{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T21:45:43Z","timestamp":1787003143215,"version":"build-2736575974"},"reference-count":58,"publisher":"Springer Science and Business Media LLC","issue":"9","license":[{"start":{"date-parts":[[2020,8,17]],"date-time":"2020-08-17T00:00:00Z","timestamp":1597622400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"},{"start":{"date-parts":[[2020,8,17]],"date-time":"2020-08-17T00:00:00Z","timestamp":1597622400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Nat. Chem."],"published-print":{"date-parts":[[2020,9]]},"DOI":"10.1038\/s41557-020-0518-0","type":"journal-article","created":{"date-parts":[[2020,8,17]],"date-time":"2020-08-17T12:04:56Z","timestamp":1597665896000},"page":"801-807","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":85,"title":["A bis(silylene)-stabilized diphosphorus compound and its reactivity as a monophosphorus anion transfer reagent"],"prefix":"10.1038","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8781-3394","authenticated-orcid":false,"given":"Yuwen","family":"Wang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tibor","family":"Szilva\u0301si","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shenglai","family":"Yao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9873-4103","authenticated-orcid":false,"given":"Matthias","family":"Driess","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2020,8,17]]},"reference":[{"key":"518_CR1","unstructured":"Corbridge, D. E. C. Phosphorus: an Outline of its Chemistry, Biochemistry, and Technology 5th edn (Elsevier, 1995)."},{"key":"518_CR2","doi-asserted-by":"crossref","first-page":"1038","DOI":"10.1039\/b510917e","volume":"34","author":"M Peruzzini","year":"2005","unstructured":"Peruzzini, M., Gonsalvi, L. & Romerosa, A. Coordination chemistry and functionalization of white phosphorus via transition metal complexes. Chem. Soc. Rev. 34, 1038\u20131047 (2005).","journal-title":"Chem. Soc. Rev."},{"key":"518_CR3","doi-asserted-by":"crossref","first-page":"862","DOI":"10.1002\/anie.200503327","volume":"45","author":"CC Cummins","year":"2006","unstructured":"Cummins, C. C. Terminal, anionic carbide, nitride, and phosphide transition-metal complexes as synthetic entries to low-coordinate phosphorus derivatives. Angew. Chem. Int. Ed. 45, 862\u2013870 (2006).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR4","doi-asserted-by":"crossref","first-page":"4164","DOI":"10.1021\/cr9003709","volume":"110","author":"BM Cossairt","year":"2010","unstructured":"Cossairt, B. M., Piro, N. A. & Cummins, C. C. Early-transition-metal-mediated activation and transformation of white phosphorus. Chem. Rev. 110, 4164\u20134177 (2010).","journal-title":"Chem. Rev."},{"key":"518_CR5","doi-asserted-by":"crossref","first-page":"4178","DOI":"10.1021\/cr900349u","volume":"110","author":"M Caporali","year":"2010","unstructured":"Caporali, M., Gonsalvi, L., Rossin, A. & Peruzzini, M. P4 activation by late-transition metal complexes. Chem. Rev. 110, 4178\u20134235 (2010).","journal-title":"Chem. Rev."},{"key":"518_CR6","doi-asserted-by":"crossref","unstructured":"Figueroa, J. S. & Cummins, C. C. A niobaziridine hydride system for white phosphorus or dinitrogen activation and N- or P-atom transfer. Dalton Trans. 