of 4f-electron density and its relation to the magnetic anisotropy axis in single-molecule magnets. Nat. Chem. 12, 213\u2013219 (2020).","journal-title":"Nat. Chem."},{"key":"69445_CR98","doi-asserted-by":"publisher","first-page":"16576","DOI":"10.1002\/chem.201803300","volume":"24","author":"EA Klahn","year":"2018","unstructured":"Klahn, E. A. et al. Mapping the magnetic anisotropy at the atomic scale in dysprosium single-molecule magnets. Chem. Eur. J. 24, 16576\u201316581 (2018).","journal-title":"Chem. Eur. J."},{"key":"69445_CR99","doi-asserted-by":"publisher","first-page":"827","DOI":"10.1039\/C5QI00079C","volume":"2","author":"Y Dong","year":"2015","unstructured":"Dong, Y., Yan, P., Zou, X. & Li, G. Azacyclo-auxiliary ligand-tuned SMMs of dibenzoylmethane Dy(III) complexes. Inorg. Chem. Front. 2, 827\u2013836 (2015).","journal-title":"Inorg. Chem. Front."},{"key":"69445_CR100","doi-asserted-by":"publisher","first-page":"4587","DOI":"10.1039\/C5SC01245G","volume":"6","author":"K Qian","year":"2015","unstructured":"Qian, K. et al. Does the thermal evolution of molecular structures critically affect the magnetic anisotropy? Chem. Sci. 6, 4587\u20134593 (2015).","journal-title":"Chem. Sci."},{"key":"69445_CR101","doi-asserted-by":"publisher","first-page":"227","DOI":"10.1021\/acs.inorgchem.1c02779","volume":"61","author":"Y-S Ding","year":"2022","unstructured":"Ding, Y.-S. et al. Studies of the temperature dependence of the structure and magnetism of a hexagonal-bipyramidal dysprosium(III) single-molecule magnet. Inorg. Chem. 61, 227\u2013235 (2022).","journal-title":"Inorg. Chem."},{"key":"69445_CR102","doi-asserted-by":"publisher","first-page":"14489","DOI":"10.1021\/acs.inorgchem.8b02725","volume":"57","author":"Q Nie","year":"2018","unstructured":"Nie, Q., Xie, Y., Huang, W. & Wu, D. A Dynamic heterometal\u2013organic rhomboid exhibiting thermochromic and piezochromic luminescence. Inorg. Chem. 57, 14489\u201314492 (2018).","journal-title":"Inorg. Chem."},{"key":"69445_CR103","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.ccr.2015.02.015","volume":"295","author":"K Binnemans","year":"2015","unstructured":"Binnemans, K. et al. Interpretation of europium(III) spectra. Coord. Chem. Rev. 295, 1\u201345 (2015).","journal-title":"Coord. Chem. Rev."},{"key":"69445_CR104","doi-asserted-by":"publisher","first-page":"2301760","DOI":"10.1002\/adom.202301760","volume":"12","author":"P Ling-Hu","year":"2024","unstructured":"Ling-Hu, P., Guo, X., Hu, J., Deng, C. & Cui, R. Anomalous 5D0\u21927F4 transition of Eu3+-doped BaLaGaO4 phosphors for WLEDs and plant growth applications. Adv. Opt. Mater. 12, 2301760 (2024).","journal-title":"Adv. Opt. Mater."},{"key":"69445_CR105","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-022-21427-6","volume":"12","author":"S Shoji","year":"2022","unstructured":"Shoji, S. et al. Plant growth acceleration using a transparent Eu3+-painted UV-to-red conversion film. Sci. Rep. 12, 17155 (2022).","journal-title":"Sci. Rep."},{"key":"69445_CR106","doi-asserted-by":"publisher","first-page":"7973","DOI":"10.1021\/acs.jpcc.2c01396","volume":"126","author":"T Yoshida","year":"2022","unstructured":"Yoshida, T. et al. Hidden heterometallic interaction emerging from resonant inelastic x-ray scattering in luminescent Tb\u2013Pt molecules. J. Phys. Chem. C\u00a0126, 7973\u20137979 (2022).","journal-title":"J. Phys. Chem. C"},{"key":"69445_CR107","doi-asserted-by":"publisher","first-page":"513","DOI":"10.1246\/bcsj.20210429","volume":"95","author":"T Yoshida","year":"2022","unstructured":"Yoshida, T. et al. Insight into the Gd\u2013Pt bond: slow magnetic relaxation of a heterometallic Gd\u2013Pt complex. Bull. Chem. Soc. Jpn. 95, 513\u2013521 (2022).","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"69445_CR108","doi-asserted-by":"publisher","first-page":"235","DOI":"10.1021\/acs.inorgchem.9b02064","volume":"59","author":"NA Bonde","year":"2020","unstructured":"Bonde, N. A. et al. Importance of axial symmetry in elucidating lanthanide\u2013transition metal interactions. Inorg. Chem. 59, 235\u2013243 (2020).","journal-title":"Inorg. Chem."