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Mater."],"published-print":{"date-parts":[[2022,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>In principle, porous physisorbents are attractive candidates for the removal of volatile organic compounds such as benzene by virtue of their low energy for the capture and release of this pollutant. Unfortunately, many physisorbents exhibit weak sorbate\u2013sorbent interactions, resulting in poor selectivity and low uptake when volatile organic compounds are present at trace concentrations. Herein, we report that a family of double-walled metal\u2013dipyrazolate frameworks, BUT-53 to BUT-58, exhibit benzene uptakes at 298\u2009K of 2.47\u20133.28\u2009mmol\u2009g<jats:sup>\u22121<\/jats:sup> at &lt;10\u2009Pa. Breakthrough experiments revealed that BUT-55, a supramolecular isomer of the metal\u2013organic framework Co(BDP) (H<jats:sub>2<\/jats:sub>BDP\u2009=\u20091,4-di(1<jats:italic>H<\/jats:italic>-pyrazol-4-yl)benzene), captures trace levels of benzene, producing an air stream with benzene content below acceptable limits. Furthermore, BUT-55 can be regenerated with mild heating. Insight into the performance of BUT-55 comes from the crystal structure of the benzene-loaded phase (C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub>@BUT-55) and density functional theory calculations, which reveal that C\u2013H\u00b7\u00b7\u00b7X interactions drive the tight binding of benzene. Our results demonstrate that BUT-55 is a recyclable physisorbent that exhibits high affinity and adsorption capacity towards benzene, making it a candidate for environmental remediation of benzene-contaminated gas mixtures.<\/jats:p>","DOI":"10.1038\/s41563-022-01237-x","type":"journal-article","created":{"date-parts":[[2022,4,28]],"date-time":"2022-04-28T16:05:54Z","timestamp":1651161954000},"page":"689-695","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":294,"title":["Trace removal of benzene vapour using double-walled metal\u2013dipyrazolate frameworks"],"prefix":"10.1038","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3443-6243","authenticated-orcid":false,"given":"Tao","family":"He","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2940-8600","authenticated-orcid":false,"given":"Xiang-Jing","family":"Kong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhen-Xing","family":"Bian","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong-Zheng","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6783-4390","authenticated-orcid":false,"given":"Guang-Rui","family":"Si","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0017-3887","authenticated-orcid":false,"given":"Lin-Hua","family":"Xie","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xue-Qian","family":"Wu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongliang","family":"Huang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3865-2165","authenticated-orcid":false,"given":"Ze","family":"Chang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2646-7974","authenticated-orcid":false,"given":"Xian-He","family":"Bu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1360-540X","authenticated-orcid":false,"given":"Michael J.","family":"Zaworotko","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9622-2318","authenticated-orcid":false,"given":"Zuo-Ren","family":"Nie","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8101-8493","authenticated-orcid":false,"given":"Jian-Rong","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2022,4,28]]},"reference":[{"key":"1237_CR1","doi-asserted-by":"publisher","first-page":"4471","DOI":"10.1021\/acs.chemrev.8b00408","volume":"119","author":"C He","year":"2019","unstructured":"He, C. et al. 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