2161\u20132168 (2006).","DOI":"10.1039\/b602530g"},{"key":"518_CR7","doi-asserted-by":"crossref","first-page":"1276","DOI":"10.1126\/science.1129630","volume":"313","author":"NA Piro","year":"2006","unstructured":"Piro, N. A., Figueroa, J. S., McKellar, J. T. & Cummins, C. C. Triple-bond reactivity of diphosphorus molecules. Science 313, 1276\u20131279 (2006).","journal-title":"Science"},{"key":"518_CR8","doi-asserted-by":"crossref","first-page":"8863","DOI":"10.1002\/anie.200803971","volume":"47","author":"BM Cossairt","year":"2008","unstructured":"Cossairt, B. M. & Cummins, C. C. A niobium-mediated cycle producing phosphorus-rich organic molecules from white phosphorus (P4) through activation, functionalization, and transfer reactions. Angew. Chem. Int. Ed. 47, 8863\u20138866 (2008).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR9","doi-asserted-by":"crossref","first-page":"7516","DOI":"10.1002\/anie.201004385","volume":"49","author":"D Tofan","year":"2010","unstructured":"Tofan, D. & Cummins, C. C. Photochemical incorporation of diphosphorus units into organic molecules. Angew. Chem. Int. Ed. 49, 7516\u20137518 (2010).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR10","doi-asserted-by":"crossref","first-page":"4236","DOI":"10.1021\/cr100010e","volume":"110","author":"M Scheer","year":"2010","unstructured":"Scheer, M., Bal\u00e1zs, G. & Seitz, A. P4 activation by main group elements and compounds. Chem. Rev. 110, 4236\u20134256 (2010).","journal-title":"Chem. Rev."},{"key":"518_CR11","doi-asserted-by":"crossref","first-page":"1342","DOI":"10.1016\/j.ccr.2010.12.016","volume":"255","author":"NA Giffin","year":"2011","unstructured":"Giffin, N. A. & Masuda, J. D. Reactivity of white phosphorus with compounds of the p-block. Coord. Chem. Rev. 255, 1342\u20131359 (2011).","journal-title":"Coord. Chem. Rev."},{"key":"518_CR12","doi-asserted-by":"crossref","first-page":"2169","DOI":"10.1039\/c2cc17449a","volume":"48","author":"S Khan","year":"2012","unstructured":"Khan, S., Sen, S. S. & Roesky, H. W. Activation of phosphorus by group 14 elements in low oxidation states. Chem. Commun. 48, 2169\u20132179 (2012).","journal-title":"Chem. Commun."},{"key":"518_CR13","doi-asserted-by":"crossref","first-page":"6639","DOI":"10.1039\/C4CS00019F","volume":"43","author":"MH Holthausen","year":"2014","unstructured":"Holthausen, M. H. & Weigand, J. J. The chemistry of cationic polyphosphorus cages\u2013syntheses, structure and reactivity. Chem. Soc. Rev. 43, 6639\u20136657 (2014).","journal-title":"Chem. Soc. Rev."},{"key":"518_CR14","doi-asserted-by":"crossref","first-page":"11738","DOI":"10.1002\/chem.201702067","volume":"23","author":"JE Borger","year":"2017","unstructured":"Borger, J. E., Ehlers, A. W., Slootweg, J. C. & Lammertsma, K. Functionalization of P4 through direct P\u2212C bond formation. Chem. Eur. J. 23, 11738\u201311746 (2017).","journal-title":"Chem. Eur. J."},{"key":"518_CR15","doi-asserted-by":"crossref","first-page":"4462","DOI":"10.1002\/anie.201301137","volume":"52","author":"CL Dorsey","year":"2013","unstructured":"Dorsey, C. L., Squires, B. M. & Hudnall, T. W. Isolation of a neutral P8 cluster by [2+2] cycloaddition of a diphosphene facilitated by carbene activation of white phosphorus. Angew. Chem. Int. Ed. 52, 4462\u20134465 (2013).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR16","doi-asserted-by":"crossref","first-page":"11078","DOI":"10.1039\/C9SC04441H","volume":"10","author":"D Rottsch\u00e4fer","year":"2019","unstructured":"Rottsch\u00e4fer, D., Blomeyer, S., Neumann, B., Stammler, H.-G. & Ghadwal, R. S. Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides. Chem. Sci. 10, 11078\u201311085 (2019).","journal-title":"Chem. Sci."},{"key":"518_CR17","doi-asserted-by":"crossref","first-page":"3443","DOI":"10.1002\/anie.200353406","volume":"43","author":"Y Peng","year":"2004","unstructured":"Peng, Y. et al. [{HC(CMeNAr)2}2Al2P4] (Ar = 2,6-iPr2C6H3): a reduction to a formal {P4}4\u2212 charged species. Angew. Chem. Int. Ed. 43, 3443\u20133445 (2004).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR18","doi-asserted-by":"crossref","first-page":"7729","DOI":"10.1002\/anie.200502865","volume":"44","author":"AR Fox","year":"2005","unstructured":"Fox, A. R., Wright, R. J., Rivard, E. & Power, P. P. Tl2[Aryl2P4]: a thallium complexed diaryltetraphosphabutadienediide and its two-electron oxidation to a diaryltetraphosphabicyclobutane, Aryl2P4. Angew. Chem. Int. Ed. 44, 7729\u20137733 (2005).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR19","doi-asserted-by":"crossref","first-page":"5530","DOI":"10.1002\/anie.200902344","volume":"48","author":"O Back","year":"2009","unstructured":"Back, O., Kuchenbeiser, G., Donnadieu, B. & Bertrand, G. Nonmetal-mediated fragmentation of P4: isolation of P1 and P2 bis(carbene) adducts. Angew. Chem. Int. Ed. 48, 5530\u20135533 (2009).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR20","doi-asserted-by":"crossref","first-page":"7052","DOI":"10.1002\/anie.200703055","volume":"46","author":"JD Masuda","year":"2007","unstructured":"Masuda, J. D., Schoeller, W. W., Donnadieu, B. & Bertrand, G. Carbene activation of P4 and subsequent derivatization. Angew. Chem. Int. Ed. 46, 7052\u20137055 (2007).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR21","doi-asserted-by":"crossref","first-page":"4486","DOI":"10.1039\/c3cc42041h","volume":"49","author":"CD Martin","year":"2013","unstructured":"Martin, C. D., Weinstein, C. M., Moore, C. E., Rheingold, A. L. & Bertrand, G. Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters. Chem. Commun. 49, 4486\u20134488 (2013).","journal-title":"Chem. Commun."},{"key":"518_CR22","doi-asserted-by":"crossref","first-page":"14180","DOI":"10.1021\/ja077296u","volume":"129","author":"JD Masuda","year":"2007","unstructured":"Masuda, J. D., Schoeller, W. W., Donnadieu, B. & Bertrand, G. NHC-mediated aggregation of P4: isolation of a P12 cluster. J. Am. Chem. Soc. 129, 14180\u201314181 (2007).","journal-title":"J. Am. Chem. Soc."},{"key":"518_CR23","doi-asserted-by":"crossref","first-page":"4511","DOI":"10.1002\/anie.200701203","volume":"46","author":"Y Xiong","year":"2007","unstructured":"Xiong, Y., Yao, S., Brym, M. & Driess, M. Consecutive insertion of a silylene into the P4 tetrahedron: facile access to strained SiP4 and Si2P4 cage compounds. Angew. Chem. Int. Ed. 46, 4511\u20134513 (2007).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR24","doi-asserted-by":"crossref","first-page":"16141","DOI":"10.1002\/anie.201609899","volume":"55","author":"I Alvarado-Beltran","year":"2016","unstructured":"Alvarado-Beltran, I., Baceiredo, A., Saffon-Merceron, N., Branchadell, V. & Kato, T. Cyclic amino(ylide) silylene: a stable heterocyclic silylene with strongly electron-donating character. Angew. Chem. Int. Ed. 55, 16141\u201316144 (2016).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR25","doi-asserted-by":"crossref","first-page":"2322","DOI":"10.1002\/anie.201005866","volume":"50","author":"SS Sen","year":"2011","unstructured":"Sen, S. S. et al. Zwitterionic Si-C-Si-P and Si-P-Si-P four-membered rings with two-coordinate phosphorus atoms. Angew. Chem. Int. Ed. 50, 2322\u20132325 (2011).