},{"key":"69445_CR109","doi-asserted-by":"publisher","first-page":"16638","DOI":"10.1039\/D0DT03716H","volume":"49","author":"S Sarwar","year":"2020","unstructured":"Sarwar, S. et al. Phthalocyanine-polyoxotungstate lanthanide double deckers. Dalton Trans. 49, 16638\u201316642 (2020).","journal-title":"Dalton Trans."},{"key":"69445_CR110","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-03706-x","volume":"9","author":"MA S\u00f8rensen","year":"2018","unstructured":"S\u00f8rensen, M. A. et al. Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet. Nat. Commun. 9, 1292 (2018).","journal-title":"Nat. Commun."},{"key":"69445_CR111","doi-asserted-by":"publisher","first-page":"3566","DOI":"10.1039\/C7SC00135E","volume":"8","author":"MA S\u00f8rensen","year":"2017","unstructured":"S\u00f8rensen, M. A. et al. Imposing high-symmetry and tuneable geometry on lanthanide centres with chelating Pt and Pd metalloligands. Chem. Sci. 8, 3566\u20133575 (2017).","journal-title":"Chem. Sci."},{"key":"69445_CR112","doi-asserted-by":"publisher","first-page":"65","DOI":"10.3390\/magnetochemistry5040065","volume":"5","author":"T Sato","year":"2019","unstructured":"Sato, T., Matsuzawa, S., Katoh, K., Breedlove, B. K. & Yamashita, M. Relationship between the coordination geometry and spin dynamics of dysprosium(iii) heteroleptic triple-decker complexes. Magnetochemistry 5, 65 (2019).","journal-title":"Magnetochemistry"},{"key":"69445_CR113","doi-asserted-by":"publisher","DOI":"10.1038\/srep08838","volume":"5","author":"H Shang","year":"2015","unstructured":"Shang, H., Zeng, S., Wang, H., Dou, J. & Jiang, J. Peripheral substitution: an easy way to tuning the magnetic behavior of tetrakis(phthalocyaninato) dysprosium(III) SMMs. Sci. Rep. 5, 8838 (2015).","journal-title":"Sci. Rep."},{"key":"69445_CR114","doi-asserted-by":"publisher","first-page":"8108","DOI":"10.1021\/jacs.1c02502","volume":"143","author":"M Briganti","year":"2021","unstructured":"Briganti, M. et al. Magnetic anisotropy trends along a full 4f-Series: The fn+7 effect. J. Am. Chem. Soc. 143, 8108\u20138115 (2021).","journal-title":"J. Am. Chem. Soc."},{"key":"69445_CR115","doi-asserted-by":"publisher","first-page":"125","DOI":"10.1056\/NEJMoa1607427","volume":"376","author":"J Strosberg","year":"2017","unstructured":"Strosberg, J. et al. Phase 3 trial of 177Lu-dotatate for midgut neuroendocrine tumors. N. Engl. J. Med. 376, 125\u2013135 (2017).","journal-title":"N. Engl. J. Med."},{"key":"69445_CR116","doi-asserted-by":"publisher","first-page":"1319","DOI":"10.1007\/s002590100574","volume":"28","author":"DJ Kwekkeboom","year":"2001","unstructured":"Kwekkeboom, D. J. et al. [177Lu-DOTA0Tyr3]octreotate: comparison with [111In-DTPA0]octreotide in patients. Eur. J. Nucl. Med. 28, 1319\u20131325 (2001).","journal-title":"Eur. J. Nucl. Med."},{"key":"69445_CR117","doi-asserted-by":"publisher","first-page":"1313","DOI":"10.1016\/S0010-8545(98)00169-6","volume":"178\u2013180","author":"M Meyer","year":"1998","unstructured":"Meyer, M., Dahaoui-Gindrey, V., Lecomte, C. & Guilard, R. Conformations and coordination schemes of carboxylate and carbamoyl derivatives of the tetraazamacrocycles cyclen and cyclam, and the relation to their protonation states. Coord. Chem. Rev. 178\u2013180, 1313\u20131405 (1998).","journal-title":"Coord. Chem. Rev."