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR26","doi-asserted-by":"crossref","first-page":"11786","DOI":"10.1002\/anie.201105610","volume":"50","author":"S Khan","year":"2011","unstructured":"Khan, S., Michel, R., Sen, S. S., Roesky, H. W. & Stalke, D. A P4 chain and cage from silylene-activated white phosphorus. Angew. Chem. Int. Ed. 50, 11786\u201311789 (2011).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR27","doi-asserted-by":"crossref","first-page":"1038","DOI":"10.1002\/anie.198910381","volume":"28","author":"M Driess","year":"1989","unstructured":"Driess, M., Fanta, A. D., Powell, D. R. & West, R. Synthesis, characterization, and complexation of an unusual P2Si2 bicyclobutane with butterfly-structure: 2,2,4,4-tetramesityl-1,3-diphospha-2,4-disilabicyclo[1.1.0]butane. Angew. Chem. lnt. Ed. Engl. 28, 1038\u20131040 (1989).","journal-title":"Angew. Chem. lnt. Ed. Engl."},{"key":"518_CR28","doi-asserted-by":"crossref","first-page":"14970","DOI":"10.1021\/ja807828t","volume":"130","author":"Y Wang","year":"2008","unstructured":"Wang, Y. et al. Carbene-stabilized diphosphorus. J. Am. Chem. Soc. 130, 14970\u201314971 (2008).","journal-title":"J. Am. Chem. Soc."},{"key":"518_CR29","doi-asserted-by":"crossref","first-page":"4365","DOI":"10.1021\/ic00193a051","volume":"23","author":"H Bock","year":"1984","unstructured":"Bock, H. & M\u00fcller, H. Gas-phase reactions. 44. The P4 \u2194 2P2 equilibrium visualized. Inorg. Chem. 23, 4365\u20134368 (1984).","journal-title":"Inorg. Chem."},{"key":"518_CR30","doi-asserted-by":"crossref","first-page":"3323","DOI":"10.1063\/1.1436112","volume":"116","author":"A Kornath","year":"2002","unstructured":"Kornath, A., Kaufmann, A. & Torheyden, M. Raman spectroscopic studies on matrix isolated phosphorus molecules P4 and P2. J. Chem. Phys. 116, 3323\u20133326 (2002).","journal-title":"J. Chem. Phys."},{"key":"518_CR31","doi-asserted-by":"crossref","first-page":"3244","DOI":"10.1002\/chem.201901204","volume":"25","author":"D Rottsch\u00e4fer","year":"2019","unstructured":"Rottsch\u00e4fer, D. et al. A phosphorus analogue of p-quinodimethane with a planar P4 ring: a metal-free diphosphorus source. Chem. Eur. J. 25, 3244\u20133247 (2019).","journal-title":"Chem. Eur. J."},{"key":"518_CR32","doi-asserted-by":"crossref","first-page":"13499","DOI":"10.1021\/jacs.7b07167","volume":"139","author":"Y Wang","year":"2017","unstructured":"Wang, Y., Kostenko, A., Yao, S. & Driess, M. Divalent silicon-assisted activation of dihydrogen in a bis(N-heterocyclic silylene)xanthene nickel(0) complex for efficient catalytic hydrogenation of olefin. J. Am. Chem. Soc. 139, 13499\u201313506 (2017).","journal-title":"J. Am. Chem. Soc."},{"key":"518_CR33","doi-asserted-by":"crossref","first-page":"626","DOI":"10.1021\/jacs.8b11899","volume":"141","author":"Y Wang","year":"2019","unstructured":"Wang, Y. et al. Silicon-mediated selective homo- and heterocoupling of carbon monoxide. J. Am. Chem. Soc. 141, 626\u2013634 (2019).","journal-title":"J. Am. Chem. Soc."},{"key":"518_CR34","doi-asserted-by":"crossref","first-page":"1655","DOI":"10.1021\/jacs.8b11605","volume":"141","author":"Y Wang","year":"2019","unstructured":"Wang, Y., Karni, M., Yao, S., Apeloig, Y. & Driess, M. An isolable bis(silylene)-stabilized germylone and its reactivity. J. Am. Chem. Soc. 141, 1655\u20131664 (2019).","journal-title":"J. Am. Chem. Soc."},{"key":"518_CR35","doi-asserted-by":"crossref","first-page":"12916","DOI":"10.1021\/jacs.9b06603","volume":"141","author":"Y Wang","year":"2019","unstructured":"Wang, Y. et al. Synthesis of an isolable bis(silylene)-stabilized silylone and its reactivity toward small gaseous molecules. J. Am. Chem. Soc. 141, 12916\u201312927 (2019).","journal-title":"J. Am. Chem. Soc."},{"key":"518_CR36","doi-asserted-by":"crossref","first-page":"1545","DOI":"10.1039\/C3SC53140F","volume":"5","author":"AM Tondreau","year":"2014","unstructured":"Tondreau, A. M., Benk\u0151, Z., Harmerb, J. R. & Gr\u00fctzmacher, H. Sodium phosphaethynolate, Na(OCP), as a \u201cP\u201d transfer reagent for the synthesis of N-heterocyclic carbene supported P3 and PAsP radicals. Chem. Sci. 5, 1545\u20131554 (2014).","journal-title":"Chem. Sci."},{"key":"518_CR37","doi-asserted-by":"crossref","first-page":"6757","DOI":"10.1002\/anie.201402884","volume":"53","author":"D Heift","year":"2014","unstructured":"Heift, D., Benk\u0151, Z. & Gr\u00fctzmacher, H. Redox-triggered reversible interconversion of a monocyclic and a bicyclic phosphorus heterocycle. Angew. Chem. Int. Ed. 53, 6757\u20136761 (2014).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR38","doi-asserted-by":"crossref","first-page":"1356","DOI":"10.1002\/anie.201610156","volume":"56","author":"R Suter","year":"2017","unstructured":"Suter, R. et al. 2,4,6-Tri(hydroxy)-1,3,5-triphosphinine, P3C3(OH)3: the phosphorus analogue of cyanuric acid. Angew. Chem. Int. Ed. 56, 1356\u20131360 (2017).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR39","doi-asserted-by":"crossref","first-page":"19131","DOI":"10.1021\/ja4115693","volume":"135","author":"AR Jupp","year":"2013","unstructured":"Jupp, A. R. & Goicoechea, J. M. Phosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine. J. Am. Chem. Soc. 135, 19131\u201319134 (2013).","journal-title":"J. Am. Chem. Soc."},{"key":"518_CR40","doi-asserted-by":"crossref","first-page":"16968","DOI":"10.1002\/anie.201803888","volume":"57","author":"JM Goicoechea","year":"2018","unstructured":"Goicoechea, J. M. & Gr\u00fctzmacher, H. The chemistry of the 2-phosphaethynolate anion. Angew. Chem. Int. Ed. 57, 16968\u201316994 (2018).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR41","doi-asserted-by":"crossref","first-page":"8420","DOI":"10.1002\/anie.201102930","volume":"50","author":"FF Puschmann","year":"2011","unstructured":"Puschmann, F. F. et al. Phosphination of carbon monoxide: a simple synthesis of sodium phosphaethynolate (NaOCP). Angew. Chem. Int. Ed. 50, 8420\u20138423 (2011).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR42","doi-asserted-by":"crossref","first-page":"11226","DOI":"10.1002\/anie.201705473","volume":"56","author":"R Suter","year":"2017","unstructured":"Suter, R., Benk\u00f6, Z., Bispinghoff, M. & Gr\u00fctzmacher., H. Annulated 1,3,4-azadiphospholides: heterocycles with widely tunable optical properties. Angew. Chem. Int. Ed. 56, 11226\u201311231 (2017).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR43","doi-asserted-by":"crossref","first-page":"5077","DOI":"10.1039\/C4RA14417A","volume":"5","author":"Z Benedek","year":"2015","unstructured":"Benedek, Z. & Szilv\u00e1si, T. Can low-valent silicon compounds be better transition metal ligands than phosphines and NHCs? RSC Adv. 5, 5077\u20135086 (2015).","journal-title":"RSC Adv."