},{"key":"69445_CR118","doi-asserted-by":"publisher","first-page":"1164","DOI":"10.1007\/BF01602806","volume":"28","author":"MS Elmanharawy","year":"1978","unstructured":"Elmanharawy, M. S., Eid, A. H. & Kader, A. A. Spectra of europium-doped yttrium oxide and yttrium vanadate phosphors. Czech. J. Phys. 28, 1164\u20131173 (1978).","journal-title":"Czech. J. Phys."},{"key":"69445_CR119","doi-asserted-by":"publisher","first-page":"118","DOI":"10.1063\/1.1723611","volume":"5","author":"AK Levine","year":"1964","unstructured":"Levine, A. K. & Palilla, F. C. A new, highly efficient red-emitting cathodoluminescent phosphor (YVO4:Eu) for color television. Appl. Phys. Lett. 5, 118\u2013120 (1964).","journal-title":"Appl. Phys. Lett."},{"key":"69445_CR120","doi-asserted-by":"crossref","unstructured":"Zhu, G. et al. GdVO4:Eu3+,Bi3+ Nanoparticles as a contrast agent for MRI and luminescence bioimaging. ACS Omega 4, 15806\u201315814 (2019).","DOI":"10.1021\/acsomega.9b00444"},{"key":"69445_CR121","doi-asserted-by":"crossref","unstructured":"K\u00fchne, I. A., Anson, C. E. & Powell, A. K. The influence of halide substituents on the structural and magnetic properties of Fe6Dy3 Rings. Front. Chem. 8, 701 (2020).","DOI":"10.3389\/fchem.2020.00701"},{"key":"69445_CR122","doi-asserted-by":"publisher","first-page":"1021","DOI":"10.1039\/C5CC08887A","volume":"52","author":"IA K\u00fchne","year":"2016","unstructured":"K\u00fchne, I. A., Mereacre, V., Anson, C. E. & Powell, A. K. Nine members of a family of nine-membered cyclic coordination clusters; Fe6Ln3 wheels (Ln = Gd to Lu and Y). Chem. Commun. 52, 1021\u20131024 (2016).","journal-title":"Chem. Commun."},{"key":"69445_CR123","doi-asserted-by":"publisher","first-page":"104","DOI":"10.1016\/j.ica.2015.05.018","volume":"434","author":"Y-L Ren","year":"2015","unstructured":"Ren, Y.-L. et al. Lanthanide coordination compounds with 2,2\u2032-bipyridine-6,6\u2032-dicarboxylate: Synthesis, crystal structure, luminescence and magnetic property. Inorg. Chim. Acta 434, 104\u2013112 (2015).","journal-title":"Inorg. Chim. Acta"},{"key":"69445_CR124","doi-asserted-by":"publisher","first-page":"2974","DOI":"10.1039\/C5DT03897A","volume":"45","author":"M Ren","year":"2016","unstructured":"Ren, M. et al. Lanthanide salen-type complexes exhibiting single ion magnet and photoluminescent properties. Dalton Trans. 45, 2974\u20132982 (2016).","journal-title":"Dalton Trans."},{"key":"69445_CR125","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.202400280","volume":"25","author":"S Schlittenhardt","year":"2024","unstructured":"Schlittenhardt, S. et al. Spectral Hole-Burning Studies of a Mononuclear Eu(III) Complex Reveal Narrow Optical Linewidths of the 5D0\u21927F0 Transition and Seconds Long Nuclear Spin Lifetimes. ChemPhysChem 25, e202400280 (2024).","journal-title":"ChemPhysChem"},{"key":"69445_CR126","doi-asserted-by":"publisher","first-page":"152","DOI":"10.1016\/j.jlumin.2011.12.036","volume":"133","author":"RL Ahlefeldt","year":"2013","unstructured":"Ahlefeldt, R. L., Manson, N. B. & Sellars, M. J. Optical lifetime and linewidth studies of the 7F0\u21925D0 transition in EuCl3\u00b76H2O: A potential material for quantum memory applications. J. Lumin. 133, 152\u2013156 (2013).","journal-title":"J. Lumin."},{"key":"69445_CR127","doi-asserted-by":"publisher","first-page":"241","DOI":"10.1038\/s41586-021-04316-2","volume":"603","author":"D Serrano","year":"2022","unstructured":"Serrano, D. et al. Ultra-narrow optical linewidths in rare-earth molecular crystals. Nature 603, 241\u2013246 (2022).","journal-title":"Nature"},{"key":"69445_CR128","doi-asserted-by":"publisher","first-page":"156","DOI":"10.1016\/j.jlumin.2006.08.012","volume":"125","author":"RM Macfarlane","year":"2007","unstructured":"Macfarlane, R. M. Optical Stark spectroscopy of solids. J. Lumin. 