},{"key":"518_CR44","doi-asserted-by":"crossref","first-page":"1485","DOI":"10.1021\/ed074p1485","volume":"74","author":"WH Hersh","year":"1997","unstructured":"Hersh, W. H. False AA\u2032X spin\u2212spin coupling systems in 13C NMR: examples involving phosphorus and a 20-year-old mystery in off-resonance decoupling. J. Chem. Educ. 74, 1485\u20131488 (1997).","journal-title":"J. Chem. Educ."},{"key":"518_CR45","doi-asserted-by":"crossref","first-page":"1326","DOI":"10.1002\/anie.199713261","volume":"36","author":"M Driess","year":"1997","unstructured":"Driess, M., Rell, S., Pritzkow, H. & Janoschek, R. R2Si=P\u2212SiR2F: 1,3-sigmatropic migration of fluorine in a 2-phospha-l,3-disilaallyl derivative capable of conjugation and its conversion to phosphadisilacyclopropanes. Angew. Chem. Int. Ed. Engl. 36, 1326\u20131329 (1997).","journal-title":"Angew. Chem. Int. Ed. Engl."},{"key":"518_CR46","doi-asserted-by":"crossref","first-page":"4262","DOI":"10.1021\/om900310u","volume":"28","author":"VYA Lee","year":"2009","unstructured":"Lee, V. Y. A., Kawai, M., Sekiguchi, A., Ranaivonjatovo, H. & Escudi\u00e9, J. A \u201cpush\u2013pull\u201d phosphasilene and phosphagermene and their anion-radicals. Organometallics 28, 4262\u20134265 (2009).","journal-title":"Organometallics"},{"key":"518_CR47","doi-asserted-by":"crossref","first-page":"369","DOI":"10.1038\/nchem.617","volume":"2","author":"O Back","year":"2010","unstructured":"Back, O., Donnadieu, B., Parameswaran, P., Frenking, G. & Bertrand, G. Isolation of crystalline carbene-stabilized P2-radical cations and P2-dications. Nat. Chem. 2, 369\u2013373 (2010).","journal-title":"Nat. Chem."},{"key":"518_CR48","doi-asserted-by":"crossref","first-page":"1335","DOI":"10.1007\/s11224-015-0668-7","volume":"26","author":"T Szilv\u00e1si","year":"2015","unstructured":"Szilv\u00e1si, T. & Veszpr\u00e9mi, T. Why do N-heterocyclic carbenes and silylenes activate white phosphorus differently? Struct. Chem. 26, 1335\u20131342 (2015).","journal-title":"Struct. Chem."},{"key":"518_CR49","doi-asserted-by":"crossref","first-page":"7193","DOI":"10.1039\/c0dt01685c","volume":"40","author":"T Szilv\u00e1si","year":"2011","unstructured":"Szilv\u00e1si, T. & Veszpr\u00e9mi, T. On the mechanism of the reaction of white phosphorus with silylenes. Dalton Trans. 40, 7193\u20137200 (2011).","journal-title":"Dalton Trans."},{"key":"518_CR50","doi-asserted-by":"crossref","first-page":"2365","DOI":"10.1021\/cr068357u","volume":"107","author":"T Sakakura","year":"2007","unstructured":"Sakakura, T., Choi, J.-C. & Yasuda, H. Transformation of carbon dioxide. Chem. Rev. 107, 2365\u20132387 (2007).","journal-title":"Chem. Rev."},{"key":"518_CR51","doi-asserted-by":"crossref","first-page":"6643","DOI":"10.1002\/anie.200901636","volume":"48","author":"CM M\u00f6mming","year":"2009","unstructured":"M\u00f6mming, C. M. et al. Reversible metal-free carbon dioxide binding by frustrated Lewis pairs. Angew. Chem. Int. Ed. 48, 6643\u20136646 (2009).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR52","doi-asserted-by":"crossref","unstructured":"Ellis, B. D., Dyker, C. A., Decken, A. & Macdonald, C. L. B. The synthesis, characterisation and electronic structure of N-heterocyclic carbene adducts of PI cations. Chem. Commun., 1965\u20131967 (2005)","DOI":"10.1039\/b500692a"},{"key":"518_CR53","doi-asserted-by":"crossref","first-page":"6864","DOI":"10.1021\/ic060186o","volume":"45","author":"BD Ellis","year":"2006","unstructured":"Ellis, B. D. & Macdonald, C. L. B. Phosphorus(I) iodide: a versatile metathesis reagent for the synthesis of low oxidation state phosphorus compounds. Inorg. Chem. 45, 6864\u20136874 (2006).","journal-title":"Inorg. Chem."},{"key":"518_CR54","doi-asserted-by":"crossref","first-page":"7465","DOI":"10.1002\/anie.201703731","volume":"56","author":"S Yao","year":"2017","unstructured":"Yao, S. et al. Facile access to NaOC\u2261As and its use as an arsenic source to form germylidenylarsinidene complexes. Angew. Chem. Int. Ed. 56, 7465\u20137469 (2017).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR55","doi-asserted-by":"crossref","first-page":"4781","DOI":"10.1002\/anie.201600701","volume":"55","author":"S Yao","year":"2016","unstructured":"Yao, S., Xiong, Y., Szilv\u00e1si, T., Gr\u00fctzmacher, H. & Driess, M. From a phosphaketenyl-functionalized germylene to 1,3-digerma-2,4-diphosphacyclobutadiene. Angew. Chem. Int. Ed. 55, 4781\u20134785 (2016).","journal-title":"Angew. Chem. Int. Ed."},{"key":"518_CR56","doi-asserted-by":"crossref","first-page":"3027","DOI":"10.1021\/om970068w","volume":"16","author":"A Buhling","year":"1997","unstructured":"Buhling, A. et al. Novel amphiphilic diphosphines: synthesis, X-ray structure, rhodium complexes, use in hydroformylation, and rhodium recycling. Organometallics 16, 3027\u20133037 (1997).","journal-title":"Organometallics"},{"key":"518_CR57","doi-asserted-by":"crossref","first-page":"1123","DOI":"10.1021\/ja9091374","volume":"132","author":"SS Sen","year":"2010","unstructured":"Sen, S. S., Roesky, H. W., Stern, D., Henn, J. & Stalke, D. High yield access to silylene RSiCl (R = PhC(NtBu)2) and its reactivity toward alkyne: synthesis of stable disilacyclobutene. J. Am. Chem. Soc. 132, 1123\u20131126 (2010).","journal-title":"J. Am. Chem. Soc."},{"key":"518_CR58","doi-asserted-by":"crossref","first-page":"5459","DOI":"10.1021\/om800714f","volume":"27","author":"S Nagendran","year":"2008","unstructured":"Nagendran, S. et al. RGe(I)Ge(I)R compound (R = PhC(NtBu)2) with a Ge\u2212Ge single bond and a comparison with the gauche conformation of hydrazine. Organometallics 27, 5459\u20135463 (2008).","journal-title":"Organometallics"}],"container-title":["Nature Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/s41557-020-0518-0.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41557-020-0518-0","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41557-020-0518-0.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,8,16]],"date-time":"2021-08-16T19:37:17Z","timestamp":1629142637000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/s41557-020-0518-0"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,8,17]]},"references-count":58,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2020,9]]}},"alternative-id":["518"],"URL":"https:\/\/doi.org\/10.1038\/s41557-020-0518-0","relation":{},"ISSN":["1755-4330","1755-4349"],"issn-type":[{"value":"1755-4330","type":"print"},{"value":"1755-4349","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,8,17]]},"assertion":[{"value":"22 January 2020","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"26 June 2020","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"17 August 2020","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"The authors declare no competing interests.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}]}}