125, 156\u2013174 (2007).","journal-title":"J. Lumin."},{"key":"69445_CR129","doi-asserted-by":"publisher","first-page":"105309","DOI":"10.1016\/j.infrared.2024.105309","volume":"139","author":"E Cai","year":"2024","unstructured":"Cai, E. et al. Sub-100 fs pulses lasers from Yb:GdScO3 crystal based on semiconductor saturable absorber mirrors. Infrared Phys. Technol. 139, 105309 (2024).","journal-title":"Infrared Phys. Technol."},{"key":"69445_CR130","doi-asserted-by":"publisher","first-page":"510","DOI":"10.1364\/OL.480400","volume":"48","author":"N Zhang","year":"2023","unstructured":"Zhang, N. et al. 44-fs pulse generation at 2.05 \u00b5m from a SESAM mode-locked Tm:GdScO3 laser. Opt. Lett. 48, 510\u2013513 (2023).","journal-title":"Opt. Lett."},{"key":"69445_CR131","doi-asserted-by":"publisher","first-page":"5409","DOI":"10.1039\/D2DT00769J","volume":"51","author":"Y Jiao","year":"2022","unstructured":"Jiao, Y. et al. Hybrid lanthanide double-deckers based on calixarene and polyoxometalate units. Dalton Trans. 51, 5409\u20135413 (2022).","journal-title":"Dalton Trans."},{"key":"69445_CR132","doi-asserted-by":"publisher","first-page":"9648","DOI":"10.1039\/D1DT00359C","volume":"50","author":"Y Jiao","year":"2021","unstructured":"Jiao, Y. et al. Exploiting complementary ligands for the construction of square antiprismatic monometallic lanthanide SMMs. Dalton Trans. 50, 9648\u20139654 (2021).","journal-title":"Dalton Trans."},{"key":"69445_CR133","doi-asserted-by":"publisher","first-page":"4551","DOI":"10.1002\/chem.201700886","volume":"23","author":"T Yoshida","year":"2017","unstructured":"Yoshida, T. et al. Field-induced slow magnetic relaxation of GdIII complex with a Pt\u2212Gd heterometallic bond. Chem. Eur. J. 23, 4551\u20134556 (2017).","journal-title":"Chem. Eur. J."},{"key":"69445_CR134","doi-asserted-by":"publisher","first-page":"921","DOI":"10.1088\/0953-8984\/3\/8\/005","volume":"3","author":"M Bouazaoui","year":"1991","unstructured":"Bouazaoui, M., Jacquier, B., Linares, C. & Strek, W. Two-photon transitions of Gd3+ in cubic Cs2NaGdCl6. J. Phys. Condens. Matter 3, 921 (1991).","journal-title":"J. Phys. Condens. Matter"},{"key":"69445_CR135","doi-asserted-by":"crossref","unstructured":"Downer, M. C. et al. The Puzzle of Two-photon Rare Earth Spectra In Solids. In Laser Spectroscopy of Solids II 29\u201375 (Springer, Berlin, Heidelberg, 1989).","DOI":"10.1007\/3540501541_2"},{"key":"69445_CR136","first-page":"210","volume":"209","author":"R Wietzke","year":"1999","unstructured":"Wietzke, R. & Mazzanti, M. Strong intramolecular \u03c0\u2013\u03c0 interactions favor the formation of 2:1 (L:M) lanthanide complexes of tris(2-benzimidazolylmethyl)amine. Chem. Commun. 209, 210 (1999).","journal-title":"Chem. Commun."},{"key":"69445_CR137","doi-asserted-by":"publisher","first-page":"13365","DOI":"10.1039\/C6CC06924J","volume":"52","author":"Q-W Li","year":"2016","unstructured":"Li, Q.-W. et al. Unprecedented hexagonal bipyramidal single-ion magnets based on metallacrowns. Chem. Commun. 52, 13365\u201313368 (2016).","journal-title":"Chem. Commun."},{"key":"69445_CR138","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202200336","volume":"28","author":"Y Gil","year":"2022","unstructured":"Gil, Y., Castro-Alvarez, A., Fuentealba, P., Spodine, E. & Aravena, D. Lanthanide SMMs Based on Belt Macrocycles: Recent Advances and General Trends. Chem. Eur. J. 28, e202200336 (2022).","journal-title":"Chem. Eur. J."},{"key":"69445_CR139","doi-asserted-by":"publisher","first-page":"10077","DOI":"10.1021\/jacs.1c05279","volume":"143","author":"Z Zhu","year":"2021","unstructured":"Zhu, Z. et al. Air-stable chiral single-molecule magnets with record anisotropy barrier exceeding 1800 K. J. Am. Chem. Soc. 143, 10077\u201310082 (2021).","journal-title":"J. Am. Chem. Soc."},{"key":"69445_CR140","doi-asserted-by":"publisher","first-page":"14146","DOI":"10.1002\/anie.201907686","volume":"58","author":"AB Canaj","year":"2019","unstructured":"Canaj, A. B. et al. Insight into D6h symmetry: targeting strong axiality in stable dysprosium(III) hexagonal bipyramidal single-ion magnets. Angew. Chem. Int. Ed. 58, 14146\u201314151 (2019).","journal-title":"Angew. Chem. Int. Ed."},{"key":"69445_CR141","doi-asserted-by":"publisher","first-page":"16219","DOI":"10.1002\/chem.201904325","volume":"25","author":"Z-H Li","year":"2019","unstructured":"Li, Z.-H., Zhai, Y.-Q., Chen, W.-P., Ding, Y.-S. & Zheng, Y.-Z. Air-Stable hexagonal bipyramidal dysprosium(iii) single-ion magnets with nearly perfect D6h local symmetry. Chem. Eur. J. 25, 16219\u201316224 (2019).","journal-title":"Chem. Eur. J."},{"key":"69445_CR142","doi-asserted-by":"publisher","first-page":"9997","DOI":"10.1002\/chem.201902068","volume":"25","author":"M Woods","year":"2019","unstructured":"Woods, M. et al. Crystal structures of DOTMA Chelates from Ce3+ to Yb3+: evidence for a continuum of metal ion hydration states. Chem. Eur. J. 25, 9997\u201310005 (2019).","journal-title":"Chem. Eur. J."},{"key":"69445_CR143","doi-asserted-by":"publisher","first-page":"113","DOI":"10.1039\/D3SC03928E","volume":"15","author":"AS Manvell","year":"2023","unstructured":"Manvell, A. S. et al. LnDOTA puppeteering: removing the water molecule and imposing tetragonal symmetry. Chem. Sci. 15, 113\u2013123 (2023).","journal-title":"Chem. Sci."},{"key":"69445_CR144","doi-asserted-by":"publisher","first-page":"e202501685","DOI":"10.1002\/chem.202501685","volume":"31","author":"TE Karpiuk","year":"2025","unstructured":"Karpiuk, T. E., Williams-Sekiguchi, R. Y., Mahato, S., Storr, T. & Leznoff, D. B. A Shape-complementarity approach to inducing short Au(III)\u00b7\u00b7\u00b7Au(III) contacts in tetracyanoaurate(III) salts. Chem. Eur. J. 31, e202501685 (2025).","journal-title":"Chem. Eur. J."},{"key":"69445_CR145","doi-asserted-by":"crossref","unstructured":"Davies, G. M. et al. Structural and Near-IR Photophysical Studies on Ternary Lanthanide Complexes Containing Poly(pyrazolyl) Borate and 1,3-diketonate Ligands. Dalton Trans. 1136\u20131144 (2004).","DOI":"10.1039\/B400992D"},{"key":"69445_CR146","doi-asserted-by":"publisher","unstructured":"Karpiuk, T. E. & Leznoff, D. B. Geometry and Point Group Information of Eight-Coordinate Lanthanide Fragments from the Cambridge Structural Database, Zenodo, https:\/\/doi.org\/10.5281\/zenodo.18064650, (2025).","DOI":"10.5281\/zenodo.18064650"}],"container-title":["Nature Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/s41467-026-69445-6","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41467-026-69445-6.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41467-026-69445-6.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,27]],"date-time":"2026-03-27T03:06:34Z","timestamp":1774580794000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/s41467-026-69445-6"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,2,17]]},"references-count":146,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2026,12]]}},"alternative-id":["69445"],"URL":"https:\/\/doi.org\/10.1038\/s41467-026-69445-6","relation":{},"ISSN":["2041-1723"],"issn-type":[{"value":"2041-1723","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,2,17]]},"assertion":[{"value":"15 August 2025","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"29 January 2026","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"17 February 2026","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"The authors declare no competing interests.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}],"article-number":